65 research outputs found

    Pengaruh Variasi Suhu dan Perbandingan Massa NaOH pada Sintesis Karboksimetil k-Karagenan (CMKC) menggunakan Asam Trikloroasetat (TCA)

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    ABSTRAK   Fadilah, Mira . 2018. Pengaruh Variasi Suhu dan Perbandingan Massa NaOH pada Sintesis Karboksimetil k-Karagenan (CMKC) dengan Asam Trikloroasetat (TCA). Skripsi, Jurusan Kimia, Fakultas Matematika dan Ilmu Pengetahuan Alam, Universitas Negeri Malang. Pembimbing: (I) Dr. Irma Kartika K, S.Si., M.Si., (II) Dr. Siti Marfu’ah, M.S.   Kata Kunci: k-karagenan, karboksimetilasi, suhu, NaOH, alkalisasi, fisikokimia. Karboksimetil kappa-Karagenan (CMKC) merupakan produk hasil karboksimetilasi k-karagenan. Konversi gugus hidroksil menjadi gugus karboksimetil pada proses karboksimetilasi berpengaruh pada karakter k-karagenan antara lain viskositas, kelarutan dan kemampuan mengikat air. Banyaknya gugus –OH yang dapat disubstitusi dinyatakan sebagai derajat substitusi (DS). Peningkatan nilai DS dapat dilakukan dengan cara mengoptimasi suhu alkalisasi serta massa NaOH yang ditambahkan pada proses karboksimetilasi. Penelitian ini adalah penelitian eksperimental dengan tujuan mengoptimasi metode pembuatan karboksimetil kappa-karagenan yang dilakukan dengan cara memvariasi suhu alkalisasi dan massa natrium hidroksida yang ditambahkan.  Penelitian dilakukan dalam dua tahap, yaitu (1) pembuatan karboksimetil k-karagenan (CMKC) dengan beberapa variasi jumlah NaOH dan suhu reaksi pada tahap alkalisasi, (2) karakterisasi sifat fisikokimia produk yang dihasilkan meliputi nilai derajat substitusi (DS), FTIR, kadar air, kelarutan, kemampuan swelling dan viskositas. Hasil penelitian ini adalah karboksimetil k-karagenan yang disintesis menggunakan agen eterifikasi asam trikloroasetat (TCA) ditandai dengan munculnya serapan FTIR pada bilangan gelombang sekitar 1650 cm-1 dan 1410 cm-1 (serapan gugus karbonil). Selain itu juga ditunjukkan dengan perubahan sifat fisikokimia yang berbeda dari molekul awalnya. Suhu alkalisasi optimum pada proses karboksimetilasi k-karagenan adalah 40oC dengan nilai DS yang diperoleh adlaah 0,87, kadar air 0,9650%, kelarutan dalam air sebesar 8,83 g/L dengan % terlarut 87,5124 %, suhu gelling pada 60oC serta viskositas sebesar 3 cP.  Peningkatan suhu alkalisasi dapat menurunkan nilai DS, juga berpengaruh pada kadar air dan kelarutan CMKC yang dihasilkan. Sedangkan massa NaOH optimum yang ditambahkan pada proses karboksimetilasi k-karagenan untuk memperoleh nilai DS yang paling besar (1,6) adalah 6,0011 g, dengan kadar air sebesar 1,0350%, kelarutan dalam air sebesar 9,55 g/L dengan %terlarut 95,1195%, suhu gelling pada 70oC serta viskositas sebesar 3,5 cP.  Penambahan yang lebih banyak dari 6,0011 g NaOH dapat menurunkan nilai DS produk dikarenakan semakin banyaknya produk samping yang terbentuk

    The ecological and socio-economic impacts of the lionfish invasion in the Southern Caribbean

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    The Indo-Pacific lionfish (Pterois volitans) is a venomous, voracious predator with a high dispersal capactity. In the space of 30 years, it has infiltrated an array of habitats, inhabited a depth range of > 300 m and exceeded the size and density reported in the native range, demonstrating the difficulty of effective lionfish management. If left unmanaged, lionfish pose a significant, but still uncertain, threat to Caribbean ecosystems thereby warranting the need for effective and efficient, tailored management schemes. Since their confirmation in Bonaire and Curacao in October 2009, an extensive monitoring program was established by the author in collaboration with CIEE Research Station Bonaire whereby >11,000 lionfish were documented and their population dynamics, reproductive and feeding ecology analysed in relation to local management strategies. The types of education and management strategies applied were evaluated based on their benefits and limitations to make recommendations for areas early in the invasion timeline. Finally efficiency of removal activities in Bonaire and Curacao were assessed and suggestions made on when and how often to remove lionfish. Socio-economic questionnaires were conducted to determine the profile and motivations of lionfish hunters, and a cost-benefit-analysis performed to assess economic effects of the invasion. Knowledge gained from this research is beneficial for tailoring future management through recommendations of which lionfish to remove, how often and which tools, methods and groups are most effective. This work revealed that dusk was the most effective time for lionfish removal and that by focusing removal efforts in the 15 – 25m depth range, this allowed for the depletion of a higher proportion of individuals in the 101 - 200mm size class. This research also revealed how valuable a prepared and rapid response to management was and how important a dedicated volunteer removal effort is to controlling the lionfish populations in the future

