16 research outputs found
New precatalysts for olefin polymerization having LX2 pincer ligands
No full textBercaw, John E. Labinger, Jay A. Tonks, Ian Winston, Matthew S. Klet, Rachel C. Lenton, Taylor N. Despagnet-Ayoub, Emmanuelle 245th National Spring Meeting of the American-Chemical-Society (ACS) Apr 07-11, 2013 New Orleans, LA Amer Chem So
New precatalysts for olefin polymerization having LX2 pincer ligands
No full textBercaw, John E. Labinger, Jay A. Tonks, Ian Winston, Matthew S. Klet, Rachel C. Lenton, Taylor N. Despagnet-Ayoub, Emmanuelle 245th National Spring Meeting of the American-Chemical-Society (ACS) Apr 07-11, 2013 New Orleans, LA Amer Chem So
Oxidation With The "o2-h2o2-vo3 --pyrazine-2-carboxylic Acid" Reagent: 6. * Oxidation Of N-heptane And Cyclohexane. Direct Determination Of Alkyl Hydroperoxides By Gas-liquid Chromatography
No full textn-Heptane is readily oxidized in acetonitrile under the action of H2O2 with a "vanadate anion-pyrazine-2-carboxylic acid" system as the catalyst in air to form isomeric heptyl hydroperoxides (detected by GLC) along with isomeric heptanols and heptanones. Heptyl hydroperoxides slowly decompose at low temperature yielding the corresponding alcohols and ketones (aldehyde). The values of the parameter of the relative normalized reactivity of the H atoms at the carbon atoms in positions 1, 2, 3, and 4 depend on the reaction time and concentrations of the reagents. The value of the parameter of selectivity C(1) : C(2) : C(3) : C(4) varies in the range from 1.0 : 2.8 : 2.9 : 1.8 to 1.0 : 5.6 : 5.9 : 5.3. The low selectivity of the reaction shows that the key role is played by the attack of highly reactive radical particles on the C-H bond of the alkane molecule.464749754Shul'pin, G.B., Drago, R.S., Gonzalez, M., (1996) Izv. Akad. Nauk, Ser. Khim., p. 2514(1996) Russ. Chem. Bull., 45, p. 2386. , Engl. TranslShul'pin, G.B., Attanasio, D., Suber, L., (1993) Izv. Akad. Nauk. Ser. Khim., p. 64(1993) Russ. Chem. Bull., 42, p. 55. , Engl. TranslShul'pin, G.B., Attanasio, D., Suber, L., (1993) J. Catal., 142, p. 147Shul'pin, G.B., Druzhinina, A.N., Nizova, G.V., (1993) Izv. Akad. Nauk, Ser. Khim., p. 1394(1993) Russ. Chem. Bull., 42, p. 1326. , Engl. TranslNizova, G.V., Shul'pin, G.B., (1994) Izv. Akad. Nauk, Ser. Khim., p. 1212(1994) Russ. Chem. Bull., 43, p. 1146. , Engl. TranslShul'pin, G.B., Süss-Fink, G., (1995) J. Chem. Soc., Perkin Trans. 2, p. 1459Shul'pin, G.B., Guerreiro, M.C., Schuchardt, U., (1996) Tetrahedron, 52, p. 13051Emanuel', N.M., Gal, D., (1984) Okislenie Etilbenzola [Oxidation of Ethylbenzene], , Nauka, Moscow, 280 pp. (in Russian)Shul'pin, G.B., Bochkova, M.M., Nizova, G.V., (1995) J. Chem. Soc., Perkin Trans. 2, p. 1465Shul'pin, G.B., Nizova, G.V., Kozlov, Yu.N., (1996) New J. Chem., 20, p. 1243Nizova, G.V., Süss-Fink, G., Shul'pin, G.B., (1997) J. Chem. Soc., Chem. Commun., p. 397Nizova, G.V., Süss-Fink, G., Shul'pin, G.B., (1997) Tetrahedron, 53, p. 3603Aveline, B.A., Kochevar, I.E., Redmond, R.W., (1996) J. Am. Chem. Soc., 118, p. 289Sheu, C., Richert, S.A., Cofré, P., Ross B., Jr., Sobkowiak, A., Sawyer, D.T., Kanofsky, J.R., (1990) J. Am. Chem. Soc., 112, p. 1936Sheu, C., Sobkowiak, A., Zhang, L., Ozbalik, N., Barton, D.H.R., Sawyer, D.T., (1989) J. Am. Chem. Soc., 111, p. 8030Ellis P.E., Jr., Lyons, J.E., (1990) Coord. Chem. Rev., 105, p. 181Schuchardt, U., Krähembühl, C.E.Z., Carvalho, W.A., (1991) New J. Chem., 15, p. 955Goldstein, A.S., Drago, R.S., (1991) J. Chem. Soc., Chem Commun., p. 21Kao, L.-C., Hutson, A.C., Sen, A., (1991) J. Am. Chem. Soc., 113, p. 700Lin, M., Sen, A., (1992) J. Am. Chem. Soc., 114, p. 7307Sen, A., Lin, M., (1992) J. Chem. Soc., Chem. Commun., p. 508Sen, A., Lin, M., Kao, L.-C., Hutson, A.C., (1992) J. Am. Chem. Soc., 114, p. 6385Schuchardt, U., Carvalho, W.A., Spinacé, E.V., (1993) Synlett, p. 713Labinger, J.A., (1994) Catal. Lett., 26, p. 95Grinstaff, M.W., Hill, M.G., Labinger, J.A., Gray, H.B., (1994) Science, 264, p. 1311Nakata, K., Yamaoka, Y., Miyata, T., Taniguchi, Y., Takaki, K., Fujiwara, Y., (1994) J. Organomet. Chem., 473, p. 329Goldstein, A.S., Beer, R.H., Drago, R.S., (1994) J. Am. Chem. Soc., 116, p. 2424Lin, M., Sen, A., (1994) Nature, 368, p. 613Kurioka, M., Nakata, K., Jintoku, T., Taniguchi, Y., Takaki, K., Fujiwara, Y., (1995) Chem. Lett., p. 244Barton, D.H.R., Taylor, D.K., (1995) Izv. Akad. Nauk, Ser. Khim., p. 595(1995) Russ. Chem. Bull., 44, p. 575. , Engl. TranslBirnbaum, E.R., Grinstaff, M.W., Labinger, J.A., Bercaw, J.E., Gray, H.B., (1995) J. Mol. Catal., A: Chem., 104, pp. L119Shilov, A.E., Shul'pin, G.B., (1995) Aktivatsiya i Kataliticheskie Reaktsii Uglevodorodov [Activation and Catalytic Reactions of Hydrocarbons], , Nauka, Moscow, 400 pp. (in Russian
Addition of a phosphine ligand switches an N-heterocyclic carbene-zirconium catalyst from oligomerization to polymerization of 1-hexene
No full text1477-9226A catalyst for the oligomerization of 1-hexene, generated by the activation of a benzimidazolylidene zirconium dibenzyl complex, switches to a polymerization catalyst on addition of a trialkylphosphine
Mechanistic Studies on Oxidative Coupling of Methane: The Interplay Between Gas-Phase, Surface and Solid-State Processes
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EXTRACTION OF HBr, HC1 AMD HNO3 BY TRIOCTYLPHOSPHINE OXIDE IN NITROBENZENE AND IN 1,2-DICHLOROETHANE1
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