1,466 research outputs found

    Chamber Studies and Modeling of Secondary Organic Aerosol Formation

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    Secondary organic aerosol (SOA), formed from atmospheric oxidation of gas-phase hydrocarbons, comprise a large fraction of ambient particulate matter. Significant uncertainties exist in identifying the sources and mechanisms responsible for SOA formation, making it difficult to understand its impact on global climate and local air quality. Laboratory chambers have been a valuable tool to study underlying chemical mechanisms of SOA formation and to quantify SOA formation from select hydrocarbons in a controlled environment. However, a good understanding of the chemical processes involved is required to be able to extrapolate data acquired from smog chamber studies. This thesis presents results from experimental investigation of SOA formation from atmospherically important compounds, and model simulations of kinetic mechanisms involved in SOA formation. The distinguishing mechanism of SOA formation is the partitioning of semivolatile hydrocarbon oxidation products between the gas and aerosol phases. While SOA formation is typically described in terms of partitioning only, the rate of formation and ultimate yield of SOA can also depend on the kinetics of both gas- and aerosol-phase processes. Here a general equilibrium/kinetic model of SOA formation is presented to provide a framework for evaluating the extent to which the controlling mechanisms of SOA formation can be inferred from laboratory chamber data. Current atmospheric models systematically underpredict SOA formation, suggesting that in current models, 1) signicant SOA precursors could be missing and 2) SOA forming processes could be misrepresented. Aerosol formation from oxidation of 2-methyl-3-buten-2-ol (MBO) and polycyclic aromatic hydrocarbons (PAHs), two important classes of compounds previously assumed to be an insignicant SOA source, is studied. Upon photooxidation, MBO produces glyoxal (an important SOA intermediate), but the yields are too low to be atmospherically important. Photooxidation of napthalene and other 2-ring PAHs leads to substantial amounts of aerosol, and can account for a large fraction of SOA formed from oxidation of diesel exhaust and other primary emissions. Isoprene is a signicant source of atmospheric organic aerosol; however, the oxidation pathways that lead to SOA have remained elusive. Under remote low-NOx conditions, epoxydiols are formed from gas-phase photooxidation of isoprene, and are found to undergo reactive uptake to lead to low-volatility compounds, such as C5-methyltetrols and organosulfates observed in ambient particulate matter. Under urban high-NOx conditions, methacrolein, an important C4 aldehyde formed from isoprene oxidation, is found to form SOA via reaction with NO2 to form peroxy methacryloyl nitrate, which subsequently forms low-volatility oligoester products. As a result of radical chemistry of aldehydes, SOA formation from isoprene depends critically on the NO2/NO ratio, and the implications on ambient aerosol formation are discussed.</p

    IMPLEMENTASI LAYANAN INFORMASI KARIR UNTUK MEMBANTU KESIAPAN PESERTA DIDIK DALAM PEMILIHAN KARIR DI SMA YP UNILA BANDAR LAMPUNG

