184 research outputs found

    PERTURBATION ANALYSIS IN THE ASUNDI SYSTEM (a3Σ+a3Π)(a^{\prime 3}\Sigma^{+}\to a{^{3}}\Pi) OF 13C16O^{13}C^{16}O) AND IN THE BALLIK-RAMASY SYSTEM (b1Σa2Π)(b^{1}\Sigma^{-} \to a^{2}\Pi) OF 13C2,12C13C^{13}C_{2}, {^{12}}C^{13}C

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    Author Institution: Address of Amiot and Islami: Laboratoire de Physique Mol\'eculaire et Optique Atmosph\'erique, CNRS, B\^{a}t. 221, Campus d'Orsay, 91405 Orsay Cedex, FranceThe molecules were produced by a microwave discharge through 13C16O^{13}C^{16}O or 13C16O+12C16O^{13}C ^{16}O + {^{12}}C^{16}O mixtures. The spectra were recorded in Laboratoire Aim\'e Cotton (Orsay) by high resolution Fourier transferm spectroscopy. Very strong perturbations (greater than 10cm110 cm^{-1}) were deteceted during the rotational analysis of the Asundi system. The vibrational levels v=0,1,3v=0,1,3, of the a13Σ+a^{13}\Sigma^{+} state interact respectively with the a3Πv=4,5,6a^{3}\Pi v=4,5,6, levels. The theoretical model we have used inculde second order spin-orbit and spin-rotation interactions parameters in order to reproduce the observed perturbed wavenumbers to the F.T.S. accuracy (about 0.003cm10.003 cm^{-1}). A similar work was performed for the Ballik-Ramsay system interactions. For the three molecules, about 11600 wavenumbers were reduce with a 0.003cm10.003 cm^{-1} R.M.S. Accurate molecular constants and interaction parameters were derived1,2derived^{1,2}. The variation of the electronic parameters with internulear distance will be discussed. 1^{1} C. Amiot and K. Islami, J. Mol. Spectrosc. (to appear) 2 K. Islami and C. Amiot, J Mol. Spectrose. (to appear)

    Pronostic de la pseudo-obstruction intestinale chronique (étude d'une cohorte dans une unité d'assistance nutritive)

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    PARIS7-Xavier Bichat (751182101) / SudocPARIS-BIUM (751062103) / SudocSudocFranceF

    HIGH RESOLUTION FOURIER SPECTROSCOPY OF THE LASER EXCITED Cs2Cs_{2} FLUORESCENCE SPECTRUM: FIVE NEW ELECTRONIC STATES

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    [1]^{[1]} C. AMIOT, C. CREPIN, J. VERGES. Chem. Phys. Lett. 98, 608 (1983) C. AMIOT, C. CREPIN, J. VERGES. Chem. Phys. Lett. (accepted) C. AMIOT, C. CREPIN, J. VERGES. J. Mol. Spectrosc. (submitted)Author Institution: Laboratoire Aim\'{e}-Cotton - CNRS II; Laboratoire de Physique Mol\'{e}culaire et d'Optique Atmosph\'{e}rique, B\^{a}timent 221, Campus d'OrsayThe fluorescence of Cs2Cs_{2} was observed inside a heat pipe oven which was operated at sim350Csim 350^{\circ}C. The spectra were recorded at high resolution (0.005cm1)(0.005 cm^{-1}) with a Fourier transform Interferometer. The fluorescence excited by the Ar+Ar^{+} and Kr+Kr^{+} lasers was observed mainly in the 4300cm1,6500cm1,8500cm14 300cm^{-1}, 6 500cm^{-1}, 8 500cm^{-1} spectral regions and also near the laser lines. The molecular constants of the pumped E1Πu+E {^{1}}\Pi_{u}^{+} state where deduced from an analysis of the rotational relaxations and also thanks to the great number of pumped rotational levels. Molecular constants for three gerade states: (1)1Πg,(2)1Σg+(1) {^{1}}\Pi_{g}, (2) {^{1}}\Sigma^{+}_{g} and (3)1Σg+(3) {^{1}}\Sigma^{+}_{g} were derived from the study of the fluorescence spectra [1]. When using the ring dye laser, very high vibrational levels of the (2) 1Σg+{^{1}}\Sigma^{+}_{g} state were observed. Triplets in the 4200cm14 200 cm^{-1} region were assigned to the fluorescence from the D1Σu+D {^{1}}\Sigma^{+}_{u} state to the 1g1_{g} component of the lowest 3Σg+{^{3}}\Sigma^{+}_{g} state

    Derived invariants for surface cut algebras II: the punctured case

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    32 pagesInternational audienceFor each algebra of global dimension 2 arising from the quiver with potential associated to a triangulation of an unpunctured surface, Amiot-Grimeland have defined an integer-valued function on the first singular homology group of the surface, and have proved that two such algebras of global dimension 2 are derived equivalent precisely when there exists an automorphism of the surface that makes their associated functions coincide. In the present paper we generalize the constructions and results of Amiot-Grimeland to the setting of arbitrarily punctured surfaces. As an application, we show that there always is a derived equivalence between any two algebras of global dimension 2 arising from the quivers with potential of (valency at least 2) triangulations of arbitrarily punctured polygons. While in the unpunctured case the quiver with potential of any triangulation admits cuts yielding algebras of global dimension at most 2, in the case of punctured surfaces the QPs of some triangulations do not admit cuts, and even when they do, the global dimension of the corresponding degree-0 algebra may exceed 2. In this paper we give a combinatorial characterization of each of these two situations

