37,101 research outputs found

    Monocationic μ-diborolyl triple-decker complexes [CpCo(μ-1,3-C 3B2Me5)M(ring)]+: Synthesis, structures, and electrochemistry

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    Cationic triple-decker complexes with a bridging diborolyl ligand, [CpCo(μ-1,3-C3B2Me5)M(ring)]+ (M(ring) = CoCp (2a), CoCp* (2b), RhCp (3a), RhCp* (3b), IrCp (4a), IrCp* (4b), Ru(C6H6) (5a), Ru(p-MeC 6H4Pri) (5b), Ru(C6Me6) (5c), Ru(η6-cycloheptatriene) (6)), were synthesized by reaction of CpCo(μ-1,3-C3B2Me5)Tl with [M(ring)Hal2]2. The structures of 2aBPh4, 2bPF6, 4aPF6, 5aOTf, and 5cPF6 were determined by X-ray diffraction. The electron-transfer ability of the complexes has been ascertained by electrochemical and spectroelectrochemical techniques. In general, they are able to shuttle reversibly in the sequence 2+/+/0/-, plausibly affording completely delocalized mixed-valence derivatives. DFT calculations revealed structural changes accompanying redox processes and satisfactorily predicted the potentials for the first reduction and first oxidation. © 2013 American Chemical Society

    Development of Movement Skills in Children with the Down Syndrome on Classes in Adaptive Physical Training

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    Annually in Ekaterinburg and the Sverdlovsk region, 40–50 children are born each year with this genetic anomaly. The problem of development and correction of motor disorders in children with Down’s syndrome remains topical. The developed method of adaptive physical education, based on the game method of TEACCH, will help children with Down syndrome improve motor skills, emotional and volitional sphere, which in the future will contribute to successful socialization in society.Ежегодно в Екатеринбурге и Свердловской области рождаются 40–50 детей с синдромом Дауна. Актуальной остается проблема развития и коррекции нарушений двигательной сферы детей с данной генетической мутацией. Разработанная методика адаптивного физического воспитания, основанная на игровом методе TEACCH, поможет детям с синдромом Дауна улучшить двигательные навыки и эмоционально-волевую сферу, что в будущем будет способствовать их успешной социализации

    Modeling of InAs-InSb nanowires grown by Au-assisted chemical beam epitaxy

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    Interesting phenomena during the Au-assisted chemical beam epitaxy of InAs-InSb nanowire heterostructures have been observed and interpreted within the framework of a theoretical model. An unusual, non-monotonous diameter dependence of the InSb nanowire growth rate is demonstrated experimentally within a range of deposition conditions. Such a behavior is explained by competition between the Gibbs-Thomson effect and different diffusion-induced material fluxes. Theoretical fits to the experimental data obtained at different flux pressures of In and Sb precursors allow us to deduce some important kinetic coefficients. Furthermore, we discuss why the InAs nanowire stem forms in the wurtzite phase while the upper InSb part has a pure zinc blende crystal structure. It is hypothesized that the 30 degrees angular rotation of nanowire when passing from InAs to the InSb part is driven by the lowest surface energy of (1(1) over bar 00) wurtzite and (110) zinc blende facets.ICM

    Informetrics on M. N. Srinivas

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    M. N. Srinivas, the well known sociologist is widely recognised as architect of modern Indian sociology and social anthropology. His publications have been analysed by year, domain, authorship pattern, channels of communication used. Keywords, etc. The results indicate that the papers published by him are of a nature that qualify him to be a 'role model' for the younger generations to emulate. By the end of 1995, Srinivas had to his credit 144 papers which, included 33 broad papers in sociology and anthropology; 18 papers in social change; 28 papers in village studies; 12 papers on religion; 17 papers on caste and 36 papers of general popular interest. The periods 1958-61 and 1974-77, when Srinivas was 38-41 and 58-61 years old. were his most productive periods with highest publication activity

    Stichotvorenie V. Krivulina‚ Čto rifmovalos'; (1990), refleksija krizisa neoficial'noj kul'tury.

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    Nel olume dedicato all'emblematico anno 1990 in Urss e ai prodromi culturali della Russia post-sovietica, si inserisce uno studio analitico di un testo di Viktor Krivulin, poeta e grande promotore della cultura non conformista sin dagli anni Settanta, che descrive la fine di una esperienza culturale indipendente nata dal rapporto dialettico e con quella ufficiale sovietica

    Illuminaçao Apologetica do retrato de Morteçor en que aparecem com mais vivas côres os erros do author do novo Methodo, e seu Apologista ...

