48 research outputs found

    Ocean acidification : a critical emerging problem for the ocean sciences

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    Author Posting. © Oceanography Society, 2009. This article is posted here by permission of Oceanography Society for personal use, not for redistribution. The definitive version was published in Oceanography 22 no. 4 (2009): 16-25.Over a period of less than a decade, ocean acidification—the change in seawater chemistry due to rising atmospheric carbon dioxide (CO2) levels and subsequent impacts on marine life—has become one of the most critical and pressing issues facing the ocean research community and marine resource managers alike. The objective of this special issue of Oceanography is to provide an overview of the current scientific understanding of ocean acidification as well as to indicate the substantial gaps in our present knowledge. Papers in the special issue discuss the past, current, and future trends in seawater chemistry; highlight potential vulnerabilities to marine species, ecosystems, and marine resources to elevated CO2; and outline a roadmap toward future research directions. In this introductory article, we present a brief introduction on ocean acidification and some historical context for how it emerged so quickly and recently as a key research topic.We thank the National Science Foundation (NSF), National Oceanic and Atmospheric Administration (NOAA), and National Aeronautics and Space Administration (NASA) for research support on ocean acidification. We specifically acknowledge grants supporting the OCB Project Office (NSF OCE-0622984, NSF OCE-0927287, and NASA NNX08AX01G). Richard A. Feely was supported by the NOAA Climate Program under the Office of Climate Observations (Grant No. GC04-314 and the Global Carbon Cycle Program (Grant No. GC05-288)

    The impact of the North Atlantic Oscillation on the uptake and accumulation of anthropogenic CO2 by North Atlantic Ocean mode waters

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    Author Posting. © American Geophysical Union, 2011. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Global Biogeochemical Cycles 25 (2011): GB3022, doi:10.1029/2010GB003892.The North Atlantic Ocean accounts for about 25% of the global oceanic anthropogenic carbon sink. This basin experiences significant interannual variability primarily driven by the North Atlantic Oscillation (NAO). A suite of biogeochemical model simulations is used to analyze the impact of interannual variability on the uptake and storage of contemporary and anthropogenic carbon (Canthro) in the North Atlantic Ocean. Greater winter mixing during positive NAO years results in increased mode water formation and subsequent increases in subtropical and subpolar Canthro inventories. Our analysis suggests that changes in mode water Canthro inventories are primarily due to changes in water mass volumes driven by variations in water mass transformation rates rather than local air-sea CO2 exchange. This suggests that a significant portion of anthropogenic carbon found in the ocean interior may be derived from surface waters advected into water formation regions rather than from local gas exchange. Therefore, changes in climate modes, such as the NAO, may alter the residence time of anthropogenic carbon in the ocean by altering the rate of water mass transformation. In addition, interannual variability in Canthro storage increases the difficulty of Canthro detection and attribution through hydrographic observations, which are limited by sparse sampling of subsurface waters in time and space.We would like to acknowledge funding from the NOAA Climate Program under the Office of Climate Observations and Global Carbon Cycle Program (NOAA‐NA07OAR4310098), NSF (OCE‐0623034), NCAR, the WHOI Ocean Climate Institute, a National Defense Science and Engineering Graduate Fellowship and an Environmental Protection Agency STAR graduate fellowship. NCAR is sponsored by the National Science Foundation