    EFEKTIVITAS SISTEM PEMBAYARAN PAJAK MENGGUNAKAN MPN-G2 DI BANK BRI KCP SUKANAGARA

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    This Final Project Report was prepared by Rifani Aria Fadilah, Student Identification Number 1841211017, with the title "Effectiveness of the Tax Payment System Using MPN-G2 at Bank BRI KCP Sukanagara" which was compiled under the guidance of Mrs. Hj Eris Darsawati, M.M. and Mrs. Risma Nurmilah, M.Si. This report was prepared based on the results of research conducted by the author at Bank BRI KCP Sukanagara. This research was proposed to find out the State Revenue Module, procedures and effectiveness of the tax payment system using the Second Generation State Revenue Module (MPN-G2). The author uses descriptive research methods in compiling this Final Report. The data collection technique used in this research is through field studies and literature studies. Field studies carried out are observations, literature studies used are through book references, government regulations, journals, and trusted internet sites. Based on the discussion on the Effectiveness of the Tax Payment System Using MPN-G2 at Bank BRI KCP Sukanagara, the authors can conclude that tax is one of the most important state revenues for the State Budget to finance various state expenditures. In supporting the recording of state revenues, MPN-G2 is applied to make it easier for the public to pay taxes online. This study found that the effectiveness of state revenues with the implementation of the MPN-G2 system was quite effective in terms of time so that it was faster to deposit state revenues. However, in terms of delegation to the State Treasury, it is still the same as the old system by waiting for transactions to be collected in advance within a predetermined period of time after which they are transferred to the State Treasury

    Perancangan Sistem Informasi Absensi dengan SMS Gateway Berbasis Web

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    Internet provides the opportunity to create markets, and serves customers in a way that is unimaginable until now., this directive establishes the scope of Internet commerce, showing the opportunities and challenges, and provides insight into the strategies that successful entrepreneurs. Based on the above facts, in this thesis the author discusses about how to design an aplication. Here the authors analyze and design the structure of the application system to be built and used is the programming language and the integration of both. This system is developed using PHP programming language tailored to the needs of the design process of this system. The thing that is contained in this system include a variety of information such as store information,From the results of this research, it can be concluded that the system information the student and computerized well.Internet memberikan kesempatan untuk menciptakan pasar, dan melayani pelanggan dengan cara yang tak terbayangkan sampai sekarang menunjukkan peluang dan tantangan, dan memberikan wawasan ke dalam strategi pengusaha yang berhasil. Berdasarkan fakta di atas, pada penulisan tugas akhir ini Penulis membahas tentang bagaimana cara merancang sebuah aplikasi Sistem informasi Absensi Dengan sms gateway berbasis web. Disini penulis menganalisa dan merancang struktur system aplikasi yang akan dibangun dan yang digunakan yaitu bahasa pemrograman serta integrasi dari keduanya. Sistem ini dikembangkan dengan menggunakan bahasa pemrograman PHP yang disesuaikan dengan kebutuhan dalam proses perancangan system ini. Adapun hal yang terdapat dalam system ini meliputi berbagai informasi seperti informasiabsensi yang disampaikan pada orang tua. Dari hasil penelitian tugas akhir ini, dapat disimpulkan bahwa system aplikasi Sistem informasi Absensi Dengan sms gateway berbasis web dan terkomputerisasikan dengan baik.106 HalamanKertas Karya Diplom

    PROSES PENYELESAIAN PERKARA KASUS KEKERASAN PADA ANAK (STUDI KASUS NOMOR REGISTER PERKARA 183/PID.SUS/2024/PN.MLG)