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    Fecha sacada de la pág.2 y 159Sign.: A-V\p4\sError tipográfico de signatura : a B\b2\s llama B\b3\

    Semiconductors V. 37, I. 04

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    Semiconductors -- April 2003 Volume 37, Issue 4, pp. 367-492 ATOMIC STRUCTURE AND NONELECTRONIC PROPERTIES OF SEMICONDUCTORS Structural Disordering and Viedemann–Franz Relation in Melts of Some II–IV–V2 Semiconductors Ya. B. Magomedov and M. A. Aidamirov pp. 367-369 Full Text: PDF (42 kB) ELECTRONIC AND OPTICAL PROPERTIES OF SEMICONDUCTORS Effect of Crystallization of Amorphous Vanadium Dioxide Films on the Parameters of a Semiconductor–Metal Phase Transition V. A. Klimov, I. O. Timofeeva, S. D. Khanin, E. B. Shadrin, A. V. Il'inskii, and F. Silva-Andrade pp. 370-374 Full Text: PDF (165 kB) Recombination Current Instability in Epitaxial p+–n Structures with Impurity Atoms Locally Incorporated into the n-type Region and Determination of the Deep Center Parameters B. S. Muravskii[dagger], O. N. Kulikov, and V. N. Chernyi pp. 375-379 Full Text: PDF (73 kB) Optical Reflection in (Pb0.78Sn0.22)1 – xInxTe Solid Solutions with a High Indium Content A. N. Veis and A. V. Nashchekin pp. 380-383 Full Text: PDF (226 kB) Effect of Lattice Deformation on Semiconducting Properties of CrSi2 A. V. Krivosheeva, V. L. Shaposhnikov, A. E. Krivosheev, A. B. Filonov, and V. E. Borisenko pp. 384-389 Full Text: PDF (109 kB) Electrical Properties of InAs Irradiated with Protons V. N. Brudnyi, N. G. Kolin, and A. I. Potapov pp. 390-395 Full Text: PDF (107 kB) Influence of Pulsed Laser Radiation on the Morphology and Photoelectric Properties of InSb Crystals V. A. Gnatyuk and O. S. Gorodnychenko pp. 396-398 Full Text: PDF (87 kB) IR Birefringence in Artificial Crystal Fabricated by Anisotropic Etching of Silicon E. V. Astrova, T. S. Perova, V. A. Tolmachev, A. D. Remenyuk, J. Vij, and A. Moore pp. 399-403 Full Text: PDF (128 kB) Energy Levels of Vacancies and Interstitial Atoms in the Band Gap of Silicon V. V. Lukjanitsa pp. 404-413 Full Text: PDF (126 kB) SEMICONDUCTOR STRUCTURES, INTERFACES, AND SURFACES Photosensitive Structures Based on ZnIn2Se4 Single Crystals A. A. Vaipolin, Yu. A. Nikolaev, V. Yu. Rud', Yu. V. Rud', and E. I. Terukov pp. 414-416 Full Text: PDF (48 kB) Special Features of Electron Scattering at AlxGa1 – xAs/AlAs(001) Interfaces S. N. Grinyaev, G. F. Karavaev, and V. N. Chernyshov pp. 417-425 Full Text: PDF (117 kB) The Charge Accumulation in an Insulator and the States at Interfaces of Silicon-on-Insulator Structures as a Result of Irradiation with Electrons and Gamma-Ray Photons D. V. Nikolaev, I. V. Antonova, O. V. Naumova, V. P. Popov, and S. A. Smagulova pp. 426-432 Full Text: PDF (92 kB) The Effect of Internal Fields on Tunneling Current in Strained GaN/AlxGa1 – xN(0001) Structures S. N. Grinyaev and A. N. Razzhuvalov pp. 433-438 Full Text: PDF (81 kB) Characteristics of Gallium Arsenide Structures and Gunn Devices Based on Them Fabricated Using the Radiation–Thermal Technology M. V. Ardyshev and V. M. Ardyshev pp. 439-442 Full Text: PDF (54 kB) The Influence of Carbon on the Properties of Si/SiGe Heterostructures M. Ya. Valakh, V. N. Dzhagan, L. A. Matveeva, A. S. Oberemok, B. N. Romanyuk, and V. A. Yukhimchuk pp. 443-447 Full Text: PDF (69 kB) Effect of Irradiation with Low-Energy Ar Ions on the Characteristics of the Working and Rear Sides of Single-Crystal GaAs Substrate A. S. Alalykin, P. N. Krylov, I. V. Fedotova, and A. B. Fedotov pp. 448-451 Full Text: PDF (56 kB) Generation–Recombination Centers in CdTe:V L. A. Kosyachenko, S. Yu. Paranchich, Yu. V. Tanasyuk, V. M. Sklyarchuk, E. F. Sklyarchuk, E. L. Maslyanchuk, and V. V. Motushchuk pp. 452-455 Full Text: PDF (72 kB) Special Features of Formation and Characteristics of Ni/21R-SiC Schottky Diodes V. L. Litvinov, K. D. Demakov, O. A. Ageev, A. M. Svetlichny, R. V. Konakova, P. M. Lytvyn, O. S. Lytvyn, and V. V. Milenin pp. 456-461 Full Text: PDF (235 kB) LOW-DIMENSIONAL SYSTEMS Properties of Ge Nanocrystals Formed by Implantation of Ge+ Ions into SiO2 Films with Subsequent Annealing under Hydrostatic Pressure I. E. Tyschenko, A. B. Talochkin, A. G. Cherkov, K. S. Zhuravlev, A. Misiuk, M. Voelskow, and W. Skorupa pp. 462-467 Full Text: PDF (93 kB) AMORPHOUS, VITREOUS, AND POROUS SEMICONDUCTORS Laser Ultrasonic Study of Porous Silicon Layers S. M. Zharkii, A. A. Karabutov, I. M. Pelivanov, N. B. Podymova, and V. Yu. Timoshenko pp. 468-472 Full Text: PDF (72 kB) Raman Spectroscopy of Amorphous Carbon Modified with Iron S. G. Yastrebov, V. I. Ivanov-Omskii, F. Dumitrache, and C. Morosanu pp. 473-476 Full Text: PDF (52 kB) Electrolytic Fabrication of Porous Silicon with the Use of Internal Current Source D. N. Goryachev, L. V. Belyakov, and O. M. Sreseli pp. 477-481 Full Text: PDF (60 kB) PHYSICS OF SEMICONDUCTOR DEVICES 3C-SiC p–n Structures Grown by Sublimation on 6H-SiC Substrates A. A. Lebedev, A. M. Strel'chuk, D. V. Davydov, N. S. Savkina, A. S. Tregubova, A. N. Kuznetsov, V. A. Solov'ev, and N. K. Poletaev pp. 482-484 Full Text: PDF (53 kB) Current and Temperature Tuning of Quantum-Well Lasers Operating in 2.0- to 2.4-µm Range A. P. Astakhova, A. N. Baranov, A. Viset, A. N. Imenkov, N. M. Kolchanova, N. D. Stoyanov, A. Chernyaev, D. A. Yarekha, and Yu. P. Yakovlev pp. 485-490 Full Text: PDF (80 kB) PERSONALIA Vladimir Ivanovich Ivanov-Omskii (dedicated to his 70th birthday) pp. 491-492 Full Text: PDF (73 kB)Archived web conten

