1,720,960 research outputs found
Making a Simple A+B→C Reaction Oscillate by Coupling to Hydrodynamic Effect
No full textWe present a new mechanism through which chemical oscillations and waves can be induced in batch conditions with a simple A+B→C reaction in the absence of any nonlinear chemical feedback or external trigger. Two reactants A and B, initially separated in space, react upon diffusive contact and the product actively fuels in situ convective Marangoni flows by locally increasing the surface tension at the mixing interface. These flows combine in turn with the reaction-diffusion dynamics, inducing damped spatiotemporal oscillations of the chemical concentrations and the velocity field. By means of numerical simulations, we single out the detailed mechanism and minimal conditions for the onset of this periodic behavior. We show how the antagonistic coupling with buoyancy convection, due to concurrent chemically induced density changes, can control the oscillation properties, sustaining or suppressing this phenomenon depending on the relative strength of buoyancy- and surface-tension-driven forces. The oscillatory instability is characterized in the relevant parametric space spanned by the reactor height, the Marangoni (Mai) and the Rayleigh (Rai) numbers of the ith chemical species, the latter ruling the surface tension and buoyancy contributions to convection, respectively
Dynamics due to combined buoyancy- and Marangoni-driven convective flows around autocatalytic fronts
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Comparative analysis of buoyancy- and Marangoni-driven convective flows around autocatalytic fronts
No full textWe introduce a reaction-diffusion-convection (RDC) model to study the combined effect of buoyancy- and Marangoni-driven flows around a traveling front. The model allows for a parametric control of the two contributions via the solutal Rayleigh number, Rac, which rules the buoyancy component and the solutal Marangoni number, Mac, governing the intensity of the velocity field at the interface between the reacting solution and air. Complex dynamics may arise when the bulk and the surface flows describe an antagonistic interplay. Typically, spatiotemporal oscillations are observed in the parameter region (Rac<0, Mac>0)
Chemo-hydrodynamic pulsations in simple batch A + B → C systems
Full text linkSpatio-temporal oscillations can be induced under batch conditions with ubiquitous bimolecular reactions in the absence of any nonlinear chemical feedback, thanks to an active interplay between the chemical process and chemically driven hydrodynamic flows. When two reactants A and B, initially separated in space, react upon diffusive contact, they can power convective flows by inducing a localized variation of surface tension and density at the mixing interface. These flows feedback with the reaction-diffusion dynamics, bearing damped or sustained spatio-temporal oscillations of the concentrations and flow field. By means of numerical simulations, we detail the mechanism underlying these chemohydrodynamic oscillations and classify the main dynamical scenarios in the relevant space drawn by parameters ΔM and ΔR, which rule the surface tension- and buoyancy-driven contributions to convection, respectively. The reactor height is found to play a critical role in the control of the dynamics. The analysis reveals the intimate nature of these oscillatory phenomena and the hierarchy among the different phenomena at play: oscillations are essentially hydrodynamic and the chemical process features the localized trigger for Marangoni flows unstable toward oscillatory instabilities. The characteristic size of Marangoni convective rolls mainly determines the critical conditions and properties of the oscillations, which can be further tuned or suppressed by the buoyancy competition. We finally discuss the possible experimental implementation of such a class of chemo-hydrodynamic oscillator and its implications in fundamental and applied terms
Going Beyond Counting First Authors in Author Co-citation Analysis
Full text linkThe present study examines one of the fundamental aspects of author co-citation analysis (ACA) - the way co-citation
counts are defined. Co-citation counting provides the data on which all subsequent statistical analyses and mappings
are based, and we compare ACA results based on two different types of co-citation counting - the traditional type that
only counts the first one among a cited work's authors on the one hand and a non-traditional type that takes into
account the first 5 authors of a cited work on the other hand. Results indicate that the picture produced through this non-traditional author co-citation counting contains more coherent author groups and is therefore considerably clearer. However, this picture represents fewer specialties in the research field being studied than that produced through the traditional first-author co-citation counting when the same number of top-ranked authors is selected and analyzed. Reasons for these effects are discussed
Variations on the Author
Full text link“Variations on the Author” discusses two of Eduardo Coutinho’s recent films (Um Dia na Vida, from 2010, and Últimas Conversas, posthumously released in 2015) and their contribution to the general question of documentary authorship. The director’s filmography is characterized by a consistent yet self-effacing form of authorial self-inscription: Coutinho often features as an interviewer that rather than express opinions propels discourses; an interviewer that is good at listening. This mode of self-inscription characterizes him as an author who is not expressive but who is nonetheless markedly present on the screen. In Um Dia na Vida, however, Coutinho is completely absent form the image, while Últimas Conversas, on the contrary, includes a confessional prologue that moves the director from the margins to the center of his films. This article examines the ways in which these works stand out in the filmography of a director who offers new insights into the notion of cinematic authorship
Appropriate Similarity Measures for Author Cocitation Analysis
Full text linkWe provide a number of new insights into the methodological discussion about author cocitation analysis. We first argue that the use of the Pearson correlation for measuring the similarity between authors’ cocitation profiles is not very satisfactory. We then discuss what kind of similarity measures may be used as an alternative to the Pearson correlation. We consider three similarity measures in particular. One is the well-known cosine. The other two similarity measures have not been used before in the bibliometric literature. Finally, we show by means of an example that our findings have a high practical relevance.information science;Pearson correlation;cosine;similarity measure;author cocitation analysis
Dispelling the Myths Behind First-author Citation Counts
Full text linkWe conducted a full-scale evaluative citation analysis study of scholars in the XML research field to explore just how different from each other author rankings resulting from different citation counting methods actually are, and to demonstrate the capability of emerging data and tools on the Web in supporting more realistic citation counting methods. Our results contest some common arguments for the continued
use of first-author citation counts in the evaluation of scholars, such as high correlations between author rankings by first-author citation counts and other citation
counting methods, and high costs of using more realistic citation counting methods that are not well-supported by the ISI databases. It is argued that increasingly available digital full text research papers make it possible for citation analysis studies to go beyond what the ISI databases have directly supported and to employ more
sophisticated methods
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