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    This research aims to provide a juridical analysis of the resolution of child abuse cases, with a particular focus on the case registered under Case Number 183/Pid.Sus/2024/Pn.Mlg. The study explores the application of criminal law in addressing child abuse, encompassing the investigation, prosecution, and trial phases.The research adopts an empirical juridical methodology, combining legal approaches with field-based observations. Primary data were collected through direct observation of the trial proceedings for Case Number 183/Pid.Sus/2024/Pn.Mlg. The author also conducted interviews with key stakeholders, including the presiding judge overseeing the case and the legal counsel at the firm where the author interned. These interviews were designed to gather comprehensive insights into the handling of child abuse cases. Additionally, primary data were supplemented by examining the official court ruling, Decision Number 183/Pid.Sus/2024/Pn.Mlg. To enhance the primary data, the author also utilized secondary data, which included various legal materials relevant to the research topic. These secondary materials encompassed the Indonesian Penal Code (KUHP), Law Number 35 of 2014 on Child Protection, and other legislation governing special criminal law related to child protection. Furthermore, additional legal sources, such as legal doctrines, journals, articles, and other relevant secondary legal materials, were used to enrich the study. This research is expected to contribute to the development of more proactive and responsive legal policies regarding child abuse issues

    The Evolution of Zoonosis-Related Studies in Indonesia, 1977-2023: Bibliometric Analysis Concepts

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    Various zoonotic diseases have been reported as epidemics throughout the world, including in Indonesia. Various studies have been conducted related to gaps in knowledge, especially on disease distribution, etiology, pathogens, hosts, vector biology, dynamics, cycle of transmission, predisposing factors, and risk factors. To find out the dynamics of zoonotic disease study and research in Indonesia, a study was conducted to report a literature analysis that focused on bibliometric analysis of the Scopus database and VOSviewer software to create a visualization map that identified how the evolution of zoonotic diseases studies from 1977-2023 in Indonesia. In co-occurrence analysis, two units of analysis are used, namely "author keywords" and "index keywords" in VOSviewer. It showed that studies related to zoonoses in Indonesia tend to increase every year with a significant increase in 2020 and 2022. Document types are dominated by articles (72%) with subjects or research areas related to “medicine†(29%). From the "author keywords" analysis unit, the words "zoonosis" and "Indonesia" were the words that appeared the most. Meanwhile, from “index keywords†six clusters were found with the word "human" "animals", and "zoonosis" being the word that appears the most in the analysis of the studies conducted

    Tindakan Bullying di Sekolah : Perspektif Sosiologi Pendidikan

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    Bullying merupakan suatu kenyataan universal yang ada sepanjang sejarah peradaban manusia. Pada dasarnya memang bullying sudah lama dikenal, terjadi dan berkembang mengikuti perkembangan zaman dan peradaban manusia. Tindakan bullying dapat dilakukan oleh siapa saja, di mana saja, kapan saja dan dengan berbagai bentuk. Tindakan bullying ini termasuk ke dalam penyimpangan dan kenalan remaja yang dilakukan oleh para pelajar. Teori kontrol oleh Hirski menyatakan bahwa penyimpangan dan bahkan kriminalitas atau pelaku kriminal merupakan bukti kegagalan kelompok-kelompok sosial konvensional seperti keluarga, sekolah atau kelompok-kelompok dominan lainnya dalam mengikat individu agar tetap conform. Untuk itu diperlukan kontrol/pengendalian dari keluarga yaitu orang tua, pihak sekolah dan komunitas ekstrakulikuler, sehingga kenakalan pelajar tidak terjadi lagi dalam dunia pendidikan. Sosiologi pendidikan sebagai suatu kajian yang mempelajari hubungan antara masyarakat, yang di dalamnya terjadi interaksi sosial dengan pendidikan. Sosiologi mencakup masyarakat baik secara makro (masyarakat keseluruhan), meso (proses belajar di sekolah), hingga bagian masyarakat terkecil yaitu mikro (individu di dalam masyarakat). Sekolah sebagai salah satu institusi pendidikan juga dipercaya oleh masyarakat sebagai proses pembudayaan sekaligus wahana pengembangan potensi kemanusiaan. Namun sayangnya dalam sejumlah kasus, justru menunjukkan bahwa sekolah dapat menjadi tempat berlangsungnya verbal dan nonverbal, seperti bullying. Salah satu kejadian yang sekarang sedang menjadi perhatian di dalam dunia pendidikan adalah terkait bullying di sekolah, bullying di sekolah adalah masalah yang sering terjadi dan berdampak buruk pada tatanan sosial di sekolah. Tujuan dari adanya penelitian ini adalah untuk mendeskripsikan tentang bullying di Sekolah dalam tinjauan perspektif Sosiologi pendidikan. Metode yang digunakan dalam penelitian ini adalah menggunakan studi kasus dan literature review. Dalam konteks sosiologi pendidikan, bullying dianggap sebagai fenomena sosial yang terjadi di lingkungan sekolah. Sosiologi pendidikan juga menyempurnakan pentingnya peran sekolah, keluarga dan masyarakat dalam mencegah bullying. Baik keluarga, Sekolah maupun lingkungan masyarakat dapat memberikan pendidikan dan pelatihan tentang pentingnya nilai akhlak mulia, moral, sopan santun, toleransi, penghargaan terhadap yang lebih tua dan kepada sesama. Beberapa kontrol sosial dan upaya untuk mengatasi perilaku bullying yang dapat diberikan oleh sekolah yaitu dengan cara membuat konsultasi layanan konseling dan melakukan pengawasan dengan ketat, memberikan teguran dan ancaman, dan bisa juga dengan dengan cara pemberian sanksi

