104 research outputs found

    DETERMINASI DIRI TOKOH UTAMA DALAM SINETRON TENDANGAN SI MADUN SEASON 1 DENGAN ANIMASI CAPTAIN TSUBASA 2018 KAJIAN SASTRA BANDINGAN

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    Napitu, Estomihi. 2020. "Self Determination of the Main Character in Tendangan Si Madun Season 1 Cinetron and Captain Tsubasa 2018 Animation Comparative Literature Study". Essay. Undergraduate Program in Indonesian Literature. Semarang. Faculty of Humanities, Diponegoro University, First Supervisor Dra. Muh. Abdullah, M.A. Second Supervisor Fajrul Falah, S.Hum, M.Hum. The research object that is used by the author includes Tendangan Si Madun Season 1 cinetron and Captain Tsubasa 2018 animation. The purpose of this research is to describe (1) the structure of TSM Season I cinetron and CT 2018 animation and (2) a comparison of the self-determination of the main character in TSM Season I cinetron with CT 2018 animation. A comparative method is used for this research. The steps used by the author includes data sources, data analysis techniques, and analysis result presentation. The data sources for this research are TSM Season 1 cinetron and CT 2018 animation. The research that has been done shows that the structure of TSM Season 1 cinetron and CT 2018 animation includes: (1) theme; (2) plot; (3) character; (4) setting. According to the structure, the two films have similarities and differences. The similarities lie in the following aspects: (1) theme, these two objects have a soccer theme; (2) plot, these two objects have a different storyline, the plot of TSM Season 1 cinetron uses a reverse plot, while CT 2018 uses a straight plot (progressive); (3) characters, have similarities in roles and functions. Apart from structural aspects, similarities and differences also exist in the aspect of self-determination. The similarities are in the following aspects: (1) competence, the two main characters have good competence resulting from hard training; (2) relatedness, the two main characters have good connections that creates a caring relationship. The differences in self-determination in the two main characters are in the following aspects: (3) Self-autonomy, the main character in the TSM Season 1 cinetron has weak self-autonomy because he is not yet able to make his own choice, while the main character in the CT 2018 animation has strong self-autonomy because he is capable of making his own choice without depending on others. Keywords: comparison, self-determination, competence, self-autonomy, relatednes

    Effect of Dissolved Silica on Immobilization of Boron by Magnesium Oxide

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    The effect of silica on the immobilization reaction of boron by magnesium oxide was investigated by laboratory experiments. In the absence of silica, due to dissolution of the magnesium oxide, boron was removed from solutions by the precipitation of multiple magnesium borates. In the presence of silica, magnesium silica hydrate (M-S-H) was formed as a secondary mineral, which takes up boron. Here B-11 magic-angle spinning nuclear magnetic resonance (MAS-NMR) and Fourier transform infrared spectrometer (FT-IR) data show that a part of the boron would be incorporated into M-S-H structures by isomorphic substitution of silicon. Another experiment where magnesium oxide and amorphous silica were reacted beforehand and boron was added later showed that the shorter the reaction time of the preceding reaction, the higher the sorption ratio of boron. That is, boron was incorporated into the M-S-H mainly by coprecipitation. The experiments in the study here show that the sorption of boron in the presence of silica is mainly due to the incorporation of boron during the formation of the M-S-H structure, which suggests that boron would not readily leach out, and that stable immobilization of boron can be expected

    Dissolved Silica Effects on Adsorption and Co-Precipitation of Sb(III) and Sb(V) with Ferrihydrite

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    Elevated antimony concentrations in aqueous environments from anthropogenic sources are becoming of global concern. In this respect iron oxides are known to strongly adsorb aqueous antimony species with different oxidation states, but the effect of silica on the removal characteristics is not well understood despite being a common component in the environment. In this study, ferrihydrite was synthesized at various Si/Fe molar ratios to investigate its adsorption and co-precipitation behaviors with aqueous antimony anionic species, Sb(III) and Sb(V). The X-ray diffraction analyses of the precipitates showed two broad diffraction features at approximately 35° and 62° 2θ, which are characteristics of 2-line ferrihydrite, but no significant shifts in peak positions in the ferrihydrite regardless of the Si/Fe ratios. The infrared spectra showed a sharp band at ~930 cm−1, corresponding to asymmetric stretching vibrations of Si–O–Fe bonds which increased in intensity with increasing Si/Fe molar ratios. Further, the surface charge on the precipitates became more negative with increasing Si/Fe molar ratios. The adsorption experiments indicated that Sb(V) was preferentially adsorbed under acidic conditions which decreased dramatically with increasing pH while the adsorption rate of Sb(III) ions was independent of pH. However, the presence of silica suppressed the adsorption of both Sb(III) and Sb(V) ions. The results showed that Sb(III) and Sb(V) ions were significantly inhibited by co-precipitation with ferrihydrite even in the presence of silica by isomorphous substitution in the ferrihydrite crystal structure

