14 research outputs found

    Percentage of the population with intakes that do not comply with the population nutrient intake goals for different nutrients in Dutch adults aged 19–30 year.

    No full text
    <p>SAFA: saturated fatty acids, TFA: trans fatty acids.</p>1<p>Population nutrient intake goals are published as percentage of energy <a href="http://www.plosone.org/article/info:doi/10.1371/journal.pone.0072378#pone.0072378-FAOWHO1" target="_blank">[1]</a>; these recommendations were translated to g/d based on a 2000 kcal diet; for sugar this resulted in 75 g of total sugar per day, assuming that total sugar intakes are made up of 2/3 added/free sugar <a href="http://www.plosone.org/article/info:doi/10.1371/journal.pone.0072378#pone.0072378-Roodenburg2" target="_blank">[15]</a>.</p

    Hydrated HCl Clusters, HCl(H<sub>2</sub>O)<sub>1−3</sub>, in Helium Nanodroplets: Studies of Free OH Vibrational Stretching Modes

    No full text
    In this work, infrared laser spectroscopy in helium droplets is used to study the solvation of HCl with small water clusters. Clusters of HCl(H2O)n with n = 1−3 and (HCl)2H2O have been identified in the free OH stretching spectral range of 3680−3820 cm−1. The assignment of the infrared vibrational bands of the clusters is aided by ab initio calculations

    Study of HCl Clusters in Helium Nanodroplets:  Experiments and ab Initio Calculations as Stepping Stones from Gas Phase to Bulk<sup>†</sup>

    No full text
    Presented here are the results of the joint theoretical and infrared laser spectroscopic study of the hydrogen chloride monomer and clusters, (HCl)n (n = 1−6), isolated in helium nanodroplets. The H−Cl stretching bands of the dimers and trimers show a large increase in the band intensity as well as low frequency shift with respect to that in a single HCl molecule. The average frequency of the bands for clusters larger than trimers remains approximately constant, which correlates well with the onset of the folded cyclic structure and the full development of the hydrogen bonding in larger clusters. The structure of the clusters was found to be cyclic planar for trimers, slightly twisted square planar for tetramers, envelope-like for pentamers, and folded pseudobipyramidal for hexamers. This change in structure upon an increase of the cluster size can be seen as an early stage of the structural transition to the HCl solid, which consists of zigzag chains of HCl molecules. Spectra of large clusters of about 500 molecules consist of a single band, which encompasses the same frequency range of trimers through hexamers

    Clinical and metabolic characteristics of the study participants in the total group and according to HOMA-IR.

    No full text
    <p><b>Abbreviations:</b> BMI: body mass index; c-f PWV: carotid-femoral pulse wave velocity; DBP: diastolic blood pressure; FG: fasting glucose; HbA<sub>1c</sub>: glycosylated hemoglobin; HOMA-IR: homeostasis model assessment of insulin resistance; LTL: leukocyte telomere length; SBP: systolic blood pressure; TA: telomerase activity; 2h OGTT:2-h glucose level following the oral glucose tolerance test; P-value: p between HOMA-IR ≤ 2.5 and HOMA-IR >2.5 groups</p><p>Clinical and metabolic characteristics of the study participants in the total group and according to HOMA-IR.</p

    Multiple linear regression analysis of c-f PWV (dependent variable) on age, SBP, LTL, HOMA-IR as independent variables.

    No full text
    <p>Abbreviations: c-f PWV, carotid-femoral pulse wave velocity; Error SS: error of sum of squares; HOMA-IR, homeostasis model assessment of insulin resistance; LTL, leukocyte telomere length; SBP, systolic blood pressure; S.E.: standard error; <b>Total SS: total sum of squares;</b> Type III SS:type III sum of squares.</p><p>Multiple linear regression analysis of c-f PWV (dependent variable) on age, SBP, LTL, HOMA-IR as independent variables.</p

    Multiple linear regression analysis of LTL (dependent variable) with age, sex, SBP, HOMA-IR as independent variables.

    No full text
    <p>Abbreviations: Error SS: error of sum of squares; HOMA-IR, homeostasis model assessment of insulin resistance; LTL, leukocyte telomere length; SBP, systolic blood pressure; S.E.: standard error; <b>Total SS: total sum of squares;</b> Type III SS: type III sum of squares</p><p>Multiple linear regression analysis of LTL (dependent variable) with age, sex, SBP, HOMA-IR as independent variables.</p

    Helium Nanodroplet Study of the Hydrogen-Bonded OH Vibrations in HCl–H<sub>2</sub>O Clusters

    No full text
    Mixed (HCl)<sub><i>N</i></sub>(H<sub>2</sub>O)<sub><i>M</i></sub> clusters have been assembled in He droplets from the constituting molecules. Spectra of the clusters were obtained in the range of hydrogen-bonded OH vibrations (3100–3700 cm<sup>–1</sup>) by infrared laser depletion spectroscopy. The observed bands were assigned to cyclic hydrogen-bonded aggregates containing up to two HCl and three H<sub>2</sub>O molecules. The obtained frequencies are in good agreement with the results of harmonic quantum chemical calculations upon appropriate uniform shifts mimicking anharmonic corrections. Although larger clusters containing up to six water molecules were also produced in the droplets, their spectra were found to contribute to the unresolved signal in the range 3250–3550 cm<sup>–1</sup>. The fact that no narrow bands could be unambiguously assigned to the mixed clusters containing more than three water molecules may indicate that such clusters exist in many isomeric forms that lead to overlapped and unresolved bands giving rise to broad structureless features. Another possible explanation includes the formation of elusive zwitterionic clusters, whose bands may have considerable breadth due to electrostatic coupling of different vibrational modes and concomitant intramolecular vibrational relaxation

    A vacuum to be filled. Central and Eastern Europe in the times of ‘geography without the Germans’

    No full text
    This article analyses strategies used by geographers of Central and Eastern Europe, foremost Poland, to improve their international position, in the interwar. The boycott of Germany and its former allies almost until mid-1930s was a challenge to this group and it gradually hindered its development. The most original attempt at overcoming the threat of marginalization were congresses of Slavic geographers organized from 1924. The greatest success, however, came with the 1934 Warsaw congress of the Geographical Union, which was also the occasion for German geographers to fully return to international scholarly exchange

    Association of Insulin Resistance, Arterial Stiffness and Telomere Length in Adults Free of Cardiovascular Diseases.

    No full text
    Chronic inflammation and oxidative stress might be considered the key mechanisms of aging. Insulin resistance (IR) is a phenomenon related to inflammatory and oxidative stress. We tested the hypothesis that IR may be associated with cellular senescence, as measured by leukocyte telomere length (LTL), and arterial stiffness (core feature of arterial aging), as measured by carotid-femoral pulse wave velocity (c-f PWV)
    corecore