25,143 research outputs found

    LOW TEMPERATURE (20K)(\sim 20K) INTRAMOLECULAR ENERGY TRANSFER IN GAS PHASE EVIDENCED BY LUMINESCENCE OF N2,N+2N_{2}, {N^{+}}_{2}, AND CN.

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    1. E.B. Gordon, A.A.Pelmenev, O.F. Pugachev and V.V.Khmelenko, Chem. Phys. 61(1,2), 35-41, 1981. 2. E.B. Gordon, M.V. Martynenko, A.A. Pelmenev, O.F. Pugachev and V.V. Khmelenko, Khimicheskay Fizika, 13(3), 15-28, 1994, (in Russian).Author Institution: Institute for Energy Problems of Chemical Physics, 1142432, Chernogolovka, Moscow Region, Russia.Gas phase luminescence spectra of N_{2} (1^{+}-system), (N^{+}}_{2} (1^{+}-system), and CN (Red system) in the temperature range 180K - 20K have been studied in the frame of original experimental approach [1] consisting in injection of helium gas jet containing the exposed to HF discharge admixtures under investigation into the cryostat with superfluid helium (T1.5K)(T \sim 1.5K). At low temperatures together with strong suppression of rotational structure the dramatic changes in the vibronic bands intensity (some bands almost completely disappear) are observed [2]. For all vibrational levels from which emission is temperature sensitive there are quasiresonant (ΔE<100cm1)(\Delta {\rm E} < 100 cm^{-1}) vibrational levels belonging to another electronic states of the same species. So the effect has been explained by effective energy transfer between the electronic states induced by collisions with cold helium atoms ([He]1019cm3)([He] \sim 10^{-19} cm^{-3}). The emission bands intensity is determined by mutual disposition of the interacting levels. Its decrease or increase depend on whether exothermic or endothermic, respectively, transition from emitting level to neighboring one. Observed phenomena provide new opportunities for accurate testing the mutual disposition of different electronic states in diatomics as well as for study of intersystem collisional induced processes

    On Some Optimization Problems that Can Be Solved in O(n) Time

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    We consider nine elementary problems in optimization. We simply explore the conditions for optimality as known from the duality theory for convex optimization. This yields a quite straightforward solution method for each of these problems. The main contribution of this paper is that we show that even in the harder cases the solution needs only O(n) time.Accepted author manuscriptDiscrete Mathematics and Optimizatio

    An O(n log n) algorithm for finding dissimilar strings

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    Let SigmaSigma be a finite alphabet and xinSigmanx in Sigma^n. A string yinSigmamy in Sigma^m is said to be kk-dissimilar to xx, if no kk length substring of xx is equal to any kk length substring of yy. We present an O(nlogn)O(n log n) algorithm which on input xinSigmanx in Sigma^n and an integer mleqnm leq n outputs an integer kk and yinSigmamy in Sigma^m such that: - yy is kk-dissimilar to xx. - There does not exist a string zz of length mm which is k1k-1 dissimilar to xx.Technical report LCSR-TR-26

    Tricritical O(n) models in two dimensions

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    We show that the exactly solved low-temperature branch of the two-dimensional O(n) model is equivalent to an O(n) model with vacancies and a different value of n. We present analytic results for several universal parameters of the latter model, which is identified as a tricritical point. These results apply to the range n ?3/2 and include the exact tricritical point, the conformal anomaly, and a number of scaling dimensions, among which are the thermal and magnetic exponents, and the exponent associated with the crossover to ordinary critical behavior and to tricritical behavior with cubic symmetry. We describe the translation of the tricritical model in a Coulomb gas. The results are verified numerically by means of transfer-matrix calculations. We use a generalized ADE model as an intermediary and present the expression of the one-point distribution function in that language. The analytic calculations are done both for the square and the honeycomb lattice.Kavli Institute of NanoscienceApplied Science

    O. N. Malmquist

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    O. N. Malmquist was a political editor for the Salt Lake Tribune, and author of "First One Hundred Years; A History of the Salt Lake Tribune 1871-1971.

