4,231 research outputs found
Nonlinear influence of excess Mn on the magnetoelastic transition in (Mn,Cr)<sub>2</sub>Sb
No full textThe influence of excess Mn on the magnetoelastic ferromagnetic-to-antiferromagnetic transition Tt in the magnetocaloric compound (Mn,Cr)2Sb has been studied. With increasing excess Mn the magnetoelastic transition temperature for (Mn,Cr)2Sb initially increases and then decreases. This trend is accompanied by a strong reduction of the (Mn,Cr)Sb secondary phase. With increasing excess Mn a higher Cr content was found in the (Mn,Cr)Sb secondary phase in comparison to the matrix phase. This competition for Cr leads to a nonlinear dependence of Tt with increasing excess Mn at a fixed nominal Cr content. However, we observed that Tt depends linear on the c/a ratio for a wide range of temperatures from 170 to 350 K. A compositional diagram of the c/a ratio was constructed to assist the selection of (Mn,Cr)2Sb alloys with a desired transition temperature.RST/Fundamental Aspects of Materials and Energ
Surface Oxidation and Wettability of Fe–Mn and Fe–Mn–Si-Alloyed Steel After Annealing
No full textThe surface oxidation and wettability of Mn and Si-alloyed steel after annealing at different conditions are studied with scanning electron microscope (SEM), X-ray photoelectron spectroscopy (XPS), and a so-called de-wetting method. After exposure at 950 °C for 1 hour in an Ar + 5 vol pct H2 gas atmosphere with dew points (DP) ranging from – 40 °C to 10 °C, oxides were observed along the grain boundaries or dispersed on the surface for the Fe–1.8 Mn steels while a continuous oxides layer was formed on Fe–1.9 Mn–0.94 Si steels (composition in weight fractions). The oxides formed at different DPs were predicted based on thermodynamic calculations. (Fe,Mn)O was formed on Fe–1.8 Mn steel at the whole range of DPs, while the oxide phase on Fe–1.9 Mn–0.94 Si steel depends on the DP. At low-DP SiO2 were formed and with increasing the DP (Fe,Mn)SiO3 or (Fe,Mn)SiO3 + (Fe,Mn)2SiO4 were formed and finally (Fe,Mn)2SiO4 were formed. An increase of the fraction of Fe in the oxide with increasing DP for both steels was observed with XPS analysis. As a measure for the surface wettability, the contact angle of Pb droplets on the annealed steels surfaces was determined with SEM and image analysis software. Also, the contact angle of Pb on pure Fe and on the Mn and Si alloyed steels free of surface oxides was measured for comparison. The results show that the contact angle of Pb on the steel surfaces after annealing decreases with increasing DP. This improved wettability with increasing dew point is related to the Fe fraction of the oxides formed on the surface.Team Kevin RossiTeam Maria Santofimia NavarroTeam Marcel Herman
Temperature-Dependent Microstructural Evolution of Al-Rich Medium-Mn Steel During Intercritical Annealing
No full textMedium-Mn automotive sheet steels require optimized heat-treatment processes to obtain benefits caused by strain-induced martensitic transformation of retained austenite (RA) during sheet metal forming or crash events. The intercritical annealing (IA) approach at different temperatures in a range of 640 °C to 800 °C is proposed in the study for a 5Mn hot-rolled medium-Mn sheet steel. The experiments were performed in terms of dilatometry. The analysis of the cooling curves allowed development of a new method for calculating the high-temperature phase equilibrium. The calculations were validated by modeling with JMatPro and experimentally verified by X-ray diffraction (XRD). The microstructure evolution was characterized using light optical microscopy and scanning electron microscopy (SEM), including electron backscatter diffraction (EBSD). The quantitative determination of the fraction, morphology, chemical composition, and stability of the RA was done. Mechanical properties were determined by hardness measurements. The research showed a substantial influence of the IA temperature on the RA fraction and chemical stability and properties of medium-Mn Al-alloyed steel. At temperatures of 680 °C and 700 °C, the largest fraction of over 35 pct of stable RA was obtained, which does not transform to martensite during cooling.Green Open Access added to TU Delft Institutional Repository 'You share, we take care!' - Taverne project https://www.openaccess.nl/en/you-share-we-take-care Otherwise as indicated in the copyright section: the publisher is the copyright holder of this work and the author uses the Dutch legislation to make this work public.Team Kevin Ross
