1,720,956 research outputs found
A New Perspective on Hydrogen Chloride Scavenging at High Temperatures for Reducing the Smoke Acidity of PVC Cables in Fires V: Comparison between EN 60754-1 and EN 60754-2
Full text linkRegulation (EU) No 305/2011 lays down harmonized conditions for marketing construction products in the European Union. One of its consequences has been the introduction of the product standard EN 50575 and standard EN 130501-6, concerning power, control, and communication cables permanently installed in buildings to prevent the risk of a fire and its consequences. EN 13501-6 provides the reaction to fire classifications for cables, the test methods to be performed, the requirements to meet a specific reaction to fire, and additional classifications for smoke production, flaming droplets, and acidity. It requires EN 60754-2 as the technical standard to assess acidity, and it defines three classes: a1, a2, and a3 (the less performant). Due to the release of hydrogen chloride during the combustion, acidity is the weak point of PVC cables, which are not yet capable of achieving the a1 or a2 classes required for specific locations according to fire risk assessments. EN 13501-6 does not include EN 60754-1, used in harmonized standards outside the scope of Regulation (EU) No 305/2011. EN 60754-1 and EN 60754-2 are common standards for determining halogen gas content, and acidity/conductivity, respectively. While they involve the same type of test apparatus, they differ in heating regimes, final temperatures, and detection methods. In particular, EN 60754-2 requires testing at temperatures between 935-965 degrees C in the tube furnace, where the sample burns, the smoke is collected in bubblers, and pH and conductivity are measured as an indirect assessment of acidity. On the other hand, the temperature regime of EN 60754-1 is a gradual heating run, followed by isothermal heating at 800 degrees C. The paper shows that when potent acid scavengers are used in PVC compounds, performing EN 60754-2 with the thermal profile of EN 60754-1 or at 500 degrees C in isothermal conditions, the evolution of hydrogen chloride changes significantly up to 10 times less than the test performed in isothermal at 950 degrees C. The reason lies behind the kinetic of hydrogen chloride release during the combustion of PVC compounds: the higher the temperature or faster the heat release, the quicker hydrogen chloride evolution and the lower the probability for the acid scavenger to trap it. Thus, these findings emphasize the "fragility" of EN 60754-2 as a tool for assessing risks associated with the release of hydrogen chloride during fires
Towards first-principles prediction of valence instabilities in mixed stack charge-transfer crystals
No full textStrongly correlated electrons delocalized on one-dimensional (1D) soft stacks govern the complex physics of mixed stack charge-transfer crystals, a well-known family of materials composed of electron-donor (D) and acceptor (A) molecules alternating along the 1D chain. The complex physics of these systems is well captured by a modified Hubbard model that also accounts for the coupling of electrons to molecular and lattice vibrational modes and for three-dimensional electrostatic interactions. Here we study several experimental systems to estimate relevant model parameters via density-functional theory calculations on DA units and isolated molecules and ions. Electrostatic intermolecular interactions, an important quantity not just to define the degree of charge transfer of the ground state but also to predict the propensity of the system towards multistability and hence towards discontinuous phase transitions, are also addressed. Results compare favorably with experimental data
Erratum: Towards first-principles prediction of valence instabilities in mixed stack charge-transfer crystals (Physical Review B (2017) 95 (155125) DOI: 10.1103/PhysRevB.95.155125)
No full textn the original paper, we have discussed the valence instabilities of several mixed stack charge-transfer (CT) crystals following the approach proposed by D'Avino and Verstraete [1] that combines modified Hubbard model calculations with atomistic calculations to provide system-specific model parameters. In the present Erratum, we amend incorrect results in our paper concerning the calculation of the electrostatic (Madelung) energies and discuss their implications for the conclusions of our paper. I. CORRECT CALCULATION OF THE MADELUNG ENERGIES II. IMPLICATIONS OF THE MADELUNG ENERGY CORRECTION
Going Beyond Counting First Authors in Author Co-citation Analysis
Full text linkThe present study examines one of the fundamental aspects of author co-citation analysis (ACA) - the way co-citation
counts are defined. Co-citation counting provides the data on which all subsequent statistical analyses and mappings
are based, and we compare ACA results based on two different types of co-citation counting - the traditional type that
only counts the first one among a cited work's authors on the one hand and a non-traditional type that takes into
account the first 5 authors of a cited work on the other hand. Results indicate that the picture produced through this non-traditional author co-citation counting contains more coherent author groups and is therefore considerably clearer. However, this picture represents fewer specialties in the research field being studied than that produced through the traditional first-author co-citation counting when the same number of top-ranked authors is selected and analyzed. Reasons for these effects are discussed
Variations on the Author
Full text link“Variations on the Author” discusses two of Eduardo Coutinho’s recent films (Um Dia na Vida, from 2010, and Últimas Conversas, posthumously released in 2015) and their contribution to the general question of documentary authorship. The director’s filmography is characterized by a consistent yet self-effacing form of authorial self-inscription: Coutinho often features as an interviewer that rather than express opinions propels discourses; an interviewer that is good at listening. This mode of self-inscription characterizes him as an author who is not expressive but who is nonetheless markedly present on the screen. In Um Dia na Vida, however, Coutinho is completely absent form the image, while Últimas Conversas, on the contrary, includes a confessional prologue that moves the director from the margins to the center of his films. This article examines the ways in which these works stand out in the filmography of a director who offers new insights into the notion of cinematic authorship
Appropriate Similarity Measures for Author Cocitation Analysis
Full text linkWe provide a number of new insights into the methodological discussion about author cocitation analysis. We first argue that the use of the Pearson correlation for measuring the similarity between authors’ cocitation profiles is not very satisfactory. We then discuss what kind of similarity measures may be used as an alternative to the Pearson correlation. We consider three similarity measures in particular. One is the well-known cosine. The other two similarity measures have not been used before in the bibliometric literature. Finally, we show by means of an example that our findings have a high practical relevance.information science;Pearson correlation;cosine;similarity measure;author cocitation analysis
Dispelling the Myths Behind First-author Citation Counts
Full text linkWe conducted a full-scale evaluative citation analysis study of scholars in the XML research field to explore just how different from each other author rankings resulting from different citation counting methods actually are, and to demonstrate the capability of emerging data and tools on the Web in supporting more realistic citation counting methods. Our results contest some common arguments for the continued
use of first-author citation counts in the evaluation of scholars, such as high correlations between author rankings by first-author citation counts and other citation
counting methods, and high costs of using more realistic citation counting methods that are not well-supported by the ISI databases. It is argued that increasingly available digital full text research papers make it possible for citation analysis studies to go beyond what the ISI databases have directly supported and to employ more
sophisticated methods
koamabayili/VECTRON-author-checklist: VECTRON author checklist
No full textWe have done our best to complete the author checklist relating to the use of animals in the hut study. Note that the objective for the hut study was to evaluate the IRS treatment applications for residual efficacy against Anopheles mosquitoes, including the local An. coluzzii mosquito population. Cows were only used to attract mosquitoes into the huts and no tests were carried out directly on the cows. The author checklist is intended for use with studies where experiments are carried out on animals, which is why we have had such difficulty in completing this for the hut study, as many of the questions do not relate to how the cows were used
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