1,721,031 research outputs found
Time-Resolved Photoacoustic-Spectroscopy - New developments of an old idea
No full textAcoustic waves generated by heat emission in radiationless transitions from photoexcited molecules can be detected by suitable transducers. Their study allows the investigation of thermal relaxations, thus providing thermodynamic and kinetic data on short-lived species produced by the absorption of pulses of light.
In this field of research the best technique has proved to be the so-called pulsed-laser, time-resolved photoacoustic spectroscopy, which is based on piezoelectric detection of pressure waves in the time domain. Deconvolution processing of the transient signals gives both the lifetimes of excited states and the energy content of the transitions, provided that decay times are in the range 5 ns-5 mu s Moreover, when compared with proper theoretical models emphasizing the energy balance, the photoacoustic results can help to build a complete picture of the deactivation pathways, including photochemical events.
The biophysical applications, although numerous and widespread both in basic and applied research, offer the real possibility of giving information on photobiological processes in conditions very close to the living state.
Among the more significant contributions obtained in this area, the results on photosynthesis and photosensitivity of plants and photosynthetic micro-organisms, structural and functional dynamics of respiratory proteins, photocycles of rhodopsin and bacteriorhodopsin and photophysical properties of several natural pigments are particularly relevant, together with some medical and biotechnological applications.
Another promising field of application of photoacoustics concerns photoactive drugs and,the photophysics of fluorescent probes for conformational studies of proteins, nucleic acids and membranes. In general terms, time-resolved photoacoustic spectroscopy promises to become one of the most powerful techniques in photobiophysics, provided that some limitations in data analysis and time resolution are removed by technical improvements
Going Beyond Counting First Authors in Author Co-citation Analysis
Full text linkThe present study examines one of the fundamental aspects of author co-citation analysis (ACA) - the way co-citation
counts are defined. Co-citation counting provides the data on which all subsequent statistical analyses and mappings
are based, and we compare ACA results based on two different types of co-citation counting - the traditional type that
only counts the first one among a cited work's authors on the one hand and a non-traditional type that takes into
account the first 5 authors of a cited work on the other hand. Results indicate that the picture produced through this non-traditional author co-citation counting contains more coherent author groups and is therefore considerably clearer. However, this picture represents fewer specialties in the research field being studied than that produced through the traditional first-author co-citation counting when the same number of top-ranked authors is selected and analyzed. Reasons for these effects are discussed
Variations on the Author
Full text link“Variations on the Author” discusses two of Eduardo Coutinho’s recent films (Um Dia na Vida, from 2010, and Últimas Conversas, posthumously released in 2015) and their contribution to the general question of documentary authorship. The director’s filmography is characterized by a consistent yet self-effacing form of authorial self-inscription: Coutinho often features as an interviewer that rather than express opinions propels discourses; an interviewer that is good at listening. This mode of self-inscription characterizes him as an author who is not expressive but who is nonetheless markedly present on the screen. In Um Dia na Vida, however, Coutinho is completely absent form the image, while Últimas Conversas, on the contrary, includes a confessional prologue that moves the director from the margins to the center of his films. This article examines the ways in which these works stand out in the filmography of a director who offers new insights into the notion of cinematic authorship
Appropriate Similarity Measures for Author Cocitation Analysis
Full text linkWe provide a number of new insights into the methodological discussion about author cocitation analysis. We first argue that the use of the Pearson correlation for measuring the similarity between authors’ cocitation profiles is not very satisfactory. We then discuss what kind of similarity measures may be used as an alternative to the Pearson correlation. We consider three similarity measures in particular. One is the well-known cosine. The other two similarity measures have not been used before in the bibliometric literature. Finally, we show by means of an example that our findings have a high practical relevance.information science;Pearson correlation;cosine;similarity measure;author cocitation analysis
Dispelling the Myths Behind First-author Citation Counts
Full text linkWe conducted a full-scale evaluative citation analysis study of scholars in the XML research field to explore just how different from each other author rankings resulting from different citation counting methods actually are, and to demonstrate the capability of emerging data and tools on the Web in supporting more realistic citation counting methods. Our results contest some common arguments for the continued
use of first-author citation counts in the evaluation of scholars, such as high correlations between author rankings by first-author citation counts and other citation
counting methods, and high costs of using more realistic citation counting methods that are not well-supported by the ISI databases. It is argued that increasingly available digital full text research papers make it possible for citation analysis studies to go beyond what the ISI databases have directly supported and to employ more
sophisticated methods
Energy and Performance Analysis of Lossless Compression Algorithms for Wireless EMG Sensors
Full text linkElectromyography (EMG) sensors produce a stream of data at rates that can easily saturate a low-energy wireless link such as Bluetooth Low Energy (BLE), especially if more than a few EMG channels are being transmitted simultaneously. Compressing data can thus be seen as a nice feature that could allow both longer battery life and more simultaneous channels at the same time. A lot of research has been done in lossy compression algorithms for EMG data, but being lossy, artifacts are inevitably introduced in the signal. Some artifacts can usually be tolerable for current applications. Nevertheless, for some research purposes and to enable future research on the collected data, that might need to exploit various and currently unforseen features that had been discarded by lossy algorithms, lossless compression of data may be very important, as it guarantees no extra artifacts are introduced on the digitized signal. The present paper aims at demonstrating the effectiveness of such approaches, investigating the performance of several algorithms and their implementation on a real EMG BLE wireless sensor node. It is demonstrated that the required bandwidth can be more than halved, even reduced to 1/4 on an average case, and if the complexity of the compressor is kept low, it also ensures significant power savings
Recurrent neural network for human activity recognition in embedded systems using ppg and accelerometer data
Full text linkPhotoplethysmography (PPG) is a common and practical technique to detect human activity and other physiological parameters and is commonly implemented in wearable devices. However, the PPG signal is often severely corrupted by motion artifacts. The aim of this paper is to address the human activity recognition (HAR) task directly on the device, implementing a recurrent neural network (RNN) in a low cost, low power microcontroller, ensuring the required performance in terms of accuracy and low complexity. To reach this goal, (i) we first develop an RNN, which integrates PPG and tri-axial accelerometer data, where these data can be used to compensate motion artifacts in PPG in order to accurately detect human activity; (ii) then, we port the RNN to an embedded device, Cloud-JAM L4, based on an STM32 microcontroller, optimizing it to maintain an accuracy of over 95% while requiring modest computational power and memory resources. The experimental results show that such a system can be effectively implemented on a constrained-resource system, allowing the design of a fully autonomous wearable embedded system for human activity recognition and logging
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