Mn/Ca ratios of Ammonia tepida as a proxy for seasonal coastal hypoxia
No full text Climate variability has major implications for marine geochemical cycles and biogenic carbonate production. Therefore, past climate-driven changes in marine environments are often inferred from geochemical data of the marine carbonate archive. Proxy calibration studies are essential for the reconstruction of such past environmental changes. Here, we use the geochemical composition of living specimens of the benthic foraminifer Ammonia tepida at three sites in a seasonally hypoxic (oxygen concentration < 63 μmol/L) marine coastal system (Lake Grevelingen, the Netherlands) to explore the use of Mn/Ca as a proxy for coastal hypoxia. The study is based on samples from three stations along a depth transect, that show contrasts in the seasonal cycle of Mn 2+ concentrations in the pore water of the surface sediment. In general, the sediment and pore water geochemistry of the three stations in Lake Grevelingen show increased Mn 2+ concentrations in late winter/spring, combined with increased Mn refluxing in summer, which are due to cable bacteria activity and bottom water hypoxia/anoxia, respectively. Laser Ablation-ICP-MS (LA-ICP-MS) allowed a comparison of Mn/Ca ratios of different parts of the benthic foraminiferal test. Our results show that higher Mn/Ca ratios are registered at the deepest station, which experiences the longest and most severe seasonal periods of hypoxia/anoxia. Additionally, the signal preserved in the central part of the benthic foraminiferal tests, which is thought to reflect the entire calcification history of the analysed specimen, appears to be driven by high pore water Mn 2+ concentrations due to cable bacteria activity in late winter/spring. Conversely, high Mn/Ca ratios in the last chambers reflect increased Mn refluxing in the surface sediment due to summer hypoxia/anoxia. Thus, Mn/Ca ratios of A. tepida give insight into the complex spatial and temporal variability of pore water manganese. Accepted Author ManuscriptBT/Environmental Biotechnolog
STEM Certificate Course Development
No full textNatasha Yates, Assistant Professor of Education, received a $2,033 Curriculum Development Award to examine course requirements as they relate to the needs of K-6 elementary education majors.
The Minnesota Department of Education requires that elementary school teachers from pre-school through sixth grade (K-6) are required to teach science, engineering and math. Yet, primary school teachers have limited science and engineering knowledge, resulting in minimal confidence in their ability to teach science, let alone engineering. When teachers in the K-6 departments, 71% agreed that elementary teacher education programs should require their undergraduates to take more coursework in science and science teaching methods.
In 2004, the Minnesota Board of Education informed St. Catherine University that our teacher candidates were not taking enough science: in response, an interdisciplinary STEM minor was designed based on the MN Board of Teaching standards.
St. Catherine University students working towards a K-6 teaching license are required to take three science courses: Environmental Biology, Chemistry of Life, and Engineering in Your World. The courses were designed to, meet the Minnesota Board of Teaching Science & Engineering Standards that institutions of higher education are required to teach their K-6 elementary education majors.
