161 research outputs found

    Effects of pendent phenol functional groups on secondary coordination spheres of heme like Fe-salen complexes

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    Since the beginning of industrial revolution, burning of fossil fuels has mainly led to increase in atmospheric concentration of CO2 , a Green House Gas (GHG), from 250 ppm to 400 ppm between 1800 and 2012. One way to reduce the burning of fossil fuels and CO2 emission rate is to explore alternative carbon free fuels to meet the energy demand.This project aims at the synthesis and study of metal complexes inspired by biological models that will help better design catalysts to perform water oxidation more effectively.This poster won the Dean, Faculty of Science award (2020). Advisor: Dr. Linus Chiang, Departmen of Chemistry

    21st-century scholarship and Wikipedia

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    Wikipedia, the world’s fifth most-used Web site, is a good illustration of the growing credibility of online resources. In his article in Ariadne earlier this year, “Wikipedia: Reflections on Use and Academic Acceptance”, Brian Whalley described the debates around accuracy and review, in the context of geology. He concluded that ‘If Wikipedia is the first port of call, as it already seems to be, for information requirement traffic, then there is a commitment to build on Open Educational Resources (OERs) of various kinds and improve their quality.’ In a similar approach to the Geological Society event that Whalley describes, Sarah Fahmy of JISC worked with Wikimedia and the British Library on a World War One (WWI) Editathon. There is a rich discourse about the way that academics relate to Wikipedia

    Aerodynamic flow control for a generic truck cabin using synthetic jets

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    This experimental work presents the achievement in drag reduction with the use of active flow control (AFC) for a generic bluff body. Experiments were done in the Chalmers University closed loop wind-tunnel at Reynolds number . The is based on the undisturbed velocity m/s and the width of the model m. The model consists of a simplified truck cabin, characterized by sharp edge separation on top and bottom edges and pressure induced separation on the rounded vertical side edges. The pressure induced separation reproduces the flow detachment occurring at the front A-pillar of a real truck. The investigation of the unactuated and actuated flow was conducted by means of time-resolved particle image velocimetry (PIV). Loudspeakers were used as the actuation device. These were characterized before the actuation study, highlighting an interesting analogy between actuation frequency and jet vortex pair size. The effects of different actuations were evaluated with hot wire anemometry. The effect of the actuation was studied using phase averaging and modal analysis. A notable reduction of the side recirculation bubble was observed. The nature of the separation mechanism was investigated and related to different actuation frequencies spanning the range . As for the , the non-dimensional frequency is based on the undisturbed velocity and the width of the model W

    Validation of PANS and active flow control for a generic truck cabin

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    This paper presents a drag reduction study using active flow control (AFC) on a generic bluff body. The model consists of a simplified truck cabin, characterized by sharp edge separation on top and bottom edges and pressure induced separation on the two other rounded vertical front corners. The pressure induced separation reproduces the flow detachment occurring at the front A-pillar of a real truck (Schuetz, 2015). The prediction of the flow field by partially averaged Navier-Stokes (PANS) simulations, conducted on a relatively coarse mesh, is validated against wind tunnel data (pressure measurements and particle image velocimetry (PIV)) and resolved large eddy simulations (LES) data. The Reynolds number for both simulations and experiments is Re=5×10^5 (which corresponds to 1/6 of a full scale truck Re) based on the inlet velocity Uinf and the width of the model W=0.4m. A validation of PANS results is followed by a CFD study on the actuation frequency that minimizes the aerodynamic drag and suppresses the side recirculation bubbles. PANS accurately predicts the flow field measured in experiments and predicted by a resolved LES. The side recirculation bubble of a simplified truck cabin model is suppressed almost completely and a notable drag reduction by means of AFC is observed

    How Many Answers Are Enough? Optimal Number of Answers for Q&A Sites

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    With the proliferation of the social web, questions about information quality and optimization attract the attention of IS scholars. Question-answering (QA) sites, such as Yahoo!Answers, have the potential to produce good answers, but at the same time not all answers are good and not all QA sites are alike. When organizations design and plan for the integration of question answering services on their sites, identification of good answers and process optimization become critical. Arguing that ‘given enough answers all questions are answered successfully,’ this paper identifies the optimal number of posts that generate high quality answers. Based on content analysis of Yahoo! Answers’ informational questions (n=174) and their answers (n=1,023), the study found that seven answers per question are ‘enough’ to provide a good answer

    Predictive Capability Assesment of Finite Element Model using Digital Image Correlation (DIC)