    From the correspondence of M. P. Drahomanov: two unknown letters to M. V. Vodovozov of 1894

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    This publication introduces into scientific discourse little-known letters of prominent Ukrainian scholar, politician and publicist M. P. Drahomanov (1841-1895), discovered in the fond of V. I. Vernadsky in the Archive of the Russian Academy of Sciences in Moscow. Two letters written in the latest period of the life of M. P. Drahomanov, which are addressed to young economist and publicist Mykola Vasyliovych Vodovozov (1870-1896), expand the source base not only for M. P. Drahomanov’s biographers. They show his ties with Russian liberals, who later formed the core of the party of constitutional democrats. A preface to the publication contains a biography of M. V. Vodovozov, and the author makes a hypothesis on the history of an acquaintance of the correspondent and the addressee, which could be connected with M. V. Vodovozov’s brother, V. V. Vodovozov, and members of the “Shelter Fraternity”, and through them with M. P. Drahomanov. The analysis of the published letters proves that M. P. Drahomanov endeavored to widen through the “Shelter Fraternity” members his contacts with democratic circles in Russia, and also to find financial support for publishing letters of Bakunin and Struve

    Fig. 1. Heterocotyle chinensis Timofeeva, 1983 in Heterocotyle chinensis (Monogenea: Monocotylidae) from the Whip Stingray Dasyatis akajei in the Seto Inland Sea, Japan

