34 research outputs found
Equilibrium Data For Systems Composed By Cottonseed Oil + Commercial Linoleic Acid + Ethanol + Water + Tocopherols At 298.2 K
No full textThe present paper reports liquid-liquid equilibrium data for the system refined cottonseed oil + commercial linoleic acid + ethanol + water at 298.2 K. The experimental data were used for adjusting parameters of the NRTL and UNIQUAC models. The global deviations between calculated and experimental concentrations were 0.80% for the NRTL model and 1.44% for the UNIQUAC equation. The influence of the solvent on the distribution coefficient of tocopherols was also studied. UNIQUAC and NRTL interaction parameters between tocopherols and the other pseudocomponents were determined assuming that the nutraceutical compound is present at infinite dilution in the liquid-liquid equilibrium system. The obtained parameter set enables the simulation of liquid-liquid extractors. © 2005 Elsevier B.V. All rights reserved.2382193203http://www.soystats.com/2004/Default-frames.htmCheryan, M., (1998) Ultrafiltration and Microfiltration Handbook, , Tecnomic LancasterAntoniassi, R., Esteves, W., Meirelles, A.J.A., (1998) J. Am. Oil Chem. Soc., 75 (10), pp. 1411-1415Hui, Y.H., (1996) Bailey's Industrial Oil and Fat Products, , John Wiley and Sons Inc. New YorkWan, P.J., Pakarinen, D.R., Hron, R.J., (1996) J. Am. Oil Chem. Soc., 73 (6), pp. 815-817Thomopoulos, C., (1971) Rev. Fran. Corps Gras, 18, pp. 143-150Apelblat, A., Zaharoskin, T., Wisniak, J., Korngold, E., (1996) J. Am. Oil Chem. Soc., 73 (2), pp. 239-244Pina, C.G., Meirelles, A.J.A., (2000) J. Am. Oil Chem. Soc., 77, pp. 553-559Rodrigues, C.E.C., Antoniassi, R., Meirelles, A.J.A., (2003) J. Chem. Eng. Data, 48, pp. 367-373Rodrigues, C.E.C., Pessôa Filho, P.A., Meirelles, A.J.A., (2004) Fluid Phase Equilib., 216 (2), pp. 271-283Rodrigues, C.E.C., Silva, F.A., Marsaioli Jr., A., Meirelles, A.J.A., (2005) J. Chem. Eng. Data, 50, pp. 517-523Kale, V., Katikaneni, S.P.R., Cheryan, M., (1999) J. Am. Oil Chem. Soc., 76, pp. 723-727Bhattacharyya, A.C., Majumdar, S., Bhattacharyya, D.K., (1987) Oléagineaux, 42, pp. 431-433Shah, K.J., Venkatesan, T.K., (1989) J. Am. Oil Chem. Soc., 66, pp. 783-787Gonçalves, C.B., Batista, E., Meirelles, A.J.A., (2002) J. Chem. Eng. Data, 47, pp. 416-420Gonçalves, C.B., Meirelles, A.J.A., (2004) Fluid Phase Equilib., 221, pp. 139-150Batista, E., Monnerat, S., Kato, K., Stragevitch, L., Meirelles, A.J.A., (1999) J. Chem. Eng. Data, 44, pp. 1360-1364Sreenivasan, K., Viswanath, D.S., (1973) Indian J. Technol., 11, pp. 83-90(1988) A.O.C.S. Official Methods and Recommended Practices of the American Oil Chemists' Society, vol. 1-2, , 3rd ed. A.O.C.S. Press Champaign(1998) A.O.C.S. Official Methods and Recommended Practices of the American Oil Chemists' Society, , 5th ed. A.O.C.S. Press ChampaignParrish, D.B., (1980) CRC Crit. Rev. Food Sci. Nutr., 13, pp. 161-187Paquot, C., (1979) IUPAC Standard Methods for the Analysis of Oils, Fats and Derivatives, , 6th ed. Pergamon PressMarcilla, A., Ruiz, F., García, A.N., (1995) Fluid Phase Equilib., 112, pp. 273-289Magnussen, T., Rasmussen, P., Fredenslund, A., (1981) Ind. Eng. Chem. Process Des. Dev., 20, pp. 331-339Stragevitch, L., D'Avila, S.G., (1997) Braz. J. Chem. Eng., 14, pp. 41-52Pessôa Filho, P.A., (2002), PhD Thesis (in portuguese), Chemical Engineering Faculty, State University of CampinasKang, C.H., Sandler, S.I., (1987) Fluid Phase Equilib., 38, pp. 245-272Antoniosi Filho, N.R., Mendes, O.L., Lanças, F.M., (1995) Chromatographia, 40, pp. 557-562Firestone, D., (1999) Physical and Chemical Characteristics of Oils, Fats, and Waxes, , AOCS Press Washington, D
