35 research outputs found
Réactivité du bromure de 5-thioxylopyranosyle et du 1,5-dithioxylopyranoside vis-à-vis d’anions thiolate
Get PDFChemoenzymatic synthesis of 5-thio-D-xylopyranose.
No full text5-thio-D-xylopyranose, a synthon used for the preparation of drugs with antithrombotic activity, was synthesised by an enzymatic isomerisation from the corresponding ketose, 5-thio-D-xylulofuranose, with glucose isomerase. This compound was obtained by two different chemoenzymatic routes, the key step being the stereospecific formation of a C-C bond, catalysed by transketolase or fructose-1,6-bisphosphate aldolas
ChemInform Abstract: Chemistry of 4-Cyanophenyl 1,5-Dithio-β-D-xylopyranoside (Beciparcil). Part 3. Synthesis of the 3-Methyl Ether and 4-Deoxy Derivatives of 4-Cyanophenyl 1,5-Dithio-β-D-xylopyranoside (Beciparcil).
No full textA new chemoenzymatic route to dihydroxyacetone phosphate from glycidol for the in situ aldolase-mediated synthesis of monosaccharides
No full textAn efficient chemoenzymatic route to dihydroxyacetone phosphate from glycidol for the in situ aldoalse-mediated synthesis of monosaccharides
No full textWe report a new two-step procedure that uses inexpensive rac-glycidol to obtain valuable dihydroxyacetone phosphate (DHAP), a building block for the synthesis of monosaccharide analogues
Synthesis of the 3-methyl ether and 4-deoxy derivatives of 4-cyanophenyl 1,5-dithio-β-d-xylopyranoside (Beciparcil)
No full textNew efficient electrochemical synthesis of 1,5-dithioxylopyranosides in the presence of a sacrificial anode
No full textChemInform Abstract: Chemical Interconversions of 4-Cyanophenyl 1,5-Dithio-β-D-xylopyranoside (Beciparcil®): Structural Modification at the C-4 Position.
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