    LONG TERM EVOLUTION OF BONE RECONSTRUCTION WITH BONE GRAFT SUBSTITUTES

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    The review involves clinical and experimental data, constitutive modeling, and computational investigations towards an understanding on how mechanical cyclic loads for long periods of time affect damage evolution in a reconstructed bone, as well as, lifetime reduction of bone graft substitutes after advanced core decompression. The outcome of the integrated model discussed in this paper will be how damage growth in femur after advanced core decompression subjected to mechanical cyclic loading under creep and fatigue conditions may be controlled in order to optimize design and processing of bone graft substitutes, and extend lifetime of bone substitutes

    FUNDAMENTAL AND TORSIONAL COMBINATION BANDS OF N2_{2}O-C2_2H2_2 AND N2_{2}O-C2_2D2_2 IN THE N2_{2}O ν1\nu_{1} REGION

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    Author Institution: Department of Physics and Astronomy, University of Calgary; Calgary, AB T2N 1N4, CANADA; Steacie Institute for Molecular Sciences, National Research; Council of Canada, Ottawa, ON K1A 0R6, CANADASpectra of the weakly-bound N2_{2}O-C2_2H2_2 and N2_{2}O-C2_2D2_2 complexes in the region of the N2_{2}O ν1\nu_{1} fundamental band (~2224 cm1^{-1}) are observed in a pulsed supersonic slit jet expansion probed with a tunable diode laser. Two bands are analyzed for each complex: the fundamental (N-N stretch), and a combination involving the intermolecular torsional (out-of-plane bend) vibration. The resulting torsional frequencies are 44.37 and 40.01 cm1^{-1} for the C2_2H2_2 and C2_2D2_2 complexes, respectively. This represents the first observation of the N2_{2}O-C2_2D2_2 isotopomer, and the first direct determination of an intermolecular frequency for nitrous oxide - acetylene

    Multicritical points of the O(N) scalar theory in 2 &lt; d &lt; 4 for large N

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    We solve analytically the renormalization-group equation for the potential of the O(N)-symmetric scalar theory in the large-N limit and in dimensions 2&lt;d&lt;4, in order to look for nonperturbative fixed points that were found numerically in a recent study. We find new real solutions with singularities in the higher derivatives of the potential at its minimum, and complex solutions with branch cuts along the negative real axis. © 2018 The Author

    Self-archiving practice and the influence of publisher policies in the social sciences

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    Authors in different disciplines exhibit very different behaviours on the so-called ‘green’ road to open access, i.e. self-archiving. This study looks at the self-archiving behaviour of authors publishing in leading journals in six social science disciplines. It tests the hypothesis that authors are self-archiving according to the norms of their respective disciplines rather than following self-archiving policies of publishers, and that, as a result, they are self-archiving significant numbers of publisher PDF versions. It finds significant levels of self-archiving, as well as significant self-archiving of the publisher PDF version, in all the disciplines investigated. Publishers’ self-archiving policies have no influence on author self-archiving practice

    Effective shear speed in two-dimensional phononic crystals

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    The quasistatic limit of the antiplane shear-wave speed ('effective speed') c in 2D periodic lattices is studied. Two new closed-form estimates of c are derived by employing two different analytical approaches. The first proceeds from a standard background of the plane wave expansion (PWE). The second is a new approach, which resides in x-space and centers on the monodromy matrix (MM) introduced in the 2D case as the multiplicative integral, taken in one coordinate, of a matrix with components being the operators with respect to the other coordinate. On the numerical side, an efficient PWE-based scheme for computing c is proposed and implemented. The analytical and numerical findings are applied to several examples of 2D square lattices with two and three high contrast components, for which the new PWE and MM estimates are compared with the numerical data and with some known approximations. It is demonstrated that the PWE estimate is most efficient in the case of densely packed stiff inclusions, especially when they form a symmetric lattice, while in general it is the MM estimate that provides the best overall fitting accuracy.Peer reviewe
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