Phase Equilibrium For Systems Composed By High Unsaturated Vegetable Oils + Linoleic Acid + Ethanol + Water At 298.2 K
No full textThis work reports experimental liquid-liquid equilibrium data for model systems composed by refined vegetable oils + linoleic acid + ethanol + water at 298.2 K. The experimental data were used for adjusting parameters of the NRTL and UNIQUAC models. Global deviations between calculated and experimental data not higher than 1 % were obtained for all systems, showing the good descriptive quality of the models. © 2006 American Chemical Society.5111521Rodrigues, C.E.C., Antoniassi, R., Meirelles, A.J.A., Equilibrium data for the system rice bran oil + fatty acids + ethanol + water at 298.2 K (2003) J. Chem. Eng. Data, 48, pp. 367-373Rodrigues, C.E.C., Pessôa Filho, P.A., Meirelles, A.J.A., Phase equilibrium for the system rice bran oil + fatty acids + ethanol + water + γ-oryzanol + tocols (2004) Fluid Phase Equilib., 216, pp. 271-283Thomopoulos, C., Méthode de desacidification des huiles par solvant sélectif (1971) Rev. Fr. Corps Gras, 18, pp. 143-150Kim, J., Godber, J., King, J., Prinyawiwatkul, W., Inhibition of cholesterol autoxidation by the nonsaponifiable fraction in rice bran in an aqueous model system (2001) J. Am. Oil Chem. Soc., 78, pp. 685-689Kale, V., Katikaneni, S.P.R., Cheryan, M., Deacidifying rice bran oil by solvent extraction and membrane technology (1999) J. Am. Oil Chem. Soc., 76, pp. 723-727Bhattacharyya, A.C., Majumdar, S., Bhattacharyya, D.K., Refining of FFA rice bran oil by isopropanol extraction and alkali neutralization (1987) Oléagineaux, 42, pp. 431-433Shah, K.J., Venkatesan, T.K., Aqueous isopropyl alcohol for extraction of free fatty acids from oils (1989) J. Am. Oil Chem. Soc., 66, pp. 783-787Fachini, S., Samazzi, S., Behavior of alcohol in presence of olive oil which is acid (1925) Ind. Olii Grassi, 4, pp. 31-33Schlenker, E., Removal of fatty acids by means of alcohol (1931) Chem. Umsch. Geb. Fette, Oele, Wachse Harze, 38, pp. 108-110Batista, E., Monnerat, S., Kato, K., Stragevitch, L., Meirelles, A.J.A., Liquid-liquid equilibrium for systems of canola oil, oleic acid and short-chain alcohols (1999) J. Chem. Eng. Data, 44, pp. 1360-1364Batista, E., Monnerat, S., Stragevitch, L., Pina, C.G., Gonçalves, C.B., Meirelles, A.J.A., Prediction of liquid-liquid equilibrium for systems of vegetable oils, fatty acids and ethanol (1999) J. Chem. Eng. Data, 44, pp. 1365-1369Gonçalves, C.B., Batista, E., Meirelles, A.J.A., Liquid-liquid equilibrium data for the system corn oil + oleic acid + ethanol + water at 298.15 K (2002) J. Chem. Eng. Data, 47, pp. 416-420Gonçalves, C.B., Meirelles, A.J.A., Liquid-liquid equilibrium data for the system palm oil + fatty acids + ethanol + water at 318.2 K (2004) Fluid Phase Equilib., 221, pp. 139-150Amagase, H., Petesch, B.L., Matsuura, H., Kasuga, S., Itakura, Y., Intake of garlic and its bioactive components (2001) J. Nutr., 131, pp. 955S-962SMolero Gómez, A., Pereyra López, C., De La Martínez Ossa, E., Recovery of grape seed oil by liquid and supercritical carbon dioxide extraction: A comparison with conventional solvent extraction (1996) Chem. Eng. J., 61, pp. 227-231Abou-Gharbia, H.A., Shehata, A.A.Y., Shahidi, F., Effect of processing on