    Mineralogical evolution of a weathering profile in the Tagaung Taung Ni laterite deposit: significance of smectite in the formation of high-grade Ni ore in Myanmar

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    Myanmar has a drier sub-tropical climate than countries that typically contain Ni laterite deposits, but hosts a Ni laterite deposit at Tagaung Taung. Given that Ni enrichment processes in the Tagaung Taung deposit are poorly understood, we investigated the geochemical and mineralogical evolution of two weathering profiles developed on different bedrocks in the central part of Myanmar: a partly serpentinized harzburgite at Tagaung and an almost completely serpentinized peridotite at Budaung. The whole-rock geochemical data indicate that Si was retained relative to Fe and Al in the weathering profiles. Nickel has been enriched to contents as high as 4.89 wt.% NiO in the saprolite layers at Tagaung, whereas the saprolite layers at Budaung contain 10 wt.% NiO), which is only observed at Tagaung, formed as a replacement product of orthopyroxene. In addition to the high Ni fixation capacity of smectite relative to secondary serpentine, Ni-rich pore water derived from the dissolution of olivine likely contributed to the high Ni contents of smectite. Our results imply that high-grade Ni laterite deposits may develop on unaltered or partly serpentinized harzburgite under the climatic conditions typical of Myanmar

    A novel method for remediation of nickel containing wastewater at neutral conditions

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    Heavy metals contained in wastewater are generally removed by adding antalkaline to increase the pH, and Ni is commonly precipitated as Ni-hydroxides at pH 10. However, a more sustainable remediation method of treatment at neutral conditions would be attractive due to the high cost of chemical reagents and inefficient treatment at present. Based on natural attenuation, the method of adding Al ions has been used in wastewater treatment to precipitate layered double hydroxides (LDH). Here, we investigated the use of Al ion addition in the Ni containing wastewater treatment, experimentally and thermodynamically. By co-precipitation experiments adding Al ions to Ni-containing water, Ni was selectively incorporated into the structure of LDH, and the removal efficiency of Ni was close to 100% even in pH 7 and 8 samples (lower pH than conventional methods) with initial Ni concentrations of 200-10,000 mg/L. Geochemical modeling results replicate the experimental results well when the Al/Ni ratio of LDH is assumed to be 0.33. This model makes it possible to estimate the amount of Al ions and additive agents necessary for use in treatment of wastewater containing different Ni concentrations

    Large Fe isotope fractionations in sulfide ores and ferruginous sedimentary rocks from the Kuroko volcanogenic massive sulfide deposits in the Hokuroku district, northeast Japan

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    Anoxic seawater may have played an important role in the preservation of volcanogenic massive sulfide (VMS) deposits in the Hokuroku district, northeast Japan, which is the type locality for Kuroko-type VMS deposits. In this study, we investigated the Fe isotopic compositions of sulfide ores and overlying ferruginous sedimentary rocks in these deposits. These data, coupled with petrographic and geochemical data, enable us to investigate the key formation processes and conditions during the formation of large Kuroko-type VMS deposits. Large Fe isotope variations of ca. 4 parts per thousand (delta Fe-56) associated with negative or positive Ce anomalies characterize the ferruginous sedimentary rocks formed in the Kuroko VMS deposits and post-Kuroko hydrothermal activity. This suggests that iron (hydr)oxides were precipitated by the partial oxidation of dissolved Fe2+ derived from hydrothermal fluids in anoxic or suboxic pools in the Hokuroku Basin. Positive Eu anomalies in the ferruginous cherts closely associated with the Kuroko VMS deposits indicate formation from high-temperature hydrothermal fluids. Zincrich black ores in both the Matsumine and Fukazawa deposits have lower delta Fe-56 values, due to rapid precipitation of pyrite triggered by the mixing of hydrothermal fluids with seawater. Positive shifts in delta Fe-56 values in the ferruginous cherts from the Ezuri and Fukazawa deposits may be explained by simultaneous precipitation of ferruginous sedimentary rocks with black ores, which modified the delta Fe-56 values of the hydrothermal fluids to positive values. However, Cu-rich yellow ores show no significant Fe isotope fractionation as compared with the dissolved Fe in the hydrothermal fluids, and were likely formed by slow growth of pyrite that replaced the black ores. The difference in the abundance of sulfide ores between the Matsumine and Fukazawa deposits may reflect the duration of hydrothermal circulation