    Ocean acidification : present conditions and future changes in a high-CO2 world

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    Author Posting. © Oceanography Society, 2009. This article is posted here by permission of Oceanography Society for personal use, not for redistribution. The definitive version was published in Oceanography 22 no. 4 (2009): 36-47.The uptake of anthropogenic CO2 by the global ocean induces fundamental changes in seawater chemistry that could have dramatic impacts on biological ecosystems in the upper ocean. Estimates based on the Intergovernmental Panel on Climate Change (IPCC) business-as-usual emission scenarios suggest that atmospheric CO2 levels could approach 800 ppm near the end of the century. Corresponding biogeochemical models for the ocean indicate that surface water pH will drop from a pre-industrial value of about 8.2 to about 7.8 in the IPCC A2 scenario by the end of this century, increasing the ocean’s acidity by about 150% relative to the beginning of the industrial era. In contemporary ocean water, elevated CO2 will also cause substantial reductions in surface water carbonate ion concentrations, in terms of either absolute changes or fractional changes relative to pre-industrial levels. For most open-ocean surface waters, aragonite undersaturation occurs when carbonate ion concentrations drop below approximately 66 μmol kg-1. The model projections indicate that aragonite undersaturation will start to occur by about 2020 in the Arctic Ocean and 2050 in the Southern Ocean. By 2050, all of the Arctic will be undersaturated with respect to aragonite, and by 2095, all of the Southern Ocean and parts of the North Pacific will be undersaturated. For calcite, undersaturation occurs when carbonate ion concentration drops below 42 μmol kg-1. By 2095, most of the Arctic and some parts of the Bering and Chukchi seas will be undersaturated with respect to calcite. However, in most of the other ocean basins, the surface waters will still be saturated with respect to calcite, but at a level greatly reduced from the present.S. Cooley and S. Doney acknowledge support from NSF ATM-0628582. Richard A. Feely was supported by the NOAA Climate Program under the Office of Climate Observations (Grant No. GC04-314 and the Global Carbon Cycle Program (Grant No. GC05-288)

    Comparison of CO2 dynamics and air-sea exchange in differing tropical reef environments

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    Author Posting. © The Author(s), 2013. This is the author's version of the work. It is posted here by permission of Springer for personal use, not for redistribution. The definitive version was published in Aquatic Geochemistry 19 (2013): 371-397, doi:10.1007/s10498-013-9214-7.Note from corresponding author: authors Feely and Shamberger were added after the initial submission, but before the final submission.An array of MAPCO2 buoys, CRIMP-2, Ala Wai, and Kilo Nalu, deployed in the coastal waters of Hawaii have produced multiyear high temporal resolution CO2 records in three different coral reef environments off the island of Oahu, Hawaii. This study, which includes data from June 2008-December 2011, is part of an integrated effort to understand the factors that influence the dynamics of CO2-carbonic acid system parameters in waters surrounding Pacific high island coral reef ecosystems and subject to differing natural and anthropogenic stresses. The MAPCO2 buoys are located on the Kaneohe Bay backreef, and fringing reef sites on the south shore of O’ahu, Hawai’i. The buoys measure CO2 and O2 in seawater and in the atmosphere at 3-hour intervals, as well as other physical and biogeochemical parameters (CTD, chlorophyll-a, turbidity). The buoy records, combined with data from synoptic spatial sampling, have allowed us to examine the interplay between biological cycles of productivity/respiration and calcification/dissolution and biogeochemical and physical forcings on hourly to inter-annual time scales. Air-sea CO2 gas exchange was also calculated to determine if the locations were sources or sinks of CO2 over seasonal, annual, and interannual time periods. Net annualized fluxes for CRIMP-2, Ala Wai, and Kilo Nalu over the entire study period were 1.15 mol C m-2 yr-1, 0.045 mol C m-2 yr-1, and -0.0056 mol C m-2 yr-1, respectively, where positive values indicate a source or a CO2 flux from the water to the atmosphere, and negative values indicate a sink or flux of CO2 from the atmosphere into the water. These values are of similar magnitude to previous estimates in Kaneohe Bay as well as those reported from other tropical reef environments. Total alkalinity (AT) was measured in conjunction with pCO2 and the carbonic acid system was calculated to compare with other reef systems and open ocean values around Hawaii. These findings emphasize the need for high-resolution data of multiple parameters when attempting to characterize the carbonic-acid system in locations of highly variable physical, chemical, and biological parameters (e.g. coastal systems, reefs).This work was supported in part by a grant/cooperative agreement from the National Oceanic and Atmospheric Administration, Project R/IR-3, which is sponsored by the University of Hawaii Sea Grant College Program, SOEST, under Institutional Grant No. NA09OAR4170060 from NOAA Office of Sea Grant, Department of Commerce.2014-11-0

