7,556 research outputs found
SHRIMP ion probe zircon geochronology and Sr and Nd isotope geochemistry for southern Longwood Range and Bluff Peninsula intrusive rocks of Southland, New Zealand
No full textPermian–Jurassic ultramafic to felsic intrusive complexes at Bluff Peninsula and in the southern Longwood Range along the Southland coast represent a series of intraoceanic magmatic arcs with ages spanning a time interval of 110 m.y. New SHRIMP U-Pb zircon data for a quartz diorite from the Flat Hill complex, Bluff Peninsula, yield an age of 259 ± 4 Ma, consistent with other geochronological and paleontological evidence confirming a Late Permian age. The new data are consistent with an age of c. 260 Ma for the intrusive rocks of the Brook Street Terrane. SHRIMP U-Pb zircon ages for the southern Longwood Range confirm that intrusions become progressively younger from east to west across the complex. A gabbro at Oraka Point (eastern end of coastal section) has an age of 245 ± 4 Ma and shows virtually no evidence of zircon inheritance. The age is significantly different from that of the Brook Street Terrane intrusives. Zircon ages from the western parts of the section are younger and more varied (203–227 Ma), indicating more complex magmatic histories. A leucogabbro dike from Pahia Point gives the youngest emplacement age of 142 Ma, which is similar to published U-Pb zircon ages for the Anglem Complex and Paterson Group on Stewart Island
Toxicity of Pb and of Pb/Cd combination on the springtail Folsomia candida in natural soils: Reproduction, growth and bioaccumulation as indicators
No full textThe toxicity of Pb and Cd+Pb was assessed on the Collembola F. candida in two cultivated soils (SV and AU) with low organic matter (OM) content and circumneutral to basic pH, and an acid forested soil (EPC) with high OM content. Collembola reproduction and growth as well as metal content in Collembola body, in soil, exchangeable fraction and soil solutions, pH and DOC were investigated. Pb and Cd+Pb were the highest in exchangeable fraction and soil solution of the acidic soils. Soil solution pH decreased after metal spiking in every soil due to metal adsorption, which was similar for Cd and the highest in AU for Pb. With increasing Pb and Cd+Pb, the most important reproduction decrease was in EPC soil. The LOEC for reproduction after metal addition was 2400 (Pb) and 200/2400 (Cd/Pb), 1200 and 100/1200, 300 and 100/1200 μg g−1 for AU, SV and EPC, respectively. The highest and the lowest Pb toxicity was observed for EPC and AU bulk soil, respectively. The metal in Collembola increased with increasing soil concentration, except in AU, but the decreasing BFsolution with increasing concentrations indicates a limited metal transfer to Collembola or an increased metal removal. Loading high Pb concentrations decreases Cd absorption by the Collembola, but the reverse was not true. The highest Pb toxicity in EPC can be explained by pH and OM content. Because of metal complexation, OM might have a protective role but its ingestion by Collembola lead to higher toxicity. Metal bioavailability in Collembola differs from soil solution indicating that soil solution is not sufficient to evaluate toxicity in soil organisms. The toxicity as a whole decreased when metals were combined, except for Pb in AU, due to adsorption competition between Cd and Pb on clay particles and OM sites in AU and EPC soils, respectively
K-feldspar sand-grain provenance in the Triassic, west of Shetland : distinguishing first-cycle and recycled sediment sources?
