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Sodyum-oksıjen pillerde katalizörlerin etkilerinin araştırılması
Cataloged from PDF version of article.Includes bibliographical references (leaves 58-67).The unique electrochemical and chemical features of sodium oxygen (Na-O2) batteries distinguish them from the lithium-oxygen (Li-O2) batteries. NaO2, which is the main discharge product, is unstable in the cell environment and its dissolution in the electrolyte triggers side products formation and charging potential increment. In the rst part of this thesis, RuO2 nanoparticles (NPs) dispersed on carbon nanotubes (CNTs) are used as a catalyst for Na-O2 batteries to elucidate the e ect of catalyst on this complex electrochemical system. RuO2/CNT contributes to the formation of a poorly crystalline and coating like NaO2 structure during oxygen reduction reaction (ORR) which is drastically di erent from the conventional micron sized cubic NaO2 crystals deposited on CNT. Our ndings demonstrate a competition among NaO2 and side products decompositions for RuO2/CNT during oxygen evolution reaction (OER). We believe that this is due to the lower stability of coating like NaO2 because of its non-crystalline nature and high electrode/electrolyte contact area. Although RuO2/CNT catalyzes the decomposition of side products at a lower potential (3.66 V) compared to CNT (4.03 V), it cannot actively contribute to the main electrochemical reaction of the cell during OER (NaO2→ Na+ + O2 + e{ ) due to the fast chemical decomposition of lm NaO2 to side products. Even though the long term e ect of RuO2 catalyst during cycling and resting tests seems to be positive in terms of lower overpotential, no bene ts of catalyst is observed for stability and e ciency of the cell for the rst cycles. Therefore, tuning the morphology and crystallinity of NaO2 by catalyst is detrimental for Na-O2 cell performance and it should be taken into account for the future applications. In the second part of this thesis, a 3D RuO2/Mn2O3/carbon nano ber (CNF) composite has been prepared as a bi-functional electrocatalyst towards oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) in Na-O2 batteries. RuO2/Mn2O3/CNF exhibited higher speci c capacity (9352 mAh.gcarbon -1) than CNF (1395 mAh.gcarbon -1), Mn2O3/CNF (3108 mAh.gcarbon -1) and RuO2/CNF (4859 mAh.gcarbon -1), which is believed to be due to its higher active surface area than its counterparts and its unique morphology. Taking the bene t of RuO2 and Mn2O3 synergistic e ect, the decomposition of inevitable side products at the end of charge occurs at 3.838 V vs. Na/Na+ by using RuO2/Mn2O3/CNF, which is 388 mV more cathodic compared with CNF.by Mohammad Fathi Tovini
Building surveyor in property maintenance management / Wan Mohammad Fathi Wan Nawang
The quality of the personality and character needed for managerial position are no longer themselves for conduct of the business. In the presenty highly competitive world, they need to be supplemented by extensive specialist knowledge
Going Beyond Counting First Authors in Author Co-citation Analysis
The present study examines one of the fundamental aspects of author co-citation analysis (ACA) - the way co-citation
counts are defined. Co-citation counting provides the data on which all subsequent statistical analyses and mappings
are based, and we compare ACA results based on two different types of co-citation counting - the traditional type that
only counts the first one among a cited work's authors on the one hand and a non-traditional type that takes into
account the first 5 authors of a cited work on the other hand. Results indicate that the picture produced through this non-traditional author co-citation counting contains more coherent author groups and is therefore considerably clearer. However, this picture represents fewer specialties in the research field being studied than that produced through the traditional first-author co-citation counting when the same number of top-ranked authors is selected and analyzed. Reasons for these effects are discussed
Variations on the Author
“Variations on the Author” discusses two of Eduardo Coutinho’s recent films (Um Dia na Vida, from 2010, and Últimas Conversas, posthumously released in 2015) and their contribution to the general question of documentary authorship. The director’s filmography is characterized by a consistent yet self-effacing form of authorial self-inscription: Coutinho often features as an interviewer that rather than express opinions propels discourses; an interviewer that is good at listening. This mode of self-inscription characterizes him as an author who is not expressive but who is nonetheless markedly present on the screen. In Um Dia na Vida, however, Coutinho is completely absent form the image, while Últimas Conversas, on the contrary, includes a confessional prologue that moves the director from the margins to the center of his films. This article examines the ways in which these works stand out in the filmography of a director who offers new insights into the notion of cinematic authorship
Appropriate Similarity Measures for Author Cocitation Analysis
We provide a number of new insights into the methodological discussion about author cocitation analysis. We first argue that the use of the Pearson correlation for measuring the similarity between authors’ cocitation profiles is not very satisfactory. We then discuss what kind of similarity measures may be used as an alternative to the Pearson correlation. We consider three similarity measures in particular. One is the well-known cosine. The other two similarity measures have not been used before in the bibliometric literature. Finally, we show by means of an example that our findings have a high practical relevance.information science;Pearson correlation;cosine;similarity measure;author cocitation analysis
Dispelling the Myths Behind First-author Citation Counts
We conducted a full-scale evaluative citation analysis study of scholars in the XML research field to explore just how different from each other author rankings resulting from different citation counting methods actually are, and to demonstrate the capability of emerging data and tools on the Web in supporting more realistic citation counting methods. Our results contest some common arguments for the continued
use of first-author citation counts in the evaluation of scholars, such as high correlations between author rankings by first-author citation counts and other citation
counting methods, and high costs of using more realistic citation counting methods that are not well-supported by the ISI databases. It is argued that increasingly available digital full text research papers make it possible for citation analysis studies to go beyond what the ISI databases have directly supported and to employ more
sophisticated methods
koamabayili/VECTRON-author-checklist: VECTRON author checklist
We have done our best to complete the author checklist relating to the use of animals in the hut study. Note that the objective for the hut study was to evaluate the IRS treatment applications for residual efficacy against Anopheles mosquitoes, including the local An. coluzzii mosquito population. Cows were only used to attract mosquitoes into the huts and no tests were carried out directly on the cows. The author checklist is intended for use with studies where experiments are carried out on animals, which is why we have had such difficulty in completing this for the hut study, as many of the questions do not relate to how the cows were used
Egypt: Mohammad Fathi 'Abd al-'Azim
A document from Amnesty International's Urgent Action Networ
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