22,449 research outputs found

    ELECTRONIC AND GEOMETRIC STRUCTURE OF ScH+ScH^{+} AND ScH2+ScH_{2}{^{+}}

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    Author Institution: Department of Chemistry, Michigan State UniversityThe electronic and geometric structures of ScH+ScH^{+} and ScH2+ScH_{2}^{+} have been studied using ab-inito MCSCF and Cl tychniques. The calculated bond lenth, DeD_{e} and ωe\omega_{e} for the first three states of ScH+ScH^{+} are [FIGURE] We calsulate the bond length in (1A1)ScH2+(^{1}A_{1})ScH^{+}_{2} to be 1.75\AA with an HScHH-Sc-H angle of 105.6105.6^{\circ}. While ScH2+ScH_{2}^{+} is strongly bond relative to ScH++HScH^{+}+H, preliminary results suggest the reaction ScH2+Sc++H2ScH_{2}^{+}\rightarrow Sc^{+}+H_{2} is isoergic. In addition to comparing these results to experiment we will present an analysis of the bonding

    Der Whodunit als Hilfsmittel im Fremdsprachenunterricht – dargestellt anhand von Jaume Fusters Claus de vidre

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    Häufig bewirkt der allfällige Übergang vom instrumentellen FSU zur Rezeption literarischer Texte einen Totalreset vorhanden geglaubter Kenntnisse. Dies ist jedoch durch die Wahl des geeigneten Textgenres vermeidbar. Der Artikel soll anhand der Claus de vidre des katalanischen Autors Jaume Fuster zeigen, warum und wie sich Kriminalrätsel besonders als Einstiegsliteratur eignen. Die Vorteile eines Whodunit-Textes für die Entwicklung des Leseverstehens auf der Basis rudimentärer oder gar nicht vorhandener Sprachkenntnisse lassen sich mittels einer wenig erlernten Sprache besonders schön illustrieren. Offenkundig beflügelt das apriorische Wissen von einer rationalen Erklärung für das Mysterium eines aufzuklärenden Verbrechens die Sprachwahrnehmungsfähigkeit regelrecht. Dabei scheint die nachgestellte „Detektivarbeit“ gerade die konzentrische Perzeption nicht unmittelbar tatbezogener Textteile zu befördern.The Whodunit as an instrument in foreign language lessons – described by means of Jaume Fuster’s Claus de vidre The necessary transition from instrumental foreign language lessons to the reading of literary texts often will be accompanied by a total reset of supposed knowledge. This might be avoided by a smart text-selection. The article, using the example of the Catalan author Jaume Fuster and his Claus de vidre, shall prove, why and in which way criminal riddles are specially suitable as beginner’s reading. The advantages of Whodunits in order to improve comprehension of written texts based on low or inexistent language experience might be illustrated especially well by introducing a rather marginal language. Obviously, the previous confidence in the existence of a reasonable explanation about the criminal mystery unchains the evolution of linguistic awareness. It’s surprising that the imitation of the detective’s job seems to improve the concentric perception even of those parts of the text which don’t keep any direct relation with the crime.Häufig bewirkt der allfällige Übergang vom instrumentellen FSU zur Rezeption literarischer Texte einen Totalreset vorhanden geglaubter Kenntnisse. Dies ist jedoch durch die Wahl des geeigneten Textgenres vermeidbar. Der Artikel soll anhand der Claus de vidre des katalanischen Autors Jaume Fuster zeigen, warum und wie sich Kriminalrätsel besonders als Einstiegsliteratur eignen. Die Vorteile eines Whodunit-Textes für die Entwicklung des Leseverstehens auf der Basis rudimentärer oder gar nicht vorhandener Sprachkenntnisse lassen sich mittels einer wenig erlernten Sprache besonders schön illustrieren. Offenkundig beflügelt das apriorische Wissen von einer rationalen Erklärung für das Mysterium eines aufzuklärenden Verbrechens die Sprachwahrnehmungsfähigkeit regelrecht. Dabei scheint die nachgestellte „Detektivarbeit“ gerade die konzentrische Perzeption nicht unmittelbar tatbezogener Textteile zu befördern.The Whodunit as an instrument in foreign language lessons – described by means of Jaume Fuster’s Claus de vidre The necessary transition from instrumental foreign language lessons to the reading of literary texts often will be accompanied by a total reset of supposed knowledge. This might be avoided by a smart text-selection. The article, using the example of the Catalan author Jaume Fuster and his Claus de vidre, shall prove, why and in which way criminal riddles are specially suitable as beginner’s reading. The advantages of Whodunits in order to improve comprehension of written texts based on low or inexistent language experience might be illustrated especially well by introducing a rather marginal language. Obviously, the previous confidence in the existence of a reasonable explanation about the criminal mystery unchains the evolution of linguistic awareness. It’s surprising that the imitation of the detective’s job seems to improve the concentric perception even of those parts of the text which don’t keep any direct relation with the crime