No full textSandstone provenance studies can help constrain palaeogeographic reconstructions and ancient drainage system scales and pathways. However, these insights can be obscured by difficulties in geochemically distinguishing or adequately characterising potential sourcelands, or by failure to identify sedimentary recycling. Triassic basins west of Shetland accumulated ~2.5 km of sand-rich sediment. The Middle-Upper Triassic Foula Formation represents fluvial, aeolian and sabkha facies deposited in the northern interior of the Pangean supercontinent. Published U-Pb zircon geochronology and heavy mineral analysis suggest that these sandstones were derived from East Greenland. They contain significant fresh K-feldspar which is likely to be first-cycle and derived directly from its source. Pb isotopic analyses of individual K-feldspar sand-grains show a single, unradiogenic Pb population, consistent with the provenance indicated by U-Pb zircon geochronology. Archaean and Palaeo-Mesoproterozoic rocks – the Nagssugtoqidian Mobile Belt, the Lewisian Complex or equivalents - are the likely source, with terranes south of the Moine Thrust (Grampian, Caledonian and Variscan) ruled out by both the Pb and U-Pb data. However, it is not possible to distinguish between rift flank sources to the east and west, as both areas have similar crustal affinity and/or share the same tectonic history. It is possible that the sediment was derived from the West Shetland Platform and not from Greenland. The comparison of provenance signals from robust and less stable mineral phases provides a means of recognising sedimentary recycling. Robust zircon populations and less stable feldspar in Foula Formation sandstones concur in indicating the same source, suggesting that they are likely to be first-cycle. The Triassic sand supply can be contrasted with that in Upper Carboniferous (Namurian) basins in the north of England where a significant zircon population has no corresponding K-feldspar component. This zircon population is likely to have been recycled from Lower Palaeozoic greywackes from the Southern Uplands Belt or its along strike extension.Science Foundation Irelan
Geochemical vectors for stratiform Zn-Pb-Ag sulfide and associated dolomite-hosted Cu mineralization at Zinkgruvan, Bergslagen, Sweden
No full textThe Zinkgruvan deposit is the largest stratiform Zn-Pb-Ag mineralization in Sweden. The most recent genetic model attributes ore formation to the discharge of oxidized, near-neutral pH, metalliferous brines into a reduced basin, forming laterally extensive, stratiform sulfide mineralization on the seafloor. It has a known strike extent of 5 km and is underlain by a regionally extensive zone of K-altered metavolcanic rock and dolomitic marble, the latter hosting Cu-(Co-Ni) replacement mineralization near the inferred hydrothermal vent to the stratiform sulfides. The deposit is stratigraphically overlain by migmatized, pyrrhotite- and graphite-rich pelite that is in turn overlain by a banded almandine-biotite-quartz-ferrosilite-bearing unit at the base of an regionally extensive metasedimentary succession. These laterally continuous units are interpreted as metamorphosed organic-rich sulphidic mudstone and silicate-dominated Fe formation, respectively.The favorable stratigraphic interval contains anomalously high Zn, Pb, Ag, Cu, K2O/(K2O+Na2O), Mn, Co, Tl, Ba and B relative to adjacent metatuffite. However, only Zn, Pb, Ag, K2O/(K2O+Na2O) and Mn are significantly enriched relative to adjacent strata beyond the known lateral extent of the ore. Elevated copper, Co and Tl only occur in the vent-proximal part of the deposit, whereas anomalous enrichments of Ba and B are sporadic and occur mainly in the stratigraphic footwall. Many elements such as Si, Fe, Mg, Ca and Cs are of limited use in vectoring due to low enrichment factors relative to inferred background compositions and/or strong lithological controls on their distribution.Although ore metal (Zn, Pb and Ag) enrichments are the best quantitative and qualitative guides to ore, K, Mn and Co enrichments also provide corroborative support. The most useful elements for vectoring have been synthesized into exploration indices. The Modified Sedex Metal Index (MSMI; Zn+3Pb+100Ag) is a vector towards stratiform Zn-Pb-Ag mineralization, whereas MSMI2 [Zn+3Pb+10(Cu+Co)] alsoallows targeting of proximal Cu mineralization.The banded iron formation and the pyrrhotite- and graphite-rich pelite of the stratigraphic hangingwall are consistently enriched in base metals (e.g. 500-1000 ppm Zn), total S and Mn throughout the entire Zinkgruvan area. However, these units are not known to grade laterally along strata into economic base metal sulfide mineralization, and they are not obviously products of the same hydrothermal system which formed the stratiform Zn-Pb-Ag deposit.In a vent-distal setting, the somewhat spurious metal anomalies of the hangingwall units can be difficult to distinguish from those of the favorable interval. The favorable stratigraphic interval can, however, be recognized by also taking into account that positive Zn anomalies are mainly coincident with positive anomalies in both K and Mn only in the favorable interval. Furthermore, samples from the favorable interval generally have Co/Ni > 1 and displays a positive Co/Ni vs. Zn trend, whereas samples of the pyrrhotite- and graphite-rich pelite have Co/Ni < 1 and define a negative Co/Ni vs. Zn trend. Thus, the index (Co/Ni)*Zn allows easy detection of weak Zn anomalies associated with the stratiform Zn-Pb-Ag mineralization.</p
Heavy metal distribution in some French forest soils: evidence for atmospheric contamination
No full textThis study is one of very few dealing with the distribution and the origin of heavy metals in French soils from a
priori non-polluted forest areas. The abundance of heavy metals measured in these soils decreases as follows: Cr)
