1,757 research outputs found
A narrative-based collaborative writing tool for coherent technical documents
No full textOne important feature of an effective document that makes it easy to read and understand is known as coherence. Technical documents produced collaboratively are often incoherent due to a lack of group consensus and misaligned contributions by the individual authors. However, current document planning techniques and writing tools do not provide explicit support for improving coherence. The goal of this research, therefore, is to develop and evaluate a new technique and tool that helps teams of authors to structure coherent technical documents. The coherence of a document can be attributed to the story (or narrative) it conveys to the reader. If this story is consistent and coherent, the same can be said about the document. A discourse theory such as Rhetorical Structure Theory (RST) that has been developed by linguists helps further to analyse and improve a narrative. RST explains the coherence of a text by virtue of relationships (such as “paragraph A justifies paragraph B”) between parts of the text. This research has combined the ideas from these parallel strands of research to develop a new document planning technique called narrative-based writing. The method involves writing down an explicit précis of the story (called a document narrative or DN) and then analysing it using RST. The DN and RST analysis are then used to structure the eventual document. To extend the usability of narrative-based writing to geographically-dispersed authors, I have designed and implemented a collaborative tool that allows co-authors to edit, analyse and review DNs. The thorough design for the tool uses a combination of three models (conceptual, business process and functional) culminating in a set of functions that enable collaborative narrative-based writing. This dissertation discusses how, in the future, these functions could be incorporated in existing collaborative writing tools. Implementing this tool, albeit in its current prototypic state, has been invaluable in understanding the complexities of modelling and manipulating DNs and RST structures. Initial investigations using the new technique and tool have been positive, encouraging me to continue the research and evaluation in this field
Evaluatie suppleties Noord-Holland en Texel
No full textNote: NH-93.ANV002a.pdf bevat het hoofdrapport en NH-93.ANV002b.pdf bevat alle bijlagen. ----- De minister van Verkeer en Waterstaat heeft de kamer een interim-nota kustverdediging in 1993 toegezegd, waarin het kustverdedigingsbeleid wordt geëvalueerd. Een onderdeel van deze evaluatie is de evaluatie van de zandsuppleties. Om deze evaluatie uit te voeren is de werkgroep EVAZAND, onder leiding van de Dienst Getijdewateren, ingesteld. De evaluatie beperkt zich in principe tot de morfologische aspecten en is hoofdzakelijk gericht op het bepalen van de doelmatigheid of de effectiviteit van zandsuppleties. Omdat suppleties van 1990 of later zich vanwege de korte levensduur nauwelijks lenen voor evaluatie is een selectie gemaakt uit de suppleties van vóór 1990. Deze nota dient als de bijdrage van de Directie Noord-Holland aan het project EVAZAND en bevat de evaluatie van alle grote zandsuppleties van Noord-Holland en Texel van vóór 1990.EVAZAN
Methyl 5-methyl-3,4-diphenyl-1H-pyrrole-2-carboxylate
No full textThe title compound, C19H17NO2, forms dimeric aggregates in the solid state due to the pyrrole-NH-carboxyl-O hydrogen bonds
Stabilisation of alkylcarbamate anions using neutral hydrogen bond donors
No full textThe interactions of a series of urea-based anion receptors and alkylcarbamate species formed by the reaction of carbon dioxide with primary amines have been investigated by 1H NMR. Significant downfield shifts in the NH proton signals of the receptors in the presence of the alkylcarbamates were observed, consistent with classical host:anion hydrogen-bonding. This observation demonstrates that neutral hydrogen bond donor receptors can compete with ammonium cations to bind carbamates in DMSO-d6 solution.<br/
Dehydrogenation of the NH−NH Bond Triggered by Potassium tert-Butoxide in Liquid Ammonia
No full textA novel strategy for the dehydrogenation of NH-NH bond is disclosed using potassium t-butoxide (tBuOK) in liquid NH3 under air (O2) at room temperature. Its synthetic values are well demonstrated via highly efficient synthesis of aromatic azo compounds (up to 100% yield, 3 min), heterocyclic azo compounds, and dehydrazination of phenylhydrazine. The broad application of this strategy and its benefit to chemical biology is proved by a novel, convenient, one-pot and efficient synthesis of aliphatic diazirines, which are important photoreactive agents for photoaffinity labeling
Molecular tagging velocimetry of NH fluorescence in a high-enthalpy rarefied gas flow
No full textIn this paper a new type of molecular tagging velocimetry based on NH fluorescence was developed and validated for the velocity measurements of a high-enthalpy rarefied gas wind tunnel where the maximum flow velocity exceeds 6 km/ s near the nozzle exit at 0.2 Pa. The feasibility of this technique using the short-lived NH fluorescence was demonstrated in the hypersonic rarefied gas flow with yielding velocity profiles at multiple downstream locations from the nozzle exit. The total uncertainty of the measured flow velocities was estimated to be less than 6% when the flow velocity is above 2000 m/ s. For the new tagging technique only a single laser and a single time-gated camera are required for velocity measurement due to the existence of NH radicals in the arc-discharged-N2 mixed with a small amount of H-2. Therefore the NH-MTV not only shows great promise for tagging in high-enthalpy rarefied gas of nitrogen or air flows without seeding but also possesses high practicability and facility for velocity measurement
Interactions of organic halide and nitrate salts with meso-octamethylcalix[4]pyrrole
No full textProton NMR titrations have been performed with meso-octamethylcalix[4]pyrrole and a variety of organic chloride and bromide salts in dichloromethane-d2. The results show apparently increasing chloride stability constants within each set of anion salts (tetrabutylammonium < imidazolium < pyridinium). Addition of 1-ethyl-3-methylimidaolium (EMIM) nitrate to dichloromethane-d2 solutions of calix[4]pyrrole caused significantly larger downfield shifts of the pyrrole NH protons of calix[4]pyrrole than addition of equimolar quantities of tetrabutylammonium nitrate. The first crystal structure of a nitrate complex of a calix[4]pyrrole is also presented
Un lema a revisar en Plinio, NH XXXII 149
No full textAt Plinius, NH XXXII 149, the author conjetures ...lepus... lupus... for ...elepris... lepus....No disponible
High-affinity anion binding by steroidal squaramide receptors
No full textExceptionally powerful anion receptors have been constructed by placing squaramide groups in axial positions on a steroidal framework. The steroid preorganizes the squaramide NH groups such that they can act cooperatively on a bound anion, while maintaining solubility in nonpolar media. The acidic NH groups confer higher affinities than previously-used ureas or thioureas. Binding constants exceeding 1014?M?1 have been measured for tetraethylammonium salts in chloroform by employing a variation of Cram’s extraction procedure. The receptors have also been studied as transmembrane anion carriers in unilamellar vesicles. Unusually their activities do not correlate with anion affinities, thus suggesting an upper limit for binding strength in the design of anion carrier
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