    Reactions of ruthenium and platinum thiolates and the development of novel homogeneous catalysts of Claus chemistry

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    The complexes CpRu(PPhsb3) sb3)(L)SR (Cp=etasp5 eta sp5-cyclopentadienyl; R=CMesb3, sb3, CHMesb2, sb2, 4-rmCsb6Hsb4Me) rm C sb6H sb4Me) reacted with NOBFsb4 sb4 to give either (CpRu(PPhsb3) sb3)(NO)SR) BFsb4 sb4 (L=PPhsb3) sb3) or complexes containing disulfide ligands (L=CO). The bisphosphine complexes, CpRu(PPhsb3)sb2 sb3) sb2SR, reacted with HBFsb4 sb4 to give the corresponding thiol complex salts (CpRu(PPhsb3)sb2 sb3) sb2(HSR)) BFsb4 sb4 and with (MeSSMErmsb2rbrackBFsb4 rm sb2 rbrack BF sb4 to give (CpRu(PPhsb3)sb2 sb3) sb2(SMesb2) sb2)) BFsb4 sb4 regardless of the starting thiolates. The complexes CpRu(PPhsb3)sb2 sb3) sb2SR reacted with the sulfur transfer agent MeSphth (phth=phthalimido) to give CpRu (PPhsb3)sb2 sb3) sb2(phth) and the dimers (mu mu-SMe)(mu mu-SR) (CpRu(phth)) sb2 sb2 for R=CMesb3 sb3 or CHMesb2, sb2, while for R=4-rmCsb6Hsb4Me rm C sb6H sb4Me the same reaction gave CpRu(PPhsb3) sb3)(phth)(MeSS-4-rmCsb6Hsb4Me) rm C sb6H sb4Me) and (mu mu-SMe)(mu mu-S-4-rmCsb6Hsb4 rm C sb6H sb4Me) (CpRu(S-4-rmCsb6Hsb4Me)rbracksb2. rm C sb6H sb4Me) rbrack sb2. The complex CpRu(PPhsb3)sb2 sb3) sb2 SCHsb2 sb2CH=CHsb2, sb2, prepared from the reaction of CpRu(PPhsb3)sb2 sb3) sb2Cl and LiSCHsb2 sb2CH=CHsb2, sb2, reacted with CO and CSsb2 sb2 to give CpRu(PPhsb3) sb3)(CO)SCHsb2 sb2CH=CHsb2 sb2 and CpRu(PPhsb3) sb3)Ssb2 sb2CSCHsb2 sb2CH=CHsb2, sb2, respectively. Refluxing a toluene solution of CpRu(PPhsb3)sb2 sb3) sb2SCHsb2 sb2CH=CHsb2 sb2 gave (musb3 mu sb3-S)sb2(mu sb2( mu-SCHsb2 sb2CH=CHsb2 sb2) (CpRu) sb3 sb3 in which the C-S bond has been cleaved.The complexes (PPhsb3)sb2 sb3) sb2Pt(SR)sb2 sb2 (R=H, rmCMesb3,CHMesb2, rm CMe sb3, CHMe sb2, 4-rmCsb6Hsb4Me) rm C sb6H sb4Me) were treated with SOsb2 sb2 as models for the Claus process. These reactions produced adducts of formula (PPhsb3)sb2 sb3) sb2Pt(S(SOsb2) sb2)R)sb2, sb2, which have a labile thiolate-bound SOsb2 sb2 molecule, for R=CMesb3, sb3, 4-rmCsb6Hsb4Me rm C sb6H sb4Me and CHMesb2. sb2. The reaction of cis-(PPhsb3)sb2 sb3) sb2Pt(SH)sb2 sb2 with SOsb2 sb2 gave (PPhsb3)sb2 sb3) sb2Pt(Ssb3 sb3O) and Hsb2 sb2O, a reaction which mimics Claus chemistry. The complexes cis-(PPhsb3)sb2 sb3) sb2Pt(SH)sb2, sb2, (PPhsb3)sb2 sb3) sb2Pt(Ssb3 sb3O) and (PPhsb3)sb2 sb3) sb2Pt(SR)sb2 sb2 catalyze the Claus reaction (2Hsb2 sb2S + SOrmsb2to3/8Ssb8+2Hsb2O). rm sb2 to3/8S sb8+2H sb2O).The complexes (PPhsb3)sb2 sb3) sb2Pt(SR)sb2 sb2 reacted with CSsb2 sb2 to form the mixed thiolato-thioxanthato complexes (PPhsb3) sb3)Pt(SR)(Ssb2 sb2CSR) wherein CSsb2 sb2 had inserted into one of the Pt-S bonds. The complex cis-(PPhsb3)sb2 sb3) sb2Pt(SH)sb2 sb2 reacted with CSsb2 sb2 to give the known complex, (PPhsb3)sb2 sb3) sb2Pt(Ssb2 sb2CS), which contains a trithiocarbonate group.The structures of (CpRu(PPhsb3) sb3)(NO)SCMermsb3rbrackBFsb4,(mu rm sb3 rbrack BF sb4, ( mu-SMe)(mu mu-S-4-rmCsb6Hsb4Me) rm C sb6H sb4Me) (CpRu(S-4-rmCsb6Hsb4Me)rbracksb2,(musb3 rm C sb6H sb4Me) rbrack sb2, ( mu sb3-S)sb2(mu sb2( mu-SCHsb2 sb2CH=CHsb2) sb2) (CpRu) sb3, sb3, (PPhsb3)sb2 sb3) sb2Pt(Ssb3 sb3O) and (PPhsb3) sb3)Pt(S-4-rmCsb6Hsb4Me) rm C sb6H sb4Me)(Ssb2 sb2CS-4-rmCsb6Hsb4Me) rm C sb6H sb4Me) were determined by x-ray crystallography

