1,720,992 research outputs found
Perfecting the Growth and Transfer of Large Single-Crystal CVD Graphene: A Platform Material for Optoelectronic Applications
No full textIn this work, we demonstrate the synthesis of millimetre-sized single-crystals of graphene, achievable in a commercially available cold-wall CVD reactor, and several different approaches to transfer it from the growth substrate to a target substrate of choice. We confirm the high crystal quality of this material using various characterisation techniques, including optical and scanning electron microscopy as well as Raman spectroscopy. By performing field effect and quantum Hall effect measurements, we demonstrate that the electronic properties of such single crystals are comparable to those of ideal mechanically exfoliated flakes of graphene. Several applications of this high-quality material are also reviewed
Mapping the mechanical properties of a graphene drum at the nanoscale
Full text linkThe operation of graphene-based nanoelectromechanical systems (NEMS) crucially depends on the local mechanical characteristics of the graphene drum resonator. In particular, inhomogeneity in the residual strain (pre-strain) of the graphene membrane may affect the vibration dynamics as well as the energy dissipation. Despite its importance, achieving a precise local mapping of the pre-strain of a graphene membrane remains challenging. Here, we correlate scanning-probe force microscopy and Raman spectroscopy to map the local mechanical properties of circular monolayer-graphene drums. At odds with other techniques, we obtain maps of the membrane pre-strain with nanometric resolution and measure the effective Young's modulus in a non invasive way. Moreover, we show that the common topographic artefacts stemming from tip-induced deformations can be precisely corrected using the information derived from force-spectroscopy data. As a result, the local map of the pre-strain can be correlated with the true morphology of the graphene drum. Our analysis demonstrates that graphene resonators can be characterized by a non-flat morphology and a non-uniform pre-strain distribution, as a consequence of complex boundary conditions at the edge of the membrane and in correlation with local material defects. Since these non-ideal features are strictly related to the growth and the fabrication procedures, our method can provide a useful screening tool for the development of 2D materials-based NEMSs
Deterministic direct growth of WS2 on CVD graphene arrays
Full text linkThe combination of the exciting properties of graphene with those of monolayer tungsten disulfide (WS2) makes this heterostack of great interest for electronic, optoelectronic and spintronic applications. The scalable synthesis of graphene/WS2 heterostructures on technologically attractive substrates like SiO2 would greatly facilitate the implementation of novel two-dimensional (2D) devices. In this work, we report the direct growth of monolayer WS2 via chemical vapor deposition (CVD) on single-crystal graphene arrays on SiO2. Remarkably, spectroscopic and microscopic characterization reveals that WS2 grows only on top of the graphene crystals so that the vertical heterostack is selectively obtained in a bottom-up fashion. Spectroscopic characterization indicates that, after WS2 synthesis, graphene undergoes compressive strain and hole doping. Tailored experiments show that such hole doping is caused by the modification of the SiO2 stoichiometry at the graphene/SiO2 interface during the WS2 growth. Electrical transport measurements reveal that the heterostructure behaves like an electron-blocking layer at large positive gate voltage, which makes it a suitable candidate for the development of unipolar optoelectronic components
Antenna-Coupled Graphene Field-Effect Transistors as a Terahertz Imaging Array
No full textTerahertz radiation is extremely suitable for various imaging applications. In real life, these range from food or pharmaceutical quality control to illegal materials or human security control inspections. Despite its great potential, the wide usage and commercialization of terahertz imaging systems are still limited by the lack of compact technologies. The emerging graphene-based devices can efficiently contribute to fill this gap, offering higher versatility, scalability, and superior electronic properties compared to conventional semiconductors. In this work, we study a new scheme for realizing a multielement terahertz sensor, which is capable of multipixel parallel detection. The array consists of linearly distributed antenna-coupled graphene field-effect transistors, which are realized by exploiting a deterministic growth by chemical vapor deposition of single-crystal graphene. This novel growth technique ensures high material quality and offers large adaptability to different electronic device architectures. Relatively uniform terahertz detection performances (with a maximum homogeneity degree of 80%) were obtained with a maximum responsivity of the order of 1 V/W and an estimated response time in the picosecond scale. These detectors have demonstrated to fulfill several main requirements for image sensors (pixel uniformity, operability, and scalability), becoming very promising candidates for the realization of commercial high-resolution roomerature terahertz cameras
50Gb/s CVD Graphene-Insulator-Graphene Electro-Absorption Modulator on Si waveguide
No full textWe demonstrate a non-return to zero optical modulation at 50Gb/s with a CVD grown Graphene-Insulator-Graphene electro-absorption modulator integrated on a Si photonic waveguide. The device exhibits a 3dB electro-optical bandwidth of 30GHz. (C) 2019 The Author(s
Scanning probe assisted local oxidation nanolithography of CVD grown graphene on Ge(l00)
No full textWe report on the morphological investigation of nanoscale thick patterns obtained by the scanning probe assisted local oxidation technique on graphene layers grown directly on Ge (100) substrates using CVD technique. Protruding mounds and lines are produced by applying a negative voltage to the atomic force microscope probe while translating the probe tip across the sample surface. The main features of the local oxide produced and the differences with respect to similar experiments conducted on Ge or Si samples are presented
Going Beyond Counting First Authors in Author Co-citation Analysis
Full text linkThe present study examines one of the fundamental aspects of author co-citation analysis (ACA) - the way co-citation
counts are defined. Co-citation counting provides the data on which all subsequent statistical analyses and mappings
are based, and we compare ACA results based on two different types of co-citation counting - the traditional type that
only counts the first one among a cited work's authors on the one hand and a non-traditional type that takes into
account the first 5 authors of a cited work on the other hand. Results indicate that the picture produced through this non-traditional author co-citation counting contains more coherent author groups and is therefore considerably clearer. However, this picture represents fewer specialties in the research field being studied than that produced through the traditional first-author co-citation counting when the same number of top-ranked authors is selected and analyzed. Reasons for these effects are discussed
Variations on the Author
Full text link“Variations on the Author” discusses two of Eduardo Coutinho’s recent films (Um Dia na Vida, from 2010, and Últimas Conversas, posthumously released in 2015) and their contribution to the general question of documentary authorship. The director’s filmography is characterized by a consistent yet self-effacing form of authorial self-inscription: Coutinho often features as an interviewer that rather than express opinions propels discourses; an interviewer that is good at listening. This mode of self-inscription characterizes him as an author who is not expressive but who is nonetheless markedly present on the screen. In Um Dia na Vida, however, Coutinho is completely absent form the image, while Últimas Conversas, on the contrary, includes a confessional prologue that moves the director from the margins to the center of his films. This article examines the ways in which these works stand out in the filmography of a director who offers new insights into the notion of cinematic authorship
Appropriate Similarity Measures for Author Cocitation Analysis
Full text linkWe provide a number of new insights into the methodological discussion about author cocitation analysis. We first argue that the use of the Pearson correlation for measuring the similarity between authors’ cocitation profiles is not very satisfactory. We then discuss what kind of similarity measures may be used as an alternative to the Pearson correlation. We consider three similarity measures in particular. One is the well-known cosine. The other two similarity measures have not been used before in the bibliometric literature. Finally, we show by means of an example that our findings have a high practical relevance.information science;Pearson correlation;cosine;similarity measure;author cocitation analysis
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