Dr. Yates study will measure how the SCU undergraduate STEM Certification is correlated to the hiring of students in the competitive job market
Kinetics of internal oxidation of Fe-Mn-Cr steel alloys
No full textSelective oxidation behaviour of Fe-Mn-Cr steel alloys annealed at 950°C in Ar plus 5 vol.% H2 atmosphere under different annealing time and dew points was studied. The Fe-Mn-Cr steel alloys are externally oxidized when annealing at dew point of -45 °C, while internally oxidized at dew points of -10 and 10 °C. The internal oxides formed in the Fe-Mn-Cr steel alloys are (Mn, Fe)O and (Cr, Mn, Fe)3O4. The kinetics of internal oxidation of Fe-Mn-Cr alloys at 950 °C is diffusion controlled and follows parabolic growth rate law. The measured kinetics of internal oxidation of Fe-Mn-Cr alloys and the concentration depth profiles of internal oxides are in good agreement with simulation results. Adding Cr to the Fe-Mn steel alloys decreases the kinetics of internal oxidation. The growth rate of internal oxidation zone can be predicted by a modified Wagner’s internal oxidation model. The external oxides formed during annealing of Fe-Mn-Cr steel alloys cannot be reduced by H2. However, an oxide-free steel surface can be obtained by first forming and then reducing a Wüstite scale.Materials Science and Engineerin
Efficient and Practical Transfer Hydrogenation of Ketones Catalyzed by a Simple Bidentate Mn−NHC Complex
No full textCatalytic reductions of carbonyl-containing compounds are highly important for the safe, sustainable, and economical production of alcohols. Herein, we report on the efficient transfer hydrogenation of ketones catalyzed by a highly potent Mn(I)−NHC complex. Mn−NHC 1 is practical at metal concentrations as low as 75 ppm, thus approaching loadings more conventionally reserved for noble metal based systems. With these low Mn concentrations, catalyst deactivation is found to be highly temperature dependent and becomes especially prominent at increased reaction temperature. Ultimately, understanding of deactivation pathways could help close the activity/stability-gap with Ru and Ir catalysts towards the practical implementation of sustainable earth-abundant Mn-complexes.Accepted Author ManuscriptChemE/Inorganic Systems EngineeringChemE/Algemee
Investigation of route to martensitic transition in Ni-Mn-In shape memory alloys
No full textThe temperature dependent x-ray diffraction and magnetization measurements on the off stoichiometric Ni2Mn1+xIn1-xalloys have confirmed the appearance of martensite at critical Mn concentration of x=0.35. The high temperature phase of all the alloys have cubic L21structure with the lattice constant steadily decreasing with increase in Mn concentration. Martensitic transition begins to appear in Ni2Mn1.35In0.65at about 197K and the structure seems to adopt two phases including the major cubic along with the modulated monoclinic phase. This has been explained on the basis of number of Mn-Ni-Mn hybridized pairs that are responsible for inducing martensitic transition
Enhanced reversibility of the magnetoelastic transition in (Mn,Fe)<sub>2</sub>(P,Si) alloys via minimizing the transition-induced elastic strain energy
No full textMagnetocaloric materials undergoing reversible phase transitions are highly desirable for magnetic refrigeration applications. (Mn,Fe)2(P,Si) alloys exhibit a giant magnetocaloric effect accompanied by a magnetoelastic transition, while the noticeable irreversibility causes drastic degradation of the magnetocaloric properties during consecutive cooling cycles. In the present work, we performed a comprehensive study on the magnetoelastic transition of the (Mn,Fe)2(P,Si) alloys by high-resolution transmission electron microscopy, in situ field- and temperature-dependent neutron powder diffraction as well as density functional theory calculations (DFT). We found a generalized relationship between the thermal hysteresis and the transition-induced elastic strain energy for the (Mn,Fe)2(P,Si) family. The thermal hysteresis was greatly reduced from 11 to 1 K by a mere 4 at.% substitution of Fe by Mo in the Mn1.15Fe0.80P0.45Si0.55 alloy. This reduction is found to be due to a strong reduction in the transition-induced elastic strain energy. The significantly enhanced reversibility of the magnetoelastic transition leads to a remarkable improvement of the reversible magnetocaloric properties, compared to the parent alloy. Based on the DFT calculations and the neutron diffraction experiments, we also elucidated the underlying mechanism of the tunable transition temperature for the (Mn,Fe)2(P,Si) family, which can essentially be attributed to the strong competition between the covalent bonding and the ferromagnetic exchange coupling. The present work provides not only a new strategy to improve the reversibility of a first-order magnetic transition but also essential insight into the electron-spin-lattice coupling in giant magnetocaloric materials.Green Open Access added to TU Delft Institutional Repository ‘You share, we take care!’ – Taverne project https://www.openaccess.nl/en/you-share-we-take-care Otherwise as indicated in the copyright section: the publisher is the copyright holder of this work and the author uses the Dutch legislation to make this work public.RST/Fundamental Aspects of Materials and Energ
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