    Plastics in the automotive industry /

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    A survey of the role of plastics materials in the motor industry. It discusses progress in the different sectors of automotive engineering, and the possible effect of economic and environmental pressures on the growth of the plastics contribution. Emphasis is given to materials selection and the author explains how a material can be 'right' or 'wrong' for a particular job - and what extraneous factors could change things."SAE order number: R-147"--Title page verso.Includes index.Online resource; title from PDF title page (ebrary, viewed February 07, 2014).A survey of the role of plastics materials in the motor industry. It discusses progress in the different sectors of automotive engineering, and the possible effect of economic and environmental pressures on the growth of the plastics contribution. Emphasis is given to materials selection and the author explains how a material can be 'right' or 'wrong' for a particular job - and what extraneous factors could change things.Front Cover; Plastics in the Automotive Industry; Copyright Page; Table of Contents; Preface; Acknowledgements; Chapter 1. Materials for cars; Plastics usage; History of automotive plastics; Why plastics?; Problems with plastics; Chapter 2. Understanding plastics; Classifying plastics; Composites; Processes; Designing with plastics; Chapter 3. Choosing plastics; The decisive properties; Characteristics of the polymer groups; Materials selection; Requirements for different application areas; Chapter 4. Interiors; General; Plastics surfaces; Plastics structures and panel applications.Structural and mechanical componentsChapter 5. Exteriors; Overview; Body panels and structures; The painting problem; Bumpers; Other exterior components; Bibliography; Books; Review papers and monographs; Conference papers; Technical and promotional literature; Chapter 6. Engine, power train and chassis; The engine compartment; The cooling system; Underbonnet stctures; Transmission; Engine 'hang-on' parts; Engine interiors; Composite engines; Suspension; Steering; Brakes; Fuel tanks; Chapter 7. EIectrics; Ignition; Battery boxes; Circuitry; lighting and instrumentation.Other electrical equipmentElectronics; Chapter 8. Recycling; Recycling: an unavoidable issue; The scrap problem; The alternatives for plastics; The energy aspect; Recycling composites; New recycling initiatives; Chapter 9. The future and automotive plastics; Design trends and legislation; Supplier involvement; Safety; Fuel economy and the energy equation; Environmental pollution; Plastics and future design; Appendix 1: Polymer abbreviations and trade names; Appendix 2: PC based polymer databases; Index.Elsevie

    Efeito da temperatura em diferentes aspectos da fotossíntese de Lithothamnion superpositum (Corallinales, Rhodophyta

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    TCC(graduação) - Universidade Federal de Santa Catarina. Centro de Ciências Biológicas. Biologia.As mudanças climáticas globais provocarão conseqüências físicas e químicas no ambiente marinho. Dentre elas, possíveis variações na temperatura promovem alterações fisiológicas alterando o comportamento respiratório e fotossintético e, assim as taxas de crescimento de organismos fitobênticos, especialmente. Dentre estes organismos, algas calcárias têm grande importância ecológica, com fornecimento de nicho e substrato para outras algas e invertebrados. Nesse grupo os efeitos de alterações da temperatura da água do mar são potencialmente ainda mais preocupantes, pois além de serem organismos chaves para o ambiente marinho, estão intimamente relacionadas ao ciclo do carbono. O presente trabalho verificou mudanças na resposta fotossintética de Lithothamnion superpositum (Corallinales, Rhodophyta) relacionadas à variação de temperatura. Assim, espécimes trazidos da Rebio do Arvoredo (22º C) foram incubados por 24h, a 15°C, 20°C, 25°C e 30°C. Por sete dias consecutivos as taxas de transferência de elétrons (ETR) e a fluorescência da Clorofila a do Fotossistema II foram aferidos com o fluorímetro DIVING-PAM. Também foram observados o balanço de oxigênio dissolvido e pH mantendo as plantas e controles no claro e escuro. Após esse tempo, foram extraídos os pigmentos (Aloficocianina, Ficocianina, Ficoeritrina e Clorofila). Os resultados evidenciam que as plantas mantidas a 20, 25 e 35°C, tiveram pouca diferença em relação à Pmáx, Ik e à β. Em relação à α não houve diferença significativa entre elas. Maiores concentrações de pigmentos foram encontradas nas plantas mantidas a 25°C. Pode-se sugerir, portanto, que as melhores temperaturas para as algas dessa espécie são as mais altas, encontradas nas regiões tropicais