oxidative stability and lipid classes of sesame oil (2000) Food Res. Int., 33, pp. 331-340(1988) Official Methods and Recommended Practices of the American Oil Chemists' Society, 3rd Ed., , AOCS: Champaign, IL(1998) Official Methods and Recommended Practices of the American Oil Chemists' Society, 5th Ed., , AOCS: Champaign, IL(1979) Standard Methods for the Analysis of Oils, Fats and Derivatives, 6th Ed., , part 1 (sections I and II)Paquot, C., Ed.Pergamon Press: OxfordMarcilla, A., Ruiz, F., García, A.N., Liquid-liquid-solid equilibria of the quaternary system water-ethanol-acetone-sodium chloride at 25°C (1995) Fluid Phase Equilib., 112, pp. 273-289Se, R.A.G., Aznar, M., Liquid-liquid equilibrium of the aqueous two-phase system water + PEG 4000 + potassium phosphate at four temperatures: Experimental determination and thermodynamic modeling (2002) J. Chem. Eng. Data, 47, pp. 1401-1405Magnussen, T., Rasmussen, P., Fredenslund, A., Unifac parameter table for prediction of liquid-liquid equilibria (1981) Ind. Eng. Chem. Process Des. Dev., 20, pp. 331-339Stragevitch, L., D'Avila, S.G., Application of a generalized maximum likelihood method in the reduction of multicomponent liquid-liquid equilibrium data (1997) Braz. J. Chem. Eng., 14, pp. 41-52Antoniosi Filho, N.R., Mendes, O.L., Lanças, F.M., Computer prediction of triacylglycerol composition of vegetable oils by HRGC (1995) Chromatographia, 40, pp. 557-562Ceriani, R., Meirelles, A.J.A., Simulation of continuous deodorizers: Effects on product streams (2004) J. Am. Oil Chem. Soc., 81, pp. 1059-1069Ceriani, R., Meirelles, A.J.A., Predicting vapor-liquid equilibria of fatty systems (2004) Fluid Phase Equilib., 215, pp. 227-23
Equilibrium Data For The System Rice Bran Oil + Fatty Acids + Ethanol + Water At 298.2 K
No full textThis work presents experimental data for the model system refined rice bran oil + commercial oleic acid + ethanol + water at 298.2 K. These data were correlated by the NRTL and UNIQUAC models, with a global deviation of approximately 0.7% for both models. The equilibrium of crude rice bran oil + aqueous ethanol was predicted with success using the adjusted interaction parameters, with deviation between calculated and experimental results not higher than 0.54%. The results showed that the addition of water to the solvent increases the solvent selectivity, reducing the losses of neutral oil and nutraceutical compounds, and expands the region of phase splitting, allowing the refining of highly acidic crude rice bran oils by solvent extraction.482367373Rukmini, C., Chemical, nutritional and toxicological studies of rice bran oil (1988) Food Chem., 30, pp. 257-268Deckere, E.A.M., Korver, O., Minor constituents of rice bran oil as functional foods (1996) Nutr. Rev., 54, pp. 120S-126SOrthoefer, F.T., Rice bran oil: Healthy lipid source (1996) Food Technol., 50, pp. 62-64Maccaskill, D.R., Zhang, F., Use of rice bran oil in foods (1999) Food Technol., 53, pp. 50-52Rong, N., Ausman, L.M., Nicolosi, R.J., Oryzanol decreases cholesterol absorption and aortic fatty streaks in hamsters (1997) Lipids, 32, pp. 303-309Kim, J., Godber, J., King, J., Prinyawiwatkul, W., Inhibition of cholesterol autoxidation by the nonsaponifiable fraction in rice bran in an aqueous model system (2001) J. Am. Oil Chem. Soc., 78, pp. 685-689Shin;, T.S., Godber, J.S., Martin, D.E., Wells, J.H., Hydrolytic stability and changes in E vitamers and oryzanol of extruded rice bran during storage (1997) J. Food Sci., 62, pp. 704-708Nakayama, S., Manabe, A., Suzuki, J., Sakamoto, K., Inagake, T., Comparative effects of two forms of γ-oryzanol in different sterol compositions on hyperlipidemia induced by cholesterol (1987) Jpn. J. Pharmacol., 44, pp. 135-143Akihisa, T., Yasukawa, K., Yamaura, M., Ukiya, M., Kimura, Y., Shimizu, N., Aral, K., Triterpene alcohol and sterol ferulates from rice bran and their antiinflammatory effects (2000) J. Agric. Food Chem., 48, pp. 2313-2319Eitenmiller, R.R., Vitamin E content of fats and oils: Nutritional implications (1997) Food Technol., 51, pp. 78-81Nesaretnan, K., Stephen, R., Dils, R., Darbre, P., Tocotrienols inhibit the growth of human breast cancer cells irrespective of estrogen receptor status (1998) Lipids, 33, pp. 461-469Qureshi, A.A., Mo, H., Packer, L., Peterson, D.M., Isolation and identification of novel tocotrienols from rice bran with hypocholesterolemic, antioxidant and antitumor properties (2000) J. Agric. Food Chem., 48, pp. 3130-3140Fornari, T., Bottini, S., Brignole, E.A., Application of UNTFAC to vegetable oil-alkane mixtures (1994) J. Am. Oil Chem. Soc., 71, pp. 391-395Gonzalez, C., Resa, J.M., Ruiz, A., Gutiérrez, J.I., Densities of mixtures containing n-alkanes with sunflower seed oil at different temperatures (1996) J. Chem. Eng. Data, 41, pp. 796-798Leibovitz, Z., Ruckenstein, C., Our experiences in processing maize (corn) germ oil (1983) J. Am. Oil Chem. Soc., 60, pp. 347A-351ACvengros, J., Physical refining of edible oils (1995) J. Am. Oil Chem. Soc., 72, pp. 1193-1196De, B.K., Bhattacharyya, D.K., Deacidification of high-acid rice bran oil by reesterification with monoglyceride (1999) J. Am. Oil Chem. Soc., 76, pp. 1243-1246Kale, V., Katikaneni, S.P.R., Cheryan, M., Deacidifying rice brain oil by solvent extraction and membrane technology (1999) J. Am. Oil Chem. Soc., 76, pp. 723-727Antoniassi, R., Esteves, W., Meirelles, A.J.A., Pretreatment of corn oil for physical refining (1998) J. Am. Oil Chem. Soc., 75, pp. 1411-1415Krishna, A.G.G., Khatoon, S., Shiela, P.M., Sarmandal, C.V., Indira, T.N., Mishra, A., Effect of refining of crude rice bran oil on the retention of oryzanol in the refined oil (2001) J. Am. Oil Chem. Soc., 78, pp. 127-131Thomopoulos, C., Méthode de desacidification des huiles par solvant sélectif (1971) Rev. Fr. Corps Gras, 18, pp. 143-150Bhattacharyya, A.C., Majumdar, S., Bhattacharyya, D.K., Refining of FFA rice bran oil by isopropanol extraction and alkali neutralization (1987) Oléagineaux, 42, pp. 431-433Shah, K.J., Venkatesan, T.K., Aqueous isopropyl alcohol for extraction of free fatty acids from oils (1989) J. Am. Oil Chem. Soc., 66, pp. 783-787Kim, S., Kim, C., Cheigh, H., Yoon, S., Effect of caustic refining, solvent refining and steam refining on the deacidification and color of rice bran oil (1985) J. Am. Oil Chem. Soc., 62, pp. 1492-1495Batista, E., Monnerat, S., Kato, K., Stragevitch, L., Meirelles, A.J.A., Liquid-liquid equilibrium for systems of canola oil, oleic acid and short-chain alcohols (1999) J. Chem. Eng. Data, 44, pp. 1360-1364Batista, E., Monnerat, S., Stragevitch, L., Pina, C.G., Gonçalves, C.B., Meirelles, A.J.A., Prediction of liquid-liquid equilibrium for systems of vegetable oils, fatty acids and ethanol (1999) J. Chem. Eng. Data, 44, pp. 1365-1369Gonçalves, C.B., Batista, E., Meirelles, A.J.A., Liquid-liquid equilibrium data for the system corn oil + oleic acid + ethanol + water at 298.15 K (2002) J. Chem. Eng. Data, 47, pp. 416-420(1988) Official Methods and Recommended Practices of the American Oil Chemists' Society, 3rd Ed., 1-2. , A.O.C.S. Press: Champaign, IlHartman, L., Lago, R.C.A., Rapid preparation of fatty acid methyl esters from lipids (1973) Lab. Pract., 22, pp. 475-476Antoniosi Filho, N.R., Mendes, O.L., Lanças, F.M., Computer prediction of triacylglycerol composition of vegetable oils by HRGC (1995) Chromatographia, 40, pp. 557-562Seetharamaiah, G.S., Prabhakar, J.V., γ-orizanol content of Indian rice bran oil and its extraction from soapstock (1986) J. Food Sci. Technol., 23, pp. 270-273Parrish, D.B., Determination of vitamin E in foods - A review (1980) CRC Crit. Rev. Food Sci. Nutr., 13, pp. 161-187Paquot, C., (1979) IUPAC Standard Methods for the Analysis of Oils, Fats and Derivatives, 6th Ed., (PART 1). , Pergamon Press: New York, sections I and IIMagnussen, T., Rasmussen, P., Fredenslund, A., Unifac parameter table for prediction of liquid-liquid equilibria (1981) Ind. Eng. Chem. Process Des. Dev., 20, pp. 331-339Stragevitch, L., D'Avila, S.G., Application of a generalized maximum likelihood method in the reduction of multicomponent liquid-liquid equilibrium data (1997) Braz. J. Chem. Eng., 14, pp. 41-5
Influence of the surface structure of Co on the selective hydrogenation of crotonaldehyde
No full text
S603 THE EFFECT OF ALKALINIZED LEVOBUPIVACAINE (R25%, S75%) IN THE ENDOTRACHEAL TUBE CUFF ON POSTOPERATIVE SORE THROAT
No full textFinance and policy in the realization of the church values seized in 1922
No full textFinancial and politics aspects of the realization of the church values seized in 1922 under the pretext of rendering assistance to the starving people are analyzed in the article. Author examines relationship between People’s Commissariat for Finance and three organizations of the all-Russian C.E.C. in which possession were the seized values. The conducted study gives grounds to assert that no sales of the church values abroad for purchase of bread for starving people were carried out and the fight against famine and it’s consequences was waged with the funds of the state Treasury. The seizure of the values from the churches in 1922 lasted too long time. The concentration of the values in Moscow took several years. Having “realized” values authorities initially announced preliminary and demonstrative purchase of the food at a very small amount — 1 million of gold rubles. Then the sale of the church values for soviet depreciated rubles made by the Central Committee for Famine Relief of the all-Russian С.E.C. to Narcomfi n according to agreement of 29 July 1922 was likewise presented by the soviet leaders. The article describes the history of the fruitless efforts undertaken by the members of Pomgol CC to obtain the gold credits, and points out more correct official cost of the seized values. As an important conclusion the author asserts that the policy of double standards pursued by the Narkomfin in the assessment of the seized church property let the financial department under the pretext of ‘’famine relief’’ get a signifi cant profi t
Estratégias de micropropagação de calibrachoa sellowiana (sendtn.) wijsman e rosmarinus officinalis l