    TUGAS PRAMUSAJI DI CAFE RAMA MESANGAN WETAN SIDOARJO

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    The purpose of this Final Project is to find out how the task of the waitress in Cafe Rama Mesangan Wetan Sidoarjo. The author made observations on the task of the waitress at Cafe Rama Mesangan Wetan Sidoarjo. The author can draw the conclusion that the waiter at the Cafe Rama Mesangan Wetan Sidoarjo has been carrying out duties according to the rules that have been set, ranging from welcoming guests, service, and serving food to guests. The duties of the waiter in Cafe Rama are in accordance with the theoretical basis, but not all theories can be implemented in Cafe Rama because Cafe Rama is a small-scale cafe. Keywords: cafe, duties waiter

    APLIKASI TINDAKAN PEMBERIAN DIET BUBUR TEMPE TERHADAP FREKUENSI BUANG AIR BESAR PADA An.N USIA 6 TAHUN DENGAN GANGGUAN SISTEM PENCERNAAN DIARE DI DESA SAYANG KECAMATAN CIANJUR KABUPATEN CIANJUR

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    Diarrhea is one of the main causes of morbidity and mortality in children around the world, which causes one billion cases of illness and 3-5 million deaths each year. This diarrheal disease is experienced by many children in growing countries, aged 0-3 years. The purpose of this study was to provide nursing care for diarrhea sufferers, especially in the provision of Tempe Porridge Diet on the Frequency of BAB in Children with Digestive System Disorders (Diarrhea). Data obtained by interview and direct observation showed that after the intervention of the application of the tempeh porridge diet, there appeared to be a decrease in the frequency of the client's bowel movements. The author hopes that all health services, both doctors, nurses and midwives can further improve the knowledge and quality of human resources as medical services for the community, especially for clients with diarrhea and suggest that communication between medical members should be improved again

    KETERBELAHAN HASRAT KEBEBASAN MASYARAKAT TURKISTAN DALAM NOVEL LAYALI TURKISTAN

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    Desire always accompanies the subject throughout his life. Subjects always identify something outside of themselves to find a complete identity. From these desires the subject has a need (need), and a desire that becomes a desire. However, symbolic reality necessitates the existence of a split and divided subject, because after all desire involves consciousness (ego) which is disrupted by the desires of others. This reality also occurs in the novel Layālī Turkistān by Najīb al-Kailānī which describes the free structure of Turkistan Society as a whole, and then crumbled when China and Russia came to colonize. The process of subject division in literary texts represents the author, how the author cannot be separated in the text process. This study aims to see how the divided freedom of the Turkistan Society occurs in the novel Layālī Turkistān.This study uses a descriptive qualitative research method with Lacanian psychoanalysis reading, where the reading is to see the divided freedom of the Turkistan Society in the novel Layālī Turkistān and see the desires that shape the subject of the novel character who is also the subject of the author himself. This research also needs to use the historical reading of the author's subject as a whole.From the novel Layālī Turkistān, using the psychoanalytic perspective of Jacques Lacan, the researcher finds how the subjects in the novel are underprivileged due to the colonial acts carried out by China and Russia to take advantage of Turkistan. The resistance of desire that every character in Layālī Turkistān's novel does is a re-satisfaction of the jouissance that has been captured by others in him. The action is a choice that they identify continuously to find the 'ideal ego'. The discourse on the divided desire for freedom of the Turkistan Society in the novel is also a form of resistance by the author Najīb al-Kailānī to fulfill his desires. It can be seen how his background and concern for Muslims around the world are trying to be discriminated against by communist movements
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