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    The goal of this thesis is to improve the predictive capability of Finite element (FE) by gathering data from experimental test and implement the characteristics into the material model that is used. FE is a commonly used method to predict the mechanical behavior of materials and components during applied forces. Therefore, it’s an important part of product development since it gives an opportunity to lower the costs as well as saving resources since it reduces the number of experimental tests. The method for this thesis was to first simulate tensile tests in Abaqus and then to analyze its results. Once all the simulations were done, we replicated the simulation with experimental tests. This was done with DIC (Digital Image Correlation) to help gather data. Since the goal of this thesis is to see how the predictive capability of the FEM-simulation can be improved the results are compared and discussed to see what from the FEM-simulation matches the DIC results and what does not. This will help understand what in the material model that needs to be changed to better match the testing. DIC is a non-contact method that is used to measure deformations and strain locally over an area which results in a more detailed view of the mechanical behavior of the material. The idea of using DIC during this thesis is to sample enough valuable data and apply it to the original material model of the FE-simulations to increase the predictive capability. After the results from the experimental tests were analyzed it was clear that there were both resemblances and differences in the results, for example the Young’s modulus in the FEM-calculations was higher than it was for the experimental tests, Yield strength was lower in the FEM-calculations compared to the experimental tests, maximum load at fracture was lower in the FEM-calculations compared to the experimental tests and elongation was lower in the FEM-calculations compared to the experimental tests. The FEM-calculations were based of the assumptions that the material was homogenous but that wasn’t the case for the experimental tests. Due to the strain varying over the tests the material model could be improved by adding a statistical variation, to all the elements to give them varying mechanical properties simulate how the strain vary more correctly over the specimen.

    Predictive Capability Assesment of Finite Element Model using Digital Image Correlation (DIC)

    No full text
    The goal of this thesis is to improve the predictive capability of Finite element (FE) by gathering data from experimental test and implement the characteristics into the material model that is used. FE is a commonly used method to predict the mechanical behavior of materials and components during applied forces. Therefore, it’s an important part of product development since it gives an opportunity to lower the costs as well as saving resources since it reduces the number of experimental tests. The method for this thesis was to first simulate tensile tests in Abaqus and then to analyze its results. Once all the simulations were done, we replicated the simulation with experimental tests. This was done with DIC (Digital Image Correlation) to help gather data. Since the goal of this thesis is to see how the predictive capability of the FEM-simulation can be improved the results are compared and discussed to see what from the FEM-simulation matches the DIC results and what does not. This will help understand what in the material model that needs to be changed to better match the testing. DIC is a non-contact method that is used to measure deformations and strain locally over an area which results in a more detailed view of the mechanical behavior of the material. The idea of using DIC during this thesis is to sample enough valuable data and apply it to the original material model of the FE-simulations to increase the predictive capability. After the results from the experimental tests were analyzed it was clear that there were both resemblances and differences in the results, for example the Young’s modulus in the FEM-calculations was higher than it was for the experimental tests, Yield strength was lower in the FEM-calculations compared to the experimental tests, maximum load at fracture was lower in the FEM-calculations compared to the experimental tests and elongation was lower in the FEM-calculations compared to the experimental tests. The FEM-calculations were based of the assumptions that the material was homogenous but that wasn’t the case for the experimental tests. Due to the strain varying over the tests the material model could be improved by adding a statistical variation, to all the elements to give them varying mechanical properties simulate how the strain vary more correctly over the specimen.

    Power Relations and Social Classes in Pengakuan Pariyem by Linus Suryadi AG: Reflection of Masculine Ideology

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    The study aims to explore power relations and social classes as the reflections of the masculine ideology of the author in the novel Pengakuan Pariyem by Linus Suryadi AG. The theories implemented in the study are van Dijk’s power relations and social classes theory and Connell’s masculinity theory. The study is qualitative descriptive and applies the Critical Discourse Analysis (CDA) method, used to dismantle the ideology that is produced and reproduced through the language within the novel. The research data are lingual units that indicate power relations and social classes which simultaneously reflect the notion of masculinity.  The results of the study are as follows. First, Pariyem as the central character in the novel lives within a hierarchical and dualistic Javanese society. Her submission as the babu (housemaid) of a priyayi (noble) family does not only lead Pariyem to be dominated symbolically, but also legitimizes the priyayi (aristocrats) power over wong cilik (commoners).  It is reinforced by the representations of the priyayis’ world views in terms of culture, aristocracy, bureaucracy, and education orientation. It shows that priyayis are culturally dominant. Secondly, since Pariyem is a character created by a male author, her behaviors and actions reflect the ideology of masculinity. Rather than voicing women, the power relations that Pariyem experiences through the events constructed in the novel show that she embodies the masculine ideology, or masculinity. 

    As the twig is bent, globalization

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