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    Fig. 1. Heterocotyle chinensis Timofeeva, 1983. NMST-Pl 6164. A, whole mount (ventral view); B, hamulus; C, hooklet; D, male copulatory organ. Scale bars: A, 200 µm; B–D, 10 µm. Abbreviations: alg, anterolateral gland; amg, anteromedian gland; d, duct; dh, dorsal haptoral accessory structure; ej, ejaculatory bulb; ey, eyespots; h, hamulus; ho, hooklet; in, intestine; m, mouth; mag, male accessory gland; mco, male copulatory organ; mg, Mehlis' gland; o, oötype; od, oviduct; ov, ovary; ph, pharynx; pg, posterior gland; phg, pharyngeal glands; r, sinuous ridge; sr, seminal receptacle; sv, seminal vesicle; t, testis; tv, transverse vitelline duct; u, uterus; vi, vitellaria; v, vagina; vp, vaginal pore; vd, vas deferens.Published as part of Nitta, Masato & Nagasawa, Kazuya, 2015, Heterocotyle chinensis (Monogenea: Monocotylidae) from the Whip Stingray Dasyatis akajei in the Seto Inland Sea, Japan, pp. 89-93 in Species Diversity 20 on page 90, DOI: 10.12782/sd.20.1.089, http://zenodo.org/record/573752

    Doklady Physics V.45, I.08

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    Doklady Physics -- August 2000 Volume 45, Issue 8, pp. 359-433 PHYSICS Association in Metallic Melts and Its Relation to Amorphization: Fe–P Alloys A. I. Zaitsev, N. E. Shelkova, and A. D. Litvina pp. 359-362 Full Text: PDF (52 kB) Studies of Mechanical Properties of Quasicrystalline Al–Cu–Fe Phase by the Indentation Technique V. I. Trefilov, Yu. V. Mil'man, D. V. Lotsko, A. N. Belous, S. I. Chugunova, I. I. Timofeeva, and A. I. Bykov pp. 363-366 Full Text: PDF (101 kB) Parabolic Approximation in the Theory of the Sound Propagation in Three-Dimensionally Heterogeneous Media O. A. Godin pp. 367-371 Full Text: PDF (65 kB) Generalized Equation for Inverse Population in a Laser Active Medium A. L. Mikaelyan and Yu. G. Turkov pp. 372-375 Full Text: PDF (55 kB) Self-Organization Processes in a System of Magnetic Moments in Polycrystals V. K. Karpasyuk and E. I. Beznisko pp. 376-379 Full Text: PDF (64 kB) Phonon Spectra for Crystal Lattices of V, Cr, Mn, Fe, Co, Ni, and Cu N. N. Sirota, I. M. Sirota, T. M. Soshnina, and T. D. Sokolovskii pp. 380-383 Full Text: PDF (68 kB) Experimental Study of Inelastic Collisions of Low-Velocity Electrons with Terbium Atoms Yu. M. Smirnov pp. 384-388 Full Text: PDF (61 kB) POWER ENGINEERING Bifurcation of Vortex Turbulent Flow and Intensification of Heat Transfer in a Hollow S. A. Isaev, A. I. Leont'ev, P. A. Baranov, and A. E. Usachev pp. 389-391 Full Text: PDF (104 kB) MECHANICS A Method of Transferring Boundary Conditions by Cauchy–Krylov Functions for Rigid Linear Ordinary Differential Equations A. Yu. Vinogradov and Yu. A. Vinogradov pp. 392-394 Full Text: PDF (45 kB) Amplification of a Shock Wave in a Saturated Porous Medium V. E. Nakoryakov and V. E. Dontsov pp. 395-396 Full Text: PDF (37 kB) Effect of Oriented Elastic and Strength Characteristics on the Impact Fracture of Anisotropic Materials A. V. Radchenko and S. V. Kobenko pp. 397-400 Full Text: PDF (76 kB) Solving the Boltzmann Equation in the Case of Passing to the Hydrodynamic Flow Regime F. G. Cheremisin pp. 401-404 Full Text: PDF (74 kB) An Isobaric–Isothermal Ensemble in Statistical Mechanics K. M. Magomedov pp. 405-409 Full Text: PDF (73 kB) On Singularities of Boundaries for Parametric Resonance A. A. Mailybaev and A. P. Seiranyan pp. 410-414 Full Text: PDF (77 kB) Structure of Solutions to Linear Unsteady Boundary Value Problems in Mechanics and Mathematical Physics A. D. Polyanin pp. 415-418 Full Text: PDF (55 kB) On Invariants of the Stress–Strain State in Mathematical Models for Mechanics of Continua E. I. Shemyakin pp. 419-421 Full Text: PDF (42 kB) Undular Bore in the Counterflow V. I. Bukreev pp. 422-424 Full Text: PDF (297 kB) Integration of Equations for Long Waves in the Drozdova–Kulikovskii Form A. G. Petrov pp. 425-429 Full Text: PDF (72 kB) Macrostructure and Microstructure of a Cocurrent Stratified Flow behind a Cylinder Yu. D. Chashechkin and V. V. Mitkin pp. 430-433 Full Text: PDF (117 kB)Archived web conten
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