    HIGH RESOLUTION SPECTRA OF NITROUS OXIDE AND OF THE ISOTOPIC SPECIESl4Nl5HO16,15N216O^{l4}N^{l5}H^{16}_{O},^{15}N_{2}^{16}O, 15N14N16O^{15}N^{14}N^{16}O IN THE REGION 3000cm18000cm13000 cm^{-1} - 8000 cm^{-1}

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    ^{*}C. Amiot and G. Guelachvili, J. Mol Spectrosc. (to be published)Author Institution: Laboratoire de Physique, Mol\'{e}culaire et d'Optique Atmosph\'{e}rique B\^{a}timent 221.High resolution spectra of nitrous oxide and of the three isotopic species l4Nl5NO16^{l4}N^{l5}N^{16}_{O}, 15N14Nl6O{}^{15}N_{14}N^{l6}O have been recorded with the Fourier transform interferometer of Laboratoire Aim\’{e} Cotton, Absorption path lengths ranging from 10M to 50M were employed with gas pressures of 1T to 100T for the normal form and equal to 3T for the isotopes. The rotational analysis of the bands was performed with a line identification program written for IBM 370/168 computer. Forty-eight Levels of 14N216O^{14}N_{2}^{16}O^{*} twenty-eight levels for each isotopic species were analyzed. Several Local Coriolis resonances have been found in the course of the analysis. These data are used in the determination of the potential function with the programs of A. Chedin and Z, Cilha for linear XYZ molecules

    LOW LYING ELECTRONIC STATES OF THE BaI MOLECULE

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    Author Institution: Universidade Federal Fluminense; Laboratoire Aim\'e Cotton, B\^at 505, Campus d'Orsay 91405, Orsay Cedex, France, Laborat\'orio de Espectroscopia e Laser, Universidade Federal FluminenseThe first five electronic states of the BaI molecule, as well as the G electronic state of the same molecule, were investigated using Thermal Emission (TE), Laser Induced Fluorescence (LIF) and Fourier Transform Spectroscopy (FTS) techniques. The LIF visible and infrared spectra were obtained by using the Ti:sapphire, dye and second harmonic of Ti:sapphire single-mode lasers and the Ar+Ar^{+} and Kr+Kr^{+} multi-mode lasers as excitation sources. Previously recorded data, taken from C. A. Leach, A. A. Tsekouras, and R. N. Zare (J. of Mol. Spectrosc., 153, 59-72 (1992)) were combined with the present work data. Accurate and improved molecular constants for the X2Σ+X^{2}\Sigma^{+}, B2Σ+B^{2}\Sigma^{+}, A2ΔA^{\prime 2}\Delta, A2ΠA^{2}\Pi, C2ΠC^{2}\Pi and D2Σ+D^{2}\Sigma^{+} states and sixteen term values of the G2Σ+G^{2}\Sigma^{+} state were derived from a simultaneous treatment of the whole data set (12,684 transitions) with a standard deviation of 3.26×103cm13.26\times 10^{-3} cm^{-1}. (R. F. Gutterres, C. E. Fellows, J. Verg\`es, and C. Amiot (J. of Mol. Spectrosc., 206, 1-11 (2001))

    Les orgues à bouche sheng du musée du Quai Branly: Pour une anthropologie des instruments comme trésors

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    First identification and description of the mouth organs sent by Amiot to Bertin in 1776 and discovered by the author at the Musée du Quai Branly (Paris)Premières identification et description des instruments envoyés par Amiot à Bertin en 1776 et retrouvés par l'auteur au Musée du Quai Branl

    Les orgues à bouche sheng du musée du Quai Branly: Pour une anthropologie des instruments comme trésors

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    First identification and description of the mouth organs sent by Amiot to Bertin in 1776 and discovered by the author at the Musée du Quai Branly (Paris)Premières identification et description des instruments envoyés par Amiot à Bertin en 1776 et retrouvés par l'auteur au Musée du Quai Branl

    DOPPLER-FREE STUDY OF THE TiO MOLECULE

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    a^{a} C. A***io***, E.M. Azaroual, P. Luc and R. Vetter, J. Chem. Phys., 102, 4375 (1995). b^{b} C. Amiot, M. Cheikh, P. Luc and R. Vetter, J. Mol. Spectroscopy, 179, 159 (1996).Author Institution: Laboratoire Aim\'{e} Cotton (CNRS UPR3321), Campus d'OrsayWe have studied the yellow-orange absorption spectrum of the TiO molecule by use of a Doppler-free spectroscopy experiment in which a cw tunable laser beam crosses an effusive beam of titanium monoxide. Thousands of wavenumbers belonging to the B3ΠX3Δ(10)B^{3}\Pi - X^{3} \Delta(1-0) and c1Φa1Δ(00)c^{1}\Phi -a^1 \Delta(0-0) bands have been measured to an accuracy of 103cm110^{-3} cm^{-1} and interpreted in terms of molecular constants. For the first bandaband^{a}, analysis of fine structure and A-doubling shows that the electronic structure of the B3ΠB^{3}\Pi state must be revisited. For the second bandbband^{b}, electronic interactions with distant vibrational levels of the c3Δc^{3} \Delta state must be considered to assign high rotational levels. Analysis of the spectra due to the five isotopes of titanium is on the tracks
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