    کریگ کنسیڈائن کی کتاب’’The Humanity of Muhammad: A Christian View‘‘کا تجزیاتی مطالعہ: An Analytical study of Craig Considine’s Book “The Humanity of Muhammad: A Christian View”

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    Analytical Review of Craig Considines, The Humanity of Muhammad: A Christian View (December 2020) This book, in particular, published in 2020, aims to create stronger bonds of understanding and peace between Christians and Muslims whose common human values continue to be promoted and Prophet Muhammad (PBUH) is protected. The author discusses several aspects of the Prophet’s life, religious pluralism, social justice, women’s rights, and the importance of knowledge, explaining these as remedies for our contemporary challenges. It references Quranic verses, Hadith, historical events and Sufi poetry as supplementary evidence in order to support its main arguments, that the basis of Islam is founded atop compassion and justice. It gained widespread acclaim but faced criticism for deviations from traditional Islamic teachings, including its unique interpretation of the finality of Prophethood. This review investigates where the book contributes to interfaith harmony as well as academic discourse in the field while also accounting for its limits

    Sugar-sweetened beverage consumption among a subset of Canadian youth

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    BACKGROUND Sugar-sweetened beverages ( SSBs) may play a role in increased rates of obesity. This study examined patterns and frequencies of beverage consumption among youth in 3 distinct regions in Canada, and examined associations between beverage consumption and age, sex, body mass index ( BMI), physical activity and dieting behavior, as well as beverage displacement. METHODS The study included data from 10,188 youth (ages 13-18) from Hamilton and Thunder Bay, Ontario, and Prince Edward Island ( PEI) in 2009 to 2010. The study used in-school self-reported surveys with 12 questions regarding beverage consumption during the previous day, along with self-reported height, weight, physical activity levels, and demographic information. Logistic regression analyses were conducted to examine variables associated with SSB intake. RESULTS Overall, 80% of youth consumed at least 1 SSB in the previous day, with 44% consuming 3 or more SSBs. Youth in Thunder Bay consumed significantly more SSBs than Hamilton and PEI, and youth in Hamilton consumed more SSBs than PEI. Boys consumed significantly more SSBs than girls. Older and more physically active youth consumed significantly fewer SSBs. No significant association between BMI and SSB consumption was observed in any model. A modest positive correlation was identified between SSB consumption and milk (r = .06, p < .001) and 100% fruit juice (r = .10, p < .001). CONCLUSIONS A large proportion of youth consumed SSBs, many at high levels. Research evaluating SSB policy and interventions should be considered a priority

    "آدمی" از عرفان جاوید: تجزیاتی مطالعہ: “Aadmi” by Irfan Javed : Analytical Study

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    Man and mannerism is study focus of those literary critics who have given respect and value to humanity as social being and master piece of creation on the earth by God Almighty. Author under discussion Irfan javed has effective interaction with high caliber literary personalities and explored their attributes through insight regarding intellectualism and literary contribution.Sketch writing&nbsp;in literature is like sculpture making type art where brush and hammer are used to develop a pen picture, same has been performed by the author of “Naya Aadmi, Purana Aadmi” First sketch by the author is museum of aesthetics and blend of old and new which inspire the reader up to the ending of sketch. The author of this article has highlighted critically how interaction is source of learning for the generation of readers. Author's viewpoint and critical thinking skills have opened new ways to study sketch writing

