IR@NEIST - North East Institute of Science and Technology (CSIR)
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    339 research outputs found

    Microwave-promoted one-pot synthesis of 4H-thiopyrans from a,b-unsaturated ketones via a three-component reaction

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    —An efficient one-pot synthesis of substituted 4H-thiopyrans has been accomplished from a three-component reaction of a,b-unsaturated ketones, Lawesson’s reagent and alkynes under microwave irradiation

    Esterification of lauric acid with lauryl alcohol using cross-linked enzyme crystals: Solvent effect and kinetic study

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    In this paper, we report a comprehensive kinetic study on esterification of lauric acid with lauryl alcohol catalyzed by commercial porcine pancreatic lipase (PPL) in the form of cross-linked enzyme crystals (CLEC) using glutaraldehyde as thecrosslinker.ThestabilityoftheCLECwasbetter thantheimmobilized enzymefor practicalapplications.Comparative studies using six different solvents having hydrophobicity (log p) values ranging from 0.70 to 3.50 revealed that the esterification reaction was favoured in hydrophobic solvents. The kinetics of the esterification reaction conformed with the so-called Ping-PongBi-Bi mechanism with alcohol inhibition

    EXTENT OF LEAD IN HIGH-SULFUR ASSAM COALS

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    This study has been undertaken to understand the precise nature of association of lead in high sulphur Assam coal. Sequential extraction of lead with ammonium acetate, HCl and RuCl 3 solutions havebeen carriedout. RuCl3 hasbeenusedasasuitable reagent fortheextractionoflead.Itisfound thattreatment ofsamplewithCCl 4increasestheextractionofleadbyRuCl 3solution. Theamountof leadinthecoalstudiedvariesbetween43.2and50.4ppm.Ithasbeenfoundthatleadispredominantly occurring in coals in association with organic matter and needs concerted attention to understand its bio-availability. The chemical principles involved therein are also discussed. D 2004 Elsevier B.V. All rights reserved

    Deposition fluxes of chemical components of fog water at a rural site in North East India

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    The north-eastern part of India has not been investigated for atmospheric deposition studies so far. In this study, deposition fluxes on an artificial surface of chemical components due to fog have been calculated during winter from December 2002 to January 2003 at Jorhat, a rural site in north-east India. As the land in this area is covered with vegetation, the site is representative of rural characteristics in this region. The average pH of fog water is 5.6. Among chemical components, NH+ 4 was observed to be dominating ion. Soil pH in this region is acidic (4.9). Unlike other parts of the country, chemical analysis of soil in this region revealed that influence of suspended soil dust on fog deposition was insignificant. A comparison of fluxes of fog with rain water during December–January months showed that deposition fluxes due to rain water were higher by almost one order of magnitude on an artificial surface but on natural surfaces, the fluxes may be comparabl

    STEREOSELECTIVE INTRAMOLECULAR HETERO-DIELS-ALDER REACTIONS OF 1-OXA-1,3-BUTADIENES - SYNTHESIS OF NOVEL ANNELATED PYRROLO[1,2-A]INDOLES

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    14Novelclassesofpyrano-1,3-dioxane-,pyranopyrimidine-andpyranopyrazole-fusedpyrrolo[1,2-a]indolesaresynthesised via stereoselective intramolecular 1-oxa-1,3-butadiene hetero Diels 13Alder reaction

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