9,856 research outputs found
Disorder in Extra-Large Pore Zeolite ITQ-33 Revealed by Single Crystal XRD
No full textThe single crystal of the extra-large pore zeolite, ITQ-33, was obtained and used to explore its crystal structure details. The ITQ-33 structure was found to be disordered with the columnar periodic building unit, explaining the morphology changes upon the different Si/Ge ratio, and the formation of the hierarchical structure from assembling of ITQ-33 nanofibers.Chemistry, MultidisciplinaryCrystallographyMaterials Science, MultidisciplinarySCI(E)EI0ARTICLE104168-41711
Hanging the harp on the willow tree: music and national identity in postcolonial Ireland
No full textAn inquiry into how music served as a nation building tool in the early decades of the Irish Free State.M.A.Includes bibliographical referencesby Crystal N. Galyea
Four-port coupled channel-guide device based on 2D photonic crystal structure
No full textWe have fabricated and measured a four-port coupled channel-waveguide device using W1 channel waveguides oriented along ΓK directions in a two-dimensional (2D) hole-based planar photonic crystal (PhC) based on silicon-on-insulator (SOI) waveguide material, at operation wavelengths around 1550 nm. 2D FDTD simulations and experimental results are shown and compared. The structure has been designed using a mode conversion approach, combined with coupled-mode concepts. The overall length of the photonic crystal structure is typically about 39 μm and the structure has been fabricated using a combination of direct-write electron-beam lithography (EBL) and dry-etch processing. Devices were measured using a tunable laser with end-fire coupling into the planar structure
CCDC 1544884: Experimental Crystal Structure Determination
No full textRelated Article: Maria A. Susano, Pablo Martín-Ramos, Teresa M.R. Maria, Steven Folkersma, Laura C.J. Pereira, Manuela Ramos Silva|2017|J.Mol.Struct.|1147|76|doi:10.1016/j.molstruc.2017.06.043,An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available from the CCDC and typically includes 3D coordinates, cell parameters, space group, experimental conditions and quality measures.
Transferring Crystallization Conditions from Small to Larger Scale for Achieving Targeted Crystal Morphologies of an Active Pharmaceutical Ingredient
No full textCrystal morphology plays a critical role in the processability and physicochemical behavior of active pharmaceutical ingredients. Manipulating crystal morphology involves consideration of crystallization conditions such as temperature, supersaturation, and solvent choice. Typically, experimental screenings on a small scale are conducted to find targeted crystal morphologies. However, results from such small-scale experiments do not assure direct success at a larger scale, particularly if the small-scale setup differs significantly from a conventional stirred crystallizator. In this study, we successfully validated the morphologies observed in the small-scale experiments of an exemplary API, Bitopertin, when scaled up by a factor of 200, through the maintenance of identical process conditions and geometrical vessel relations. This successful scalability highlights the significant potential of small-scale crystallization studies to provide a reliable foundation for further exploration in large-scale endeavors
Investigation of nucleation and crystal growth kinetics of nickel manganese oxalates
No full textThe nucleation and the crystal growth rates of mixed nickel manganese oxalates have been determined from the changes of the ionic concentration of the solution and the crystal size distribution during the precipitation process within a supersaturation range 0–0.1 M. Thermodynamic solubility calculations have been used to identify the different species contributing the precipitation reaction and for estimation of the thermodynamic constant. Experimental data show that the nucleation rate of mixed nickel manganese oxalate in this supersaturation range is consistent with a primary heterogeneous mechanism and was found to obey to an exponential law. The crystal growth rates indicate a surface-integration-controlled mechanism with a first-order law with respect to the supersaturation
CCDC 1544884: Experimental Crystal Structure Determination
No full textRelated Article: Maria A. Susano, Pablo Martín-Ramos, Teresa M.R. Maria, Steven Folkersma, Laura C.J. Pereira, Manuela Ramos Silva|2017|J.Mol.Struct.|1147|76|doi:10.1016/j.molstruc.2017.06.043,An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available from the CCDC and typically includes 3D coordinates, cell parameters, space group, experimental conditions and quality measures.
Finite element method for 3D optical modeling of liquid crystal on silicon spatial light modulator
No full textAccurate optical modeling for design and optimization of liquid crystal on silicon spatial light modulators (LCoS SLMs) is important for phase-related applications. Traditional matrix method cannot accurately predict the optical performance when the LC distribution is complex, therefore the rigorous finite element method (FEM) is preferred. However, the optical modeling of LCoS is a multidimensional problem, which is difficult to simulate with FEM. Here, we present the development of an improved FEM by combining the scattering matrix method with the domain decomposition method to reduce the computational burden for optical simulation of LCoS. Furthermore, a 2D simulation example with phase grating displayed on LCoS is presented and compared with experiment.Grant ID: ColoOpt- EU H2020 ITN 721465ImPhys/Optic
Gel-mediated chemo-mechanical control of calcium carbonate crystal formation
No full textThe production of synthetic crystals with controlled shapes and properties is an enticing prospect, yet, the production of such materials is an ongoing challenge. Here, we present a strategy for chemo-mechanically directing the growth of crystals with non-equilibrium structures using a custom-designed double-diffusion cell. We combine chemical additives (e.g., Mg2+ ions) and mechanical confinement (e.g., hydrogel networks) to modulate the growth of calcium carbonate crystals. Specifically, the combination of Mg2+ ions with a strong agarose gel results in calcitic structures, at the gel-glass slide interface, with distinct fried egg-like morphologies and radial or Maltese-cross extinction patterns. In contrast, precipitation with only Mg2+ or agarose results in aragonite spherulites or squished calcite rhombohedra, respectively. Raman spectroscopy and energy dispersive spectroscopy of the “fried eggs” reveals that they are composed of Mg-calcite, which becomes less disordered over time, and the “egg whites” make this transition before the “yolks”. We propose that the “fried eggs” form due to a spherulitic growth process molded by the crystallization-induced delamination of the gel away from the glass slide at the gel-glass interface. In support of the importance of the gel-glass interface, the “fried eggs” do not form when the glass slide is treated with a hydrophobic silane, suppressing heterogeneous nucleation and weakening the interfacial adhesion between the gel and glass, making it easier for the gel to delaminate, thus reducing the confinement effect. As such, this work highlights the important chemo-mechanical role that gel environments can play in crystal formation.Green Open Access added to TU Delft Institutional Repository 'You share, we take care!' - Taverne project https://www.openaccess.nl/en/you-share-we-take-care Otherwise as indicated in the copyright section: the publisher is the copyright holder of this work and the author uses the Dutch legislation to make this work public.Materials and Environmen
Crystal Kuykendall - 04/17/2006 - (Riall Lecture Series)
No full textBegun in 1988, the E. Pauline Riall Lecture Series brings to the University and community outstanding national lecturers in the field of education. The series was established by the late Miss Riall, long-time principal and teacher of the former Salisbury University's Campus School. A generous bequest was provided by Miss Riall's will to fund this special program.
Crystal Arlene Kuykendall, Author and Educational Consultant – Riall Speaker on 4/17/2006 (pm) and 4/18/2006 (am).https://www.youtube.com/watch?v=vFmq73VLgZ
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