1,720,986 research outputs found

    Stagno

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    Il capitolo analizza nel dettaglio il racconto "Stagno" del "Sistema periodico" di Primo Levi, interpretandolo nel quadro del macrotesto e alla luce delle possibili relazioni intertestuali, con particolare attenzione agli aspetti strutturali, stilistici e linguistici

    Stagno

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    Il capitolo analizza nel dettaglio il racconto "Stagno" del "Sistema periodico" di Primo Levi, interpretandolo nel quadro del macrotesto e alla luce delle possibili relazioni intertestuali, con particolare attenzione agli aspetti strutturali, stilistici e linguistici

    Zolfo

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    Analisi linguistica e stilistica del racconto "Zolfo" nella raccolta "Il sistema periodico" di Primo Levi

    Arsenico

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    "Arsenico" è uno dei racconti del "Sistema periodico" di Primo Levi, in cui il lavoro del chimico e l'arte di raccontare storie trovano un incontro e una conciliazione peculiare. Il mistero e il fondamento etico e morale danno luogo a un breve ma denso racconto, in cui la lingua rende ragione di una riflessione che accompagna il percorso creativo dell'autore

    Heat or light? Tools of choice for on-surface synthesis

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    In recent years, direct on-surface synthesis in UHV has been exploited as a promising strategy to obtain thermally and chemically stable structures by covalent bonding of suitable precursors. So far, covalent linking of organic molecules onto metal, semiconducting and bulk insulator surfaces has been mostly carried out thermally. Heat supplied to the system promotes the formation of covalent bonds between the monomeric building units either simultaneously with the surface diffusion phenomena it promotes (i.e. under dynamic bond-forming conditions) or as a trigger, after a pre-assembly step into a surface-supported supramolecular, non-covalent network. However, heat as a tool for on-surface synthesis has the ambivalent status of a pharmakon, since it has the capacity to be beneficial and detrimental to the production and to the structural quality of the covalently-linked network at the same time. The close interplay between molecular surface diffusion, chemical reactivity and temperature, in fact, often hampers the possibility to independently control reaction initiation and surface mobility, ultimately leading to highly defective covalent networks, poorly ordered on the long range. Photochemically activated reactions are a potentially powerful tool to stabilize self-organized structures without disrupting the long-range order. Yet, to date photo-initiated on-surface reactions are still rather uncommon, since the processes following light absorption are not completely understood and, in particular, the role of the substrate is still poorly characterized in quantitative terms: the high quenching rate of electronically excited species on metal surfaces, which inhibits the photophysical processes commonly observed in the gas phase and in solution; the presence of new, surface-related excitation and relaxation pathways; the occurrence of charge-transfer-mediated photochemistry are but a few important issues. Based on the recent experience of our group in this field [1–6], in this talk I will provide some hints on the necessary conditions to be fulfilled to make either heat or light – or a combination of both – the tool of choice for the successful on-surface synthesis of long range-ordered covalent networks. References [1] F. Sedona, M. Di Marino, M. Sambi, T. Carofiglio, E. Lubian, M. Casarin, and E. Tondello. ACS Nano 4, 5147 (2010) [2] A. Basagni, L. Colazzo, F. Sedona, M. Di Marino, T. Carofiglio, E. Lubian, D. Forrer, A. Vittadini, M. Casarin, A. Verdini, A. Cossaro, L. Floreano and M. Sambi. Chem. Eur. J. 20, 14296 (2014) [3] A. Basagni, F. Sedona, C. A. Pignedoli, M. Cattelan, L. Nicolas, M. Casarin, and M. Sambi. J. Am. Chem. Soc. 137, 1802 (2015) [4] A. Basagni, L. Ferrighi, M. Cattelan, L. Nicolas, K. Handrup, L. Vaghi, A. Papagni, F. Sedona, C. Di Valentin, S. Agnoli and M. Sambi. Chem. Commun. 51, 12593 (2015) [5] S. Tognolini, S. Ponzoni, F. Sedona, M. Sambi and S. Pagliara. Phys. Chem. Lett. 6, 3632 (2015) [6] A. Basagni, G. Vasseur, C. A. Pignedoli, M. Vilas-Varela, D. Peña, L. Nicolas, L. Vitali, J. Lobo-Checa, D. G. de Oteyza, F. Sedona, M. Casarin, J. E. Ortega, and M. Sambi. ACS Nano 10, 2644 (2016

    Azoto

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    Going Beyond Counting First Authors in Author Co-citation Analysis

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    The present study examines one of the fundamental aspects of author co-citation analysis (ACA) - the way co-citation counts are defined. Co-citation counting provides the data on which all subsequent statistical analyses and mappings are based, and we compare ACA results based on two different types of co-citation counting - the traditional type that only counts the first one among a cited work's authors on the one hand and a non-traditional type that takes into account the first 5 authors of a cited work on the other hand. Results indicate that the picture produced through this non-traditional author co-citation counting contains more coherent author groups and is therefore considerably clearer. However, this picture represents fewer specialties in the research field being studied than that produced through the traditional first-author co-citation counting when the same number of top-ranked authors is selected and analyzed. Reasons for these effects are discussed

    Variations on the Author

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    “Variations on the Author” discusses two of Eduardo Coutinho’s recent films (Um Dia na Vida, from 2010, and Últimas Conversas, posthumously released in 2015) and their contribution to the general question of documentary authorship. The director’s filmography is characterized by a consistent yet self-effacing form of authorial self-inscription: Coutinho often features as an interviewer that rather than express opinions propels discourses; an interviewer that is good at listening. This mode of self-inscription characterizes him as an author who is not expressive but who is nonetheless markedly present on the screen. In Um Dia na Vida, however, Coutinho is completely absent form the image, while Últimas Conversas, on the contrary, includes a confessional prologue that moves the director from the margins to the center of his films. This article examines the ways in which these works stand out in the filmography of a director who offers new insights into the notion of cinematic authorship

    Appropriate Similarity Measures for Author Cocitation Analysis

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    We provide a number of new insights into the methodological discussion about author cocitation analysis. We first argue that the use of the Pearson correlation for measuring the similarity between authors’ cocitation profiles is not very satisfactory. We then discuss what kind of similarity measures may be used as an alternative to the Pearson correlation. We consider three similarity measures in particular. One is the well-known cosine. The other two similarity measures have not been used before in the bibliometric literature. Finally, we show by means of an example that our findings have a high practical relevance.information science;Pearson correlation;cosine;similarity measure;author cocitation analysis
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