No full textTCC (graduação)- Universidade Federal de Santa Catarina. Campus Curitibanos. Agronomia.A micropropagação de plantas é uma estratégia, que se vem ao encontro das necessidades dessas duas espécies aqui apresentadas o Rosmarinus officinalis e Calibrachoa sellowiana ambas com potencial econômico a ser explorado. O Alecrim (R. officinalis) planta de origem do Mediterrâneo, possui características medicinais, podendo ser amplamente utilizado na indústria de cosméticos e medicamentos. A Petúnia (C. sellowiana) com seus atributos ornamentais, com valor de conservação e pioneira na recuperação de áreas degradadas e, por se tratar de uma espécie nativa dos campos sulinos, do Bioma Mata Atlântica tem um alto valor ecológico. Além disto, esta duas espécies possuem características para ser adotada como fonte de renda alternativa para agricultores. No presente trabalho segmentos nodais e apicais foram extraídos de plantas matrizes de Rosmarinus officinalis e de Calibrachoa sellowiana, foram utilizados em diferentes protocolos para a micropropagação através do cultivo em meio de cultura com diferentes tipos e concentrações de fitorreguladores, durante a indução, regeneração e alongamento de brotos. Para a introdução in vitro de Rosmarinus officinalis foram testados 11 tratamentos: 1) MSB isento de fitorreguladores; 2) ácido naftalenoacético - ANA (1 μM); 3) ANA (2 μM); 4) a combinados de ANA (1 μM) com Benzilaminopurina - BAP (1 μM); 5) ANA (1 μM) com BAP (4 μM); 6) ANA (2 μM) com BAP (1 μM); 7) ANA (2 μM) com BAP (2 μM); 8) ANA (2 μM) com BAP (4 μM); 9) BAP (1 μM); 10) BAP (2 μM) e; 11) BAP (4 μM). Para promover a proliferação e a regeneração múltiplas de brotos, os calos e as brotações, foram repicados em três diferentes meios de cultura: 1) ANA (2 μM) + BAP (4 μM); 2) MS + ANA (0,1 μM) + BAP (1 μM) e; 3) MS isento de fitorreguladores. Em R. officinalis observou-se que mais de 43,6% dos explantes apresentaram um tipo de contaminação e 30 % destes revelaram a presença de oxidação e a formação de calo e brotos foi de 56,4%, após 5 semanas de cultivo. A permanência de contaminações com bactérias endógenas evidencia a necessidade de uso de antibióticos no meio de cultivo. Além disto, a alta porcentagem de oxidação e necrose das culturas sugere o uso de antioxidantes durantes os subcultivos. Portanto uma das possíveis estratégias para a micropropagação do alecrim é pela via de organogênese direta, pela ocorrência de regeneração de brotos diretamente dos explantes e pela via indireta, com a indução de calo seguida da regeneração de brotos. Em C. sellowiana, a indução e estabelecimento in vitro das culturas foi conduzida em seis tratamentos, com a suplementação ao meio de cultura básico MSB com diferentes combinações de ácido naftalenoacético - ANA (0 e 0,1 μM) combinados com Benzilaminopurina - BAP (0; 0,5 e 1,0 μM). Regeneração e Multiplicação de Brotos. Brotações e culturas nodulares induzidas e estabelecidas in vitro, foram repicadas para promover a proliferação e a regeneração de brotações múltiplas, em dois diferentes meios de cultura básico MSB suplementado com a combinações dos fitorreguladores: 1) ANA (0,1 μM) e BAP (0,5 μM) e; 2) ANA (0,1 μM) e BAP (1,0 μM). Para a regeneração e o alongamento, os brotos foram repicados para frascos tipo conserva (340 ml) em meio de cultura MSB e isento de fitorreguladores. Brotações com 3-5 cm de altura foram retiradas das folhas para evitar a desidratação e imersa em solução de Ácido Indolilbutírico – AIB (50 ppm) para a indução de enraizamento e transferidas para a substratos para promover a aclimatização. O uso do meio de cultura MSB suplementado com ANA (0,1 μM) mais BAP (1,0 μM) promoveu a alta produção de brotos, e o surgimento de