Zn)Pb)Ni)Cu)Co4Cd. Total concentrations of Pb, Cr and Ni in some soils exceed the European thresholds for non-polluted soils and even the French association of normalization critical values for sludge spreading. The lowest heavy metal contents are observed in acid soils while the highest concentrations are in the calcaric cambisol and in
the mollic andosol, which is rather scarce as compared with the other French forest soils. With the exception of the
podzol, Cr and Ni concentrations increase with depth in all soil profiles. The distribution pattern of Co, Cu, Zn
depends on the soil characteristics. In some acid soils, however, Cu and Zn decrease with depth. Pb and Cd are
accumulated in the upper soil horizons. Heavy metals accumulate in deep soil horizons in relation to important clay content in the dystric planosol and stagnic luvisol. The concentration of each heavy metal is always controlled by different parameters (soil pH, iron and aluminum oxide content, clay content, organic matter and cation exchange
capacity), which are heavy metal specific. This study highlights the metal-trapping character of andosol and calcaric soil, the weak heavy metal retention in acid soils, the leaching and trapping character in leached clayed soils, and the migration of heavy metals in the podzol. Pb and Cr concentrations indicate a significant enrichment in surface horizons from various soils in areas which receive significant acid atmospheric pollution. Particularly, the highest Pb content is observed in a soil located in the N-NE part of France. Lead isotope ratios measured in the cambic podzol and the calcaric cambisol, exhibit the importance of the anthropogenic sources and particularly the influence of global atmospheric inputs from leaded gasoline compared to regional and local industrial emissions. The anthropogenic Pb contribution is estimated to 83, 30 and 11%, respectively, for surface, intermediate and deep horizons of the cambic podzol located in the northern part of France, and to 68% in surface horizon of the calcaric cambisol located in the Alps
Source lithology of the Galápagos plume
No full textWe have measured the contents of Ni, Ca, and Mn in olivine phenocrysts from volcanoes in the Galápagos archipelago to infer the mantle source lithologies. Results show that peridotite is the dominant source lithology for Fernandina, Floreana, Genovesa, Marchena, Pinta, Wolf Island, and Darwin Island. These volcanoes largely characterize the PLUME, WD, FLO and DUM Nd, Sr, and Pb isotopic endmembers of Harpp and White (2001). Only a minor pyroxenite component contributes to Fernandina and Floreana. Peridotite is also the dominant source lithology for Volcan Wolf, Alcedo, and Cerro Azul, and that these have isotopic compositions that can be defined by mixing of the 4 endmembers. Peridotite is therefore the dominant source lithology of the Galápagos plume. However, pyroxenite melting is significant in two spatially separated domains which are also isotopically distinct: Roca Redonda, Volcan Ecuador, Sierra Negra in the enriched western part of the archipelago and Volcan Darwin, Santiago, Santa Cruz, and Santa Fe in the depleted east. An implication is that the western and eastern pyroxenite domains likely represent two separate bodies of recycled crust within the Galápagos mantle plume. Isotopically enriched and depleted domains of the archipelago melted from both peridotite and pyroxenite, and there is no relationship between source lithology and its isotopic characteristics. The identification of peridotite source melting in volcanoes with isotopic characteristics that have been attributed to recycled crust points to the importance of mixing in OIB genesis, in agreement with studies on the Canary Islands.M.S.Includes bibliographical referencesby Christopher Allen Vidit
Terminal suturing of Gondwana along the southern margin of South China Craton : evidence from detrital zircon U-Pb ages and Hf isotopes in Cambrian and Ordovician strata, Hainan Island
No full textThis work was supported by the National Natural Science Foundation of China (grants 41472086 and 41272120), “111” Project (B08030), the fundamental Research Funds for the Central Universities, China University of Geosciences (Wuhan) (CUG2012019240 and CUG2013019137). The first author also acknowledges China Scholarship Council (grant 201208420001) for supporting his research in the University of St. Andrews. Date of Acceptance: 20/11/2014Hainan Island, located near the southern end of mainland South China, consists of the Qiongzhong Block to the north and the Sanya Block to the south. In the Cambrian, these blocks were separated by an intervening ocean. U-Pb ages and Hf isotope compositions of detrital zircons from the Cambrian succession in the Sanya Block suggest that the unit contains detritus derived from late Paleoproterozoic and Mesoproterozoic units along the western margin of the West Australia Craton (e.g., Northampton Complex) or the Albany-Fraser-Wilkes orogen, which separates the West Australia and Mawson cratons. Thus, in the Cambrian the Sanya Block was not part of the South China Craton but rather part of the West Australian Craton and its environs. In contrast, overlying Late Ordovician strata display evidence for input of detritus from the Qiongzhong Block, which constituted part of the southeastern convergent plate margin of the South China Craton in the early Paleozoic. The evolving provenance record of the Cambrian and Ordovician strata suggests that the juxtaposition of South China and West Australian cratons occurred during the early to mid-Ordovician. The event was linked with the northern continuation of Kuungan Orogeny, with South China providing a record of final assembly of Gondwana.Peer reviewe
O processo de verticalização e seus problemas no bairro de Manaíra, João Pessoa-PB.
