1,720,957 research outputs found

    Frustrated network of indirect exchange paths between tetrahedrally coordinated Co in Ba2 CoO4

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    We present a detailed study of the electronic and magnetic interactions of Ba2CoO4, structurally very uncommon because of the isolated CoO4 distorted tetrahedral coordination. We show the presence of Co(d)-O(p) hybridized states characterized by spin polarized oxygen atoms, with their magnetic moments parallel to that on Co. The calculated isotropic exchange interaction parameters, which include the contributions from ligand spins, demonstrate the presence of a three-dimensional (3D) network of magnetic couplings that are partially frustrated in the identified magnetic ground state. Our results indicate that the dominant indirect exchange mechanism responsible for this ground state is mediated by O atoms along the Co-O »O-Co path

    Going Beyond Counting First Authors in Author Co-citation Analysis

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    The present study examines one of the fundamental aspects of author co-citation analysis (ACA) - the way co-citation counts are defined. Co-citation counting provides the data on which all subsequent statistical analyses and mappings are based, and we compare ACA results based on two different types of co-citation counting - the traditional type that only counts the first one among a cited work's authors on the one hand and a non-traditional type that takes into account the first 5 authors of a cited work on the other hand. Results indicate that the picture produced through this non-traditional author co-citation counting contains more coherent author groups and is therefore considerably clearer. However, this picture represents fewer specialties in the research field being studied than that produced through the traditional first-author co-citation counting when the same number of top-ranked authors is selected and analyzed. Reasons for these effects are discussed

    Variations on the Author

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    “Variations on the Author” discusses two of Eduardo Coutinho’s recent films (Um Dia na Vida, from 2010, and Últimas Conversas, posthumously released in 2015) and their contribution to the general question of documentary authorship. The director’s filmography is characterized by a consistent yet self-effacing form of authorial self-inscription: Coutinho often features as an interviewer that rather than express opinions propels discourses; an interviewer that is good at listening. This mode of self-inscription characterizes him as an author who is not expressive but who is nonetheless markedly present on the screen. In Um Dia na Vida, however, Coutinho is completely absent form the image, while Últimas Conversas, on the contrary, includes a confessional prologue that moves the director from the margins to the center of his films. This article examines the ways in which these works stand out in the filmography of a director who offers new insights into the notion of cinematic authorship

    Appropriate Similarity Measures for Author Cocitation Analysis

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    We provide a number of new insights into the methodological discussion about author cocitation analysis. We first argue that the use of the Pearson correlation for measuring the similarity between authors’ cocitation profiles is not very satisfactory. We then discuss what kind of similarity measures may be used as an alternative to the Pearson correlation. We consider three similarity measures in particular. One is the well-known cosine. The other two similarity measures have not been used before in the bibliometric literature. Finally, we show by means of an example that our findings have a high practical relevance.information science;Pearson correlation;cosine;similarity measure;author cocitation analysis

    μsR evidence of a marked exchange-interaction effect on the local spin dynamics of Tb-based molecular nanomagnets

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    We report on the spin dynamics of two terbium-based molecular nanomagnets, namely Tb(DTBSQ)(HBPz(3))(2) (in short Tb-SQ) and Tb(Trp)(HBPz(3))(2) (in short Tb-Trp), investigated by means of longitudinal muon spin relaxation (mu SR) measurements as a function of applied field, flanked by ac susceptibility characterization. In the two molecules the terbium(III) ion has an isostructural coordination sphere, but in the former the terbium(III) is coordinated by an organic paramagnetic ligand (3,5 ditertbutylsemiquinonate, SQ), while in the latter is coordinated by a diamagnetic one (tropolonate, Trp). Thus Tb-SQ presents an exchange interaction between the terbium(III) ion and a radical while Tb-Trp does not. Both samples exhibit a muon spin-lattice relaxation rate lambda 1(T, BL) peak in the temperature range 10-25 K at all applied longitudinal magnetic fields BL = 50, 150, 300 milli-Tesla (mT). In Tb-SQ, lambda(1)(T, BL) displays a BPP-like behavior led by three different correlations times: the first, dominating for T >= 15 K, follows a thermally activated law tau(c )= tau(0) exp(sigma(A)/k(B)T ) with energy barrier sigma A/kB, while the second and third ones, dominating, respectively, for 8 < T < 15 K and T < 8 K, follow a power-law-like behavior tau(c) = c(0)T (-alpha) with two different values of c(0) and alpha. On the other hand, the temperature and field behavior of lambda(1)(T, B-L) in Tb-Trp strongly deviates from a BPP law, displaying a strongly anomalous character. Our results indicate that, in the absence of an exchange interaction and maintaining all the other relevant interactions constant, the local spin dynamics of single-ion magnets strongly differ from the one observed in the presence of such interaction. The combination of mu SR and ac susceptibility measurements allows us to disentangle the different Orbach, Raman, and direct mechanisms, which are the key ingredients that control the spin dynamics in Tb-SQ, and evidence the potentiality of mu SR in elucidating complex spin dynamics

    Dispelling the Myths Behind First-author Citation Counts

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    We conducted a full-scale evaluative citation analysis study of scholars in the XML research field to explore just how different from each other author rankings resulting from different citation counting methods actually are, and to demonstrate the capability of emerging data and tools on the Web in supporting more realistic citation counting methods. Our results contest some common arguments for the continued use of first-author citation counts in the evaluation of scholars, such as high correlations between author rankings by first-author citation counts and other citation counting methods, and high costs of using more realistic citation counting methods that are not well-supported by the ISI databases. It is argued that increasingly available digital full text research papers make it possible for citation analysis studies to go beyond what the ISI databases have directly supported and to employ more sophisticated methods

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    Automated computational workflows for muon spin spectroscopy

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    Positive muon spin rotation and relaxation spectroscopy is a well established experimental technique for studying materials. It provides a local probe that generally complements scattering techniques in the study of magnetic systems and represents a valuable alternative for materials that display strong incoherent scattering or neutron absorption. Computational methods can effectively quantify the microscopic interactions underlying the experimentally observed signal, thus substantially boosting the predictive power of this technique. Here, we present an efficient set of algorithms and workflows devoted to the automation of this task. In particular, we adopt the so-called DFT+mu procedure, where the system is characterized in the density functional theory (DFT) framework with the muon modeled as a hydrogen impurity. We devise an automated strategy to obtain candidate muon stopping sites, their dipolar interaction with the nuclei, and hyperfine interactions with the electronic ground state. We validate the implementation on well-studied compounds, showing the effectiveness of our protocol in terms of accuracy and simplicity of use

    koamabayili/VECTRON-author-checklist: VECTRON author checklist

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    We have done our best to complete the author checklist relating to the use of animals in the hut study. Note that the objective for the hut study was to evaluate the IRS treatment applications for residual efficacy against Anopheles mosquitoes, including the local An. coluzzii mosquito population. Cows were only used to attract mosquitoes into the huts and no tests were carried out directly on the cows. The author checklist is intended for use with studies where experiments are carried out on animals, which is why we have had such difficulty in completing this for the hut study, as many of the questions do not relate to how the cows were used
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