65,797 research outputs found

    C. Cramer Florist, Interior of Store

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    Image shows the display of flowers inside the Cramer flower shop.This image included in both the Shipler and Classified Photo Collections

    Measurement of the ratio of prompt χ c to J / ψ production in pp collisions at √s = 7 TeV

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    The prompt production of charmonium χ c and J / ψ states is studied in proton-proton collisions at a centre-of-mass energy of √s = 7 TeV at the Large Hadron Collider. The χ c and J / ψ mesons are identified through their decays χ c → J / ψ γ and J / ψ → μ + μ - using 36 pb - 1 of data collected by the LHCb detector in 2010. The ratio of the prompt production cross-sections for χ c and J / ψ, σ (χ c → J / ψ γ) / σ (J / ψ), is determined as a function of the J / ψ transverse momentum in the range 2 < p T J / ψ < 15 GeV / c. The results are in excellent agreement with next-to-leading order non-relativistic expectations and show a significant discrepancy compared with the colour singlet model prediction at leading order, especially in the low p T J / ψ region

    [Carl Eduard Cramer, 1831-1901]

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    Enthält verschiedene Nachrufe aus Zeitungen: Artikel in Neue Zürcher Zeitung vom 28. November 1901 (Autor unbekannt) ; Erinnerungen an Prof. Dr. C. Cramer von J. Hohl (Zeitung unbekannt) ; Professor Dr. Carl Eduard Cramer von C. Schröter in Neue Zürcher Zeitung vom 1. Dezember 190

    [Freundschaftsbuch von Carl Eduard Cramer (1831-1901)] : 78 Porträts / 61 J.J. Hanhart s/m C. Cramer z. fr. Er

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    Dedikationssilhouette nach links von J. J. Hanhart, gewidmet Carl Eduard Cramer (1831-1901)Anonyme/r Künstler/inHandschriftliche Widmung in Feder unterhalb des Bildes "J. J. Hanhart s[eine]m C. Cramer z. fr. Er. [i.e.: zur freundlichen Erinnerung]"Aus der Sammlung Carl Eduard Cramer Exemplar der Zentralbibliothek Zürich, Graphische Sammlung und Fotoarchi

    Aegisthus LINNAEUS OF CRAMER 1777

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    AEGISTHUS LINNAEUS OF CRAMER, 1777 Pap[ilio] Eq[ues] Achiv[us] aegistus, Cramer, 1777: 15, 147, pl.106, figs C, D [original plate 72, figs E, E] (incorrect subsequent spelling). China. Papilio Eques Achivus agamemnon, Stoll, 1782b: 3 [No. 25]. Material examined. No potential Cramer specimens located. Identity. Graphium (s.s.) a. agamemnon (Linnaeus, 1758).Published as part of Chainey, John E., 2005, The species of Papilionidae and Pieridae (Lepidoptera) described by Cramer and Stoll and their putative type material in the Natural History Museum in London, pp. 283-337 in Zoological Journal of the Linnean Society 145 (3) on page 292, DOI: 10.1111/j.1096-3642.2005.00184.x, http://zenodo.org/record/543509

    C. Cramer Florist p.2

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    Cramer Floral Company\u27s Christmas window, December 24, 1925.This photo included in both the Shipler and Classified Photo Collections

    Influence of first and second coordination environment on structural Fe(II) sites in MIL-101 for C−H bond activation in methane

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    Divalent iron sites in tri-iron oxo-centered metal nodes in metal−organic frameworks (MOFs) catalyze light alkane oxidation. The first two steps of the reaction sequence, which are also the most energetically demanding ones, are the formation of the active species, Fe(IV)=O, by N2O decomposition and subsequent C−H bond cleavage. We have employed Kohn−Sham density functional methods to explore how modification of the microenvironment around the Fe(II) center can modulate its catalytic activity, akin to what noted in metalloenzymes. We have varied the substituents on the organic linker of the MIL-101(Fe) MOF, as a way to modulate the energy barriers associated with the first two steps of the methane to methanol reaction. The calculations show that varying substituents has a minimal electronic effect on the iron center and its first coordination shell. However, their proximity to the active site can modify the barriers by 20%. Hydrogen bond donors can lower both barriers, such that the resulting Fe(IV)=O species are simultaneously more stable and more reactive than those of the parent MOF. The screening of a large set of systems allowed us to establish rules for the selection of second coordination shell elements to improve the reactivity of oxoferryl-based catalysts: (i) functionality with a low pKa or large positive electrostatic potential, (ii) a distance around 1.5 Å between the oxoferryl and any atom of the ring substituent, and (iii) low conformational flexibility of the added substituent

    Theoretical Models on the Cu2O2 Torture Track. Mechanistic Implications for Oxytyrosinase and Small-molecule Analogs

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    Accurately describing the relative energetics of alternative bis(μ-oxo) and μ-η2:η2 peroxo isomers of Cu2O2 cores supported by 0, 2, 4, and 6 ammonia ligands is remarkably challenging for a wide variety of theoretical models, primarily owing to the difficulty of maintaining a balanced description of rapidly changing dynamical and nondynamical electron correlation effects and a varying degree of biradical character along the isomerization coordinate. The completely renormalized coupled-cluster level of theory including triple excitations and extremely efficient pure density functional levels of theory quantitatively agree with one another and also agree qualitatively with experimental results for Cu2O2 cores supported by analogous but larger ligands. Standard coupled-cluster methods, such as CCSD(T), are in most cases considerably less accurate and exhibit poor convergence in predicted relative energies. Hybrid density functionals significantly underestimate the stability of the bis(μ-oxo) form, with the magnitude of the error being directly proportional to the percentage Hartree−Fock exchange in the functional. Single-root CASPT2 multireference second-order perturbation theory, by contrast, significantly overestimates the stability of bis(μ-oxo) isomers. Implications of these results for modeling the mechanism of C−H bond activation by supported Cu2O2 cores, like that found in the active site of oxytyrosinase, are discussed

    Título: Canonicarum quaestionum utriusque fori tam exterioris quàm interioris animae liber tertius

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    Marca tip. en portSign.: ¶\p4\s, A-2E\p6\s, 2F\p4\s, A-B\p6\s, C\p4\sTexto a dos colSign.: ¶\p4\s, A-Z\p8\s, 2A-2E\p8\s, 2F\p4\s, A-B\p6\s, C\p4\
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