No full textThe work traces the verticalization process in District Manaíra in João Pessoa-PB. To fulfill its purpose broke the concept, causes, and consequences of this process mainly the problems caused by such a process. Reports related to the process of urban verticalization in order to understand the process and support research studies. "Was taken as a base study dissertation titled The study Manaíra neighborhood in João Pessoa, Paraíba," Nobrega (2011). Additionally, consultation to planning legislation relating to the theme. Research upgraded the empirical survey and mapping by the cited author. Thus, in addition to consulting government institutions such as the Water and Sewerage Company of Paraíba, the core of the research corresponds to the empirical survey of land use studied in the neighborhood that was recorded by consignment types of buildings. This survey maps of land use were developed. Finally, the article discusses the problems caused by the process of verticalization in District Manaíra located on the edge of João Pessoa-PB.O trabalho traça um panorama do processo de verticalização, no Bairro de Manaíra na cidade de João Pessoa-PB. Para cumprir seu propósito partiu-se do conceito, causas, consequências resultantes deste processo e principalmente, os problemas ocasionados por tal processo. Reporta-se a estudos relacionados ao processo de verticalização urbana, no intuito de compreender o processo e fundamentar a pesquisa. “Tomou-se como estudo base a dissertação de mestrado intitulada O estudo do bairro de Manaíra em João Pessoa, Paraíba”, de Nóbrega (2011). Além disso, consulta-se a legislação urbanística referente à temática. A pesquisa atualizou o levantamento empírico e o mapeamento realizado pela autora citada. Desta forma, além da consulta as instituições governamentais como a Companhia de Águas e Esgotos da Paraíba, IBGE, Corpo de Bombeiros e etc., o cerne da pesquisa corresponde ao levantamento empírico do uso do solo do bairro estudado em que se registrou lote por lote o tipo de edificação. Deste levantamento foram elaborados mapas do uso do solo. Por fim, foram identificados e abordados os problemas ocasionados pelo processo de verticalização no Bairro de Manaíra localizado na orla de João Pessoa-PB
Vector boson production in p+Pb and Pb+Pb collisions measured with ATLAS at the LHC
No full textElectroweak boson production processes (W, Z and photon) provide access to the earliest moments of heavy ion collisions. Furthermore, because they do not undergo strong interactions, they are sensitive to the initial-state geometry of the collision and potentially the details of the nuclear parton distribution functions (PDF). ATLAS results on vector boson yields have demonstrated binary collision scaling in Pb+Pb collisions. In p+Pb collisions, the measurement of vector bosons provides possible constraints on the nuclear PDF and insights into the details of the initial collision geometry. We report on the latest results of vector boson production in p+Pb collisions at sqrt(sNN)=5.02 TeV and Pb+Pb collisions at sqrt(sNN)=2.76 TeV. In p+Pb collisions, production yields and lepton charge asymmetry of W bosons are presented as a function of pseudorapidity of the charged lepton and centrality. Photon and Z yields are presented differentially as a function of transverse momentum, rapidity and centrality. The vector boson yields are compared to calculations incorporating different PDF sets, as well as different centrality calculations
Thermochronology of the modern Indus River bedload: New insight into the controls on the marine stratigraphic record
No full textThe Indus River is the only major drainage in the western Himalaya and delivers a long geological record of continental erosion to the Arabian Sea, which may be deciphered and used to reconstruct orogenic growth if the modern bedload can be related to the mountains. In this study we collected thermochronologic data from river sediment collected near the modern delta. U-Pb ages of zircons spanning 3 Gyr show that only ∼5% of the eroding crust has been generated since India-Asia collision. The Greater Himalaya are the major source of zircons, with additional contributions from the Karakoram and Lesser Himalaya. The 39Ar/40Ar dating of muscovites gives ages that cluster between 10 and 25 Ma, differing from those recorded in the Bengal Fan. Biotite ages are generally younger, ranging 0–15 Ma. Modern average exhumation rates are estimated at ∼0.6 km/m.y. or less, and have slowed progressively since the early Miocene (∼20 Ma), although fission track (FT) dating of apatites may indicate a recent moderate acceleration in rates since the Pliocene (∼1.0 km/m.y.) driven by climate change. The 39Ar/40Ar and FT techniques emphasize the dominance of high topography in controlling the erosional flux to the ocean. Localized regions of tectonically driven, very rapid exhumation (e.g., Nanga Parbat, S. Karakoram metamorphic domes) do not dominate the erosional record
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