    جہانِ دانش میں سیاسی وسماجی منظرنامہ: SOCIO-POLITICAL SCENARIO IN AUTOBIOGRAPHY “JAHAN-E-DANISH”

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    The autobiography, "Jahan-e-Danish", by Ahsaan Danish, is a narrative description comprising the life-story of the author himself, who was awarded the titles "The Labourers' Poet" and "The Poet of Nature". There is a vivid observation of human psychology at one place and the complete political scenario of the contemporary era, on the other place. This autobiography is an anthology of exceptional memories of the author in which there is an obvious description of deep thought along with various aspects of fine criticism. This book can be described as a miscellany of memories of well-known personalities, a story of literary meetings of poets and writers, the feelings of the author himself and the trends and interests of a popular poet. This is, in short, a vase, full of many varied flowers and every flower has its own unique, distinct fragrance.

    ’’اردو افسانہ۔ ایک صدی کا قصہ‘‘کا تجزیاتی مطالعہ: A CRITICAL STUDY OF‘URDU AFSANA. AIKSADI KA QISA’

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    Anwar Ahmed is distinguished and esteemed critic of Urdu fiction. This article shows the study of his remarkable book, ‘‘Urdu Afsana - Aik Sadi ka Qisa’’. He is generally known as progressive critic of Urdu. He expressed the history of Urdu short story in the form of tradition. Basically this book is divided into two parts; tradition of Praim Chand and realization of tradition. The author has explored and criticized the art of short story of two hundred and fortyfive Urdu short story writers. In this article first of all an eye bird view is taken of his book. Secondly, principles of research which the author exercises in this book are conversed. Thirdly author's research along with analytical process is separately observed. Lastly being author is progressive critic his progressive criticism is deeply studied in this article

    INVESTIGATING THE IMPACT OF SONGS ON VOCABULARY OF HIGH SCHOOL ESL LEARNERS OF THE SELECTED PRIVATE SCHOOLS IN LAHORE

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    The purpose of this study was to find out how songs impact ESL students' vocabulary studying in a private high school in Lahore. Gardner's Theory of Multiple Intelligences served as the study's theoretical foundation. The quantitative study used a survey and quasi-experimental approach. The research subjects were thirty ninth and tenth grades from several private schools in Lahore. The students were selected through convenience sampling. This study used pre- and post-tests as a basis for quasi-experimental research. The impact of the selected treatment was analyzed through SPSS software, using the paired t test. The Songs technique seems to have a marginally greater impact on vocabulary scores than the conventional technique, as indicated by the higher Cohen's d. Language Policy makers, curriculum designers and teachers may find the results valuable in incorporating songs as teaching methodology in the curriculum and classroom activities

    A Study to Analyze Collaboration Patterns for Asian Library and Information Science (LIS) Scholars on Author, Institutional and Country Levels

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    The aim of the present study is to determine the collaborative activities of Asian library and information science (LIS) researchers through bibliometric, social network analysis at the author, institution, and country levels of the LIS publications produced by Asian researchers. For the study, research articles were derived from the 1994-2013 Web of Science (WoS) archives. Coauthor analysis software was used to analyze author contributions on the New Modified Author Activity Index (NMAAI(1, 2, 3))-a measurement tool to evaluate author research activities. Results reveal (a) that LIS &quot;institutions collaboration pattern&quot; outcomes did not yield strong collaboration with Asian countries or regions, (b) intracontinent and intercontinent collaboration was less harmonious on institutional and author levels, and (c) interpretation through NMAAI(1,2,3) revealed that Asian countries did not produce sufficient collaborative LIS publications. Taiwan, South Korea, Singapore, India, Iran, Israel, and Turkey have been producing ample LIS papers, but the United States and United Kingdom emerged as leaders. This work provides a holistic view of Asian LIS development and emphasizes individual levels of collaboration, finding that most influential authors serve on coauthor networks, which differentiates this study from previous studies in the LIS field. There is immense need to develop liaisons, sign memoranda of understanding (MOUs), and participate in combined research plans and short-term research exchange programs.BIT; National Science Foundation of China (NSFC) [71033001, 71273030]; MOST of China [2012DFG11750][email protected]
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