culturas do tipo nodular, que posteriormente regeneram em brotações múltiplas. As brotações e estas culturas do tipo nódulos induzidas e estabelecidas in vitro, quando subcultivadas com ANA (0,1 μM) mais BAP (1,0 μM) promoveram uma alta regeneração de brotos. Para a altura (cm) das plantas, as médias mais elevadas foram obtidas nos tratamentos contendo ANA (0,1 μM) e em MS sem a suplementação de fitorreguladores. Enquanto que, a suplementação ao MSB com ANA (0,1 μM) em combinação com BAP resultou em média maior e significativo número médio e micro brotos por explantes. Portanto, a estratégia para a micropropagação da C. sellowiana se caracteriza pelo modelo da organogênese via formação de nódulos como às culturas nodulares
Deacidification Of Palm Oil By Solvent Extraction
No full textCoordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)The present work reports the influence of some process variables on the losses/transfer of fatty compounds during the deacidification of palm oil by liquid-liquid extraction. The response surface methodology (RSM) was used to analyze the effect of the mass ratio of oil to solvent and the water content in the solvent, aiming to minimize the losses of neutral oil and maximize the transfer of free fatty acids plus carotenoids preservation. By using appropriate conditions observed in RSM analysis (mass ratio of oil to solvent equal to 0.74 and water content around 6 mass%), the deacidification of palm oil by continuous liquid-liquid extraction was performed in a perforated rotating disc contactor (PRDC). The experimental results indicate that it is possible to obtain refined palm oil with a free acidity lower than 0.1 mass% by continuous liquid-liquid extraction. © 2016 Elsevier B.V. All rights reserved.160106111CAPES, Coordenação de Aperfeiçoamento de Pessoal de Nível Superior00/01685-7, FAPESP, Coordenação de Aperfeiçoamento de Pessoal de Nível Superior01/13733-9, FAPESP, Coordenação de Aperfeiçoamento de Pessoal de Nível Superior12/23203-1, FAPESP, Coordenação de Aperfeiçoamento de Pessoal de Nível Superior14/09446-4, FAPESP, Coordenação de Aperfeiçoamento de Pessoal de Nível Superior308024/2013-3, CNPq, Coordenação de Aperfeiçoamento de Pessoal de Nível Superior99/12033-1, FAPESP, Coordenação de Aperfeiçoamento de Pessoal de Nível SuperiorCoordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)Barison, Y., Palm oil (2005) Bailey's Industrial Oil and Fat Products, 2, pp. 333-429. , F. 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O uso das medidas provisórias no estado democrático de direito brasileiro
No full textTese [doutorado) - Universidade Federal de Santa Catarina, Centro de Ciências Jurídicas. Programa de Pós-Graduação em Direito.Análise crítica do uso abusivo das medidas provisórias pelo Poder Executivo brasileiro desde 1988 até o advento da Emenda Constitucional Nº 32/2001, com as conseqüências que isso acarretou ao Estado Democrático de Direito tal qual como configurado pela Constituição Federal de 1988, pela violação de vários princípios constitucionais conformadores deste tipo de Estado. Demonstração das inconstitucionalidades praticadas em colaboração pelos poderes Executivo, Legislativo e Judiciário, pautando-se pela apresentação de exemplos. Apreciação da regulamentação do uso das medidas provisórias feita pela EC 32/01, ressaltando as ainda excessivas possibilidades de lesão do Estado Constitucional e Democrático de Direito Brasileiro por essa espécie normativa