    Spatial variability and decadal trend of the oceanic CO2 in the western equatorial Pacific warm/fresh water

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    Data of the partial pressure of carbon dioxide in surface seawater (pCO2sw) collected in the western equatorial Pacific (144°E - 160°W, 5°S - 5°N) since the 1980's have been used to determine the spatial variability and decadal trends in pCO2sw. A total of 109 cruises since 1983, including 30 cruises since 1990 with total dissolved inorganic carbon (TCO2) measurements, are synthesized for this zone. The western equatorial Pacific warm/fresh surface water where T ≥ 29.0 ℃ and S ≤ 34.8 is nitrate-depleted and it is moderately supersaturated with CO2 (0 < ΔpCO2 (= pCO2sw - pCO2air) / μatm < 40). A slight CO2 undersaturation (-20 < ΔpCO2 / μatm < 0) was also observed on many cruises where thin, low density layers (σt < 21.4) capped barrier layers. The undersaturation may result from net biological uptake of CO2 due to nitrogen fixation. Excluding the data in such a extremely light waters, we determined changes in the linear growth rate of pCO2sw of +0.3 ± 1.3 μatm year^[-1] for 1985 - 1990, +2.2 ± 0.7 μatm year^[-1] for 1990 - 1999, and -0.2 ± 1.0 μatm year^[-1] for 1999 - 2004. The rate of increase was +1.5 ± 0.2 μatm year^[-1] for the entire period (1985 - 2004). The variation in the rate of increase of pCO2sw is fairly consistent with the change in the rate of increase of salinity-normalized TCO2 from +2.1 ± 0.4 μmol kg^[-1] year^[-1] during 1992 - 1999 to +0.4 ± 0.9 μmol kg^[-1] year^[-1] during 1999 - 2004. These changes are anti-correlated with the decadal variation in the geostrophic mass transport from subtropics of both hemispheres into the equatorial zone in the Pacific

    Life-years-gained from population risk factor changes and modern cardiology treatments in Ireland

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    Background: Coronary heart disease (CHD) mortality rates in Ireland have halved since the mid-1980s, and adult life expectancy has also steadily improved. This study estimated the life-years-gained by CHD treatments and by changes in cardiovascular risk factor levels. Methods: A previously validated Irish IMPACT CHD mortality model was used to integrate large amounts of data on (i) patient numbers, (ii) treatment uptake, (iii) risk factor trends, (iv) effectiveness of cardiology treatments and risk factor reductions, and (v) median survival in patients with and without CHD, all stratified by age and sex. Results were tested in rigorous sensitivity analyses. Results: There were 3763 fewer CHD deaths than expected in 2000 compared with the base year, 1985. This resulted in ∼44 060 life-years-gained among people aged 25-84. Specific medical and surgical treatments given in 2000 for CHD patients together gained ∼14 505 life-years. Population changes in cholesterol and smoking levels accounted for some 32 705 life-years-gained, 66% from reductions in cholesterol alone. Adverse changes in obesity and diabetes resulted in a loss of ∼3670 life-years. Conclusions: Use of modern cardiology treatments in Ireland from 1985 to 2000 gained many thousands of life-years. However, twice as many life-years were generated by relatively modest reductions in major risk factors. Effective policies, such as the promotion of healthy diets, and weight reduction, together with the recent nationwide workplace smoking ban, will be essential to maintain and further enhance health gain. \ua9 The Author 2006. Published by Oxford University Press on behalf of the European Public Health Association. All rights reserved
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