    GC Separation of cis-Eicosenoic Acid Positional Isomers on an Ionic Liquid SLB-IL100 Stationary Phase

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    Gas chromatography (GC) of cis-eicosenoic acid (20:1) positional isomers has been investigated on a capillary column of ionic liquid 1,9-di(3-vinyl-imidazolium)nonane bis(trifluoromethyl)sulfonylimidate stationary phase (SLB-IL100). A test mixture of isomeric 20:1 methyl esters was prepared from flathead flounder flesh lipids. On a 60-m column operated at 150-180 °C, six peaks appeared in the elution order of 20:ln-15 → 20:ln-13 → 20:ln-11 → 20:ln-9 → 20:ln-7 → 20:ln-5. These peaks were baseline resolved within 20 min at 180 °C. The 20:ln-13 and 20:ln-11 isomers, poorly resolved on conventional polar polysiloxane stationary phases, were completely separated from each other with separation factor α = 1.02 and peak resolution (Rs) >- 1.57. When equivalent chain length (ECL) values were compared between the SLB-IL100 and CP-Sil 88 (biscyanopropyl polysiloxane), those of 20:ln-15 and 20:ln-13 exceptionally tended to be lower on the SLB-IL100. The excellent separation of 20:1 isomers seems due to less retention of 20:ln-15 and 20:ln-13 on SLB-IL100 rather than simply due to its high polarity. Analysis of herring oil 20:1 revealed the occurrence of 20:ln-13 in the Pacific herring but not in the Atlantic herring. The ionic liquid stationary phase, SLB-IL100, is effective for analyzing 20:1 isomers occurring in fish and other natural oils

    DICHOTOMY OF GLOBAL CAPACITY DENSITY

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    Let 1 = 2. By Cap(p, mu)(E, D) we denote the variational (p, mu)-capacity of condenser (E, D). We show a dichotomy of the global density with respect to Cap(p, mu). One of our results is as follows: Let lambda > 1 and let B(x, r) stand for the open ball with center at x and radius r. Then lim(r ->infinity) (inf(x is an element of Rn) Cap(p, mu)(E boolean AND B(x, r), B(x, lambda r))/Cap(p, mu)(B(x, r), B(x, lambda r))) is equal to either 0 or 1; the first case occurs if and only if inf(x is an element of Rn) Cap(p, mu)(E boolean AND B(x, r(0)), B(x, lambda r))/Cap(p, mu)(B(x, r), B(x, lambda r)) is identically equal to 0. This provides a sharp contrast between capacity and Lebesgue measure

    Formation of Fe- and Mg-Rich Smectite under Hyperalkaline Conditions at Narra in Palawan, the Philippines

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    The formation of Fe- and Mg-rich smectite and zeolite under alkaline conditions, as secondary minerals after the alkaline alteration of bentonite in repositories for radioactive waste, is of major concern. It is crucial for safety assessments to know whether smectite is formed as a secondary mineral after the alkaline alteration of bentonite. In the present paper, Fe- and Mg-rich smectite, which interacted with the hyperalkaline groundwater at Narra in Palawan, Philippines, was used. Mineralogical and geochemical investigation was conducted to understand the formation process of the smectite and the factors determining the formation of secondary mineral species. The results suggest that a certain amount of smectite may be generated under hyperalkaline conditions, by alteration from amorphous or poorly crystalline components such as M-S-H and F-S-H. Therefore, the controlling factor determining whether smectite or zeolite will be generated as secondary minerals after alkaline alteration of bentonite could be whether nuclei of M-S-H and/or F-S-H are formed. Whether such formation takes place may be determined by the presence of dissolved Mg2+ and Fe2+ in the environment. The formation process of smectite under alkaline conditions, suggested by the results here, is analogous to the generally accepted model of smectite formation as it may have occurred on early Mars
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