117,465 research outputs found

    Photoelectron spectroscopy of atomic oxygen using the Elettra synchrotron source

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    Atomic oxygen has been studied using angle resolved photoelectron spectroscopy (PES) and constant-ionic-state (CIS) measurements using radiation from the Elettra synchrotron as the photon source. Relative partial photoionization cross-sections and angular distributions for the O+(S-4) ? O(P-3) and O+(D-2) ? O(P-3) ionizations have been measured as a function of photon energy from threshold (13.6 eV) to 19.0 eV. Comparison of the results obtained with recent experimental work performed at lower resolution reveals a number of differences and comparison with results of recent calculations shows the need for the inclusion of coupling intermediate between the j-j and L-S limits in future calculations of photoionization cross-sections and angular distributions. This work has demonstrated the feasibility of and results to be expected from angle resolved PES and CIS measurements on reactive intermediates at Elettra, a third-generation synchrotron source, and further studies on small molecular radicals are proposed

    Photoelectron spectroscopy of atomic oxygen using the Elettra synchrotron source

    No full text
    Atomic oxygen has been studied using angle resolved photoelectron spectroscopy (PES) and constant-ionic-state (CIS) measurements using radiation from the Elettra synchrotron as the photon source. Relative partial photoionization cross-sections and angular distributions for the Oþð4SÞ Oð3PÞ and Oþð2DÞ Oð3PÞ ionizations have been measured as a function of photon energy from threshold (13.6 eV) to 19.0 eV. Comparison of the results obtained with recent experimental work performed at lower resolution reveals a number of differences and comparison with results of recent calculations shows the need for the inclusion of coupling intermediate between the j–j and L–S limits in future calculations of photoionization crosssections and angular distributions. This work has demonstrated the feasibility of and results to be expected from angle resolved PES and CIS measurements on reactive intermediates at Elettra, a third-generation synchrotron source, and further studies on small molecular radicals are proposed

    Going Beyond Counting First Authors in Author Co-citation Analysis

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    The present study examines one of the fundamental aspects of author co-citation analysis (ACA) - the way co-citation counts are defined. Co-citation counting provides the data on which all subsequent statistical analyses and mappings are based, and we compare ACA results based on two different types of co-citation counting - the traditional type that only counts the first one among a cited work's authors on the one hand and a non-traditional type that takes into account the first 5 authors of a cited work on the other hand. Results indicate that the picture produced through this non-traditional author co-citation counting contains more coherent author groups and is therefore considerably clearer. However, this picture represents fewer specialties in the research field being studied than that produced through the traditional first-author co-citation counting when the same number of top-ranked authors is selected and analyzed. Reasons for these effects are discussed

    Study of the electronic structure of the actinide tetrabromides ThBr4 and UBr4 using ultraviolet photoelectron spectroscopy and density functional calculations

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    Ultraviolet photoelectron spectra of UBr4 and ThBr4 have been recorded in the gas-phase and interpreted using relativistic density functional calculations. For ThBr4, eight bands were observed which are interpreted as ionization from the five Br 4p symmetry orbitals of a Br-4 unit in T-d symmetry, with three of the bands [the (4t(2))(-1), (1t(1))(-1), and (3t(2))(-1) ionizations] each being split into two by spin-orbit interaction. The observed splittings are rationalized in terms of the Th 6p and Br 4p contributions to the orbitals and by comparison with the known ultraviolet photoelectron spectra of ThF4 and ThCl4. The first vertical ionization energy (VIE) of ThBr4 was measured as (10.92 +/-0.03) eV. UBr4 shows a very similar photoelectron spectrum with an extra band at (9.65 +/-0.02) eV VIE. This is associated with a (5t(2))(-1) (U 5f,6d) ionization. Supporting matrix isolation infrared experiments were also carried out under very similar vaporization conditions to those used in the photoelectron spectroscopy experiments to check the composition of the vapor beams used. In these experiments, the T-2 stretching modes of ThBr4 and UBr4 have been measured as 230 +/-2 and 239 +/-2 cm(-1), respectively. Both the photoelectron and infrared matrix isolation spectra are consistent with an effective tetrahedral geometry for UBr4 and ThBr4

    Square Dancing with the Stars to Enhance Dynamic Hirschman Linkages?

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    In this Presidential Address, the author takes the reader on a reconnaissance of his life and time as a regional scientist. He points out scenery he found scintillating along the way, hoping that some may pick up the banner and chew on a few of the ideas for a while. He suggests a revisit to Albert O. Hirschman’s notion of key sectors and more empirical analysis related to Marcus Berliant’s and Masahisa Fujita’s notion of knowledge creation and transfer.Presidential Address, San Antonio, Texas, March 29, 2014 (53rd Meetings of the Southern Regional Science Association

    Appropriate Similarity Measures for Author Cocitation Analysis

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    We provide a number of new insights into the methodological discussion about author cocitation analysis. We first argue that the use of the Pearson correlation for measuring the similarity between authors’ cocitation profiles is not very satisfactory. We then discuss what kind of similarity measures may be used as an alternative to the Pearson correlation. We consider three similarity measures in particular. One is the well-known cosine. The other two similarity measures have not been used before in the bibliometric literature. Finally, we show by means of an example that our findings have a high practical relevance.information science;Pearson correlation;cosine;similarity measure;author cocitation analysis

    Letter from unknown writer to Jesse L. Boyce

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    Letter to Jesse L. Boyce from unknown author (possibly Jack) about the investigation into the powder magazine located in the Grand Canyon. Some personal news is included in the letter such as the writer's marriage to the daughter of C.A. Taylor, former Supervisor of Cochise County

    Dispelling the Myths Behind First-author Citation Counts

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    We conducted a full-scale evaluative citation analysis study of scholars in the XML research field to explore just how different from each other author rankings resulting from different citation counting methods actually are, and to demonstrate the capability of emerging data and tools on the Web in supporting more realistic citation counting methods. Our results contest some common arguments for the continued use of first-author citation counts in the evaluation of scholars, such as high correlations between author rankings by first-author citation counts and other citation counting methods, and high costs of using more realistic citation counting methods that are not well-supported by the ISI databases. It is argued that increasingly available digital full text research papers make it possible for citation analysis studies to go beyond what the ISI databases have directly supported and to employ more sophisticated methods

    Sarah L. Blum Author Visit - Warrior Nurse: PTSD and Healing

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    Hear Sarah L. Blum, author of Women Under Fire: Abuse in the Military, discuss her newest book, Warrior Nurse: PTSD and Healing followed by a Q&A and book signing. Sarah L. Blum is a decorated Vietnam veteran who served as an operating room nurse during the intense fighting of 1967. In recognition of her service, she was awarded the Army Commendation Medal. Sponsored by CWU Veterans Center and CWU Libraries.https://digitalcommons.cwu.edu/libraryevents/1252/thumbnail.jp
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