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    ABSTRAK Peneliti memperoleh gambaran bahwa peserta didik Di SMA YP UNILA Bandar Lampung masih ada beberapa siswa yang masih bingung tentang sekolah lanjutan setelah dari SMA dan juga menentukan arah hidupnya atas apakah ingin melanjutkan pendidikan ke perguruan tinggi atau bekerja. Berdasarkan hal tersebut penulis tertarik untuk djudul “Implementasi Layanan Informasi Karir Untuk Membantu Kesiapan Peserta Didik Dalam Pemilihan Karir di SMA YP UNILA Bandar Lampung”. Adapun Tujuan dari penelitian ini pertama, untuk mengetahui dan manganalisis bagaimana Implementasi layanan informasi karir untuk membantu kesiapan peserta didik dalam pemilihan karir di SMA YP UNILA Bandar Lampung. Kedua, Untuk mengetahui dan manganalisis apa saja hambatan-hambatan yang ada dalam implementasi layanan informasi karir untuk membantu kesiapan peserta didik dalam pemilihan karir di SMA YP UNILA Bandar Lampung. Ketiga, Untuk mengetahui dan manganalisis seperti apa hasil daripada implememtasi layanan informasi karir untuk membantu kesiapan peserta didik dalam pemilihan karir di SMA YP UNILA Bandar Lampung. Metode Penelitian adalah pendekatan kualitatif, penelitian ini termasuk kedalam jenis penelitian lapangan (field research). Penelitian ini menggunakan teknik pengumpulan data berupa wawancara, observasi dan dokumentasi. Data primer sumber data yang didapat melalui wawancara dengan guru bimbingan dan konseling. Data sekunder didapat melalui media perantara yang dapat berupa dokuementasi dari responden yaitu guru bimbingan dan konseling di SMA YP UNILA Bandar Lampung. Penelitian ini dilaksanakan mulai dari perencanaan yang berupa penyusunan RPL (Rancangan Perencanaan Layanan). Kemudian dalam pelaksanaanya pertama, kegiatan pendahuluan. Kedua, kegiatan inti dan ketiga, kegitan penutup. Kemudian setelah selesai pelaksanaanya dilanjut dengan tahap akhir yakni tahap evaluasi. Pada tahap evaluasi dalam implementasi layanan informasi tentang karir untuk membantu kesiapan peserta didik dalam pemilihan karir di SMA YP UNILA Bandar Lampung dilakukan melalui dua tahap evaluasi yakni evaluasi proses dan evaluasi hasil. Dimana Kedua jenis evaluasi ini penting dalam memastikan efektivitas dan keberhasilan suatu aktivitas atau proyek. iv Berdasarkan pada hasil penelitian yang dilakukan oleh peneliti seputar Implementasi layanan informasi tentang karir untuk membantu kesiapan peserta didik dalam pemilihan karir di SMA YP UNILA Bandar Lampung tedapat hambatan dalam pelaksanaanya berupa kurang akuratnya informasi yang didapat, kemudian keberagaman karir dari tiapindividu peserta didik. Akan tetapi hasil dari implementasi layanan informasi tentang karir untuk membantu kesiapan peserta didik dalam pemilihan karir di SMA YP UNILA Bandar Lampung yakni tentunya peserta didik dapat memperoleh solusi dari layanan informasi karir terkait pemilihan karir mereka. Kata Kunci : Implementasi, Layanan Informasi Karir, Peserta Didik v ABSTRACT The researcher obtained an illustration that there were still some students at YP UNILA SMA Bandar Lampung who were still confused about going to secondary school after high school and also determining the direction of their life whether they wanted to continue their education to college or work. Based on this, the author is interested in the title "Implementation of Career Information Services to Assist Students' Readiness in Career Choices at SMA YP UNILA Bandar Lampung". The objectives of this research are 1. To find out and analyze how career information services are implemented to help students' readiness in choosing a career at SMA YP UNILA Bandar Lampung. 2. To find out and analyze what obstacles exist in implementing career information services to help students' readiness in choosing a career at SMA YP UNILA Bandar Lampung. 3. To find out and analyze the results of implementing career information services to help students' readiness in choosing a career at SMA YP UNILA Bandar Lampung. The research method is a qualitative approach, this research is included in the type of field research. This research uses data collection techniques in the form of interviews, observation and documentation. Primary data is a source of data obtained through interviews with guidance and counseling teachers regarding the Implementation of Career Information Services to Assist Students' Readiness in Career Choices at YP UNILA SMA Bandar Lampung. Secondary data sources are obtained through intermediary media which can be in the form of documentation from respondents, namely guidance and counseling teachers at SMA YP UNILA Bandar Lampung. This research was carried out starting from planning in the form of preparing an RPL (Service Planning Plan). Then in the first implementation, preliminary activities. Second, core activities and third, closing activities. Then after completion of the implementation, it continues with the final stage, namely the evaluation stage. At the evaluation stage, the implementation of career information services to help students' readiness in choosing a career at SMA YP UNILA Bandar Lampung was carried out through two evaluation stages, namely process evaluation and results evaluation. Where these two types of evaluation are important in ensuring the effectiveness and success of an activity or project. Based on the results of research conducted by researchers regarding the implementation of information services about careers vi to help students' readiness in choosing a career at SMA YP UNILA Bandar Lampung, there are obstacles in its implementation in the form of less accurate information obtained, then the diversity of careers for each individual student. However, the result of implementing information services about careers to help students' readiness in choosing a career at YP UNILA High School Bandar Lampung is that of course students can get solutions from career information services regarding their career choices. Keyword : Implementation, Career Information Services, Student

    Yeast Particle Encapsulation of Scaffolded Terpene Compounds for Controlled Terpene Release

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    Terpenes are naturally occurring compounds produced by plants that are of great commercial interest in the food, agricultural, cosmetic, and pharmaceutical industries due to their broad spectra of antibacterial, antifungal, anthelmintic, membrane permeation enhancement, and antioxidant biological activities. Applications of terpenes are often limited by their volatility and the need for surfactants or alcohols to produce stable, soluble (non-precipitated) products. Yeast particles (YPs) are hollow, porous microspheres that have been used for the encapsulation of terpenes (YP terpenes) by passive diffusion of terpenes through the porous YP cell walls. We here report the development of a second generation YP encapsulated terpene technology that incorporates the stimuli-responsive control of terpene release using biodegradable pro-terpene compounds (YP pro-terpenes). YP terpenes and YP pro-terpenes were both produced, in which high levels of carvacrol, eugenol, thymol and geraniol were encapsulated. The YP pro-terpenes show higher encapsulation stability than YP terpenes due to pro-terpenes being non-volatile solids at room temperature and stable in suspensions at neutral pH. YP pro-terpenes and YP terpenes were evaluated for biological activity in antibacterial, antifungal and anthelmintic assays. The YP pro-terpenes retained the full biological activity of the parent terpene compound

    ELECTRONIC TRANSITIONS OF YTTRIUM MONOPHOSPHIDE

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    Electronic transition spectrum of the yttrium monophosphide (YP) molecule in the visible region between 715 nm and 880 nm has been recorded using laser ablation/reaction free-jet expansion and laser induced fluorescence spectroscopy. The YP molecule was produced by reacting laser - ablated yttrium atoms with PH3_{3} seeded in argon. Thirteen vibrational bands were analyzed and five electronic transition systems have identified, namely the [12.2] OmegaOmega = 3 - X3Pi2^{3} Pi_2 transition, [13.3] OmegaOmega = 3 - X3Pi2^{3} Pi_2 transition, [13.4] OmegaOmega = 3 - X3Pi2^{3} Pi_2 transition, [13.5] OmegaOmega = 3 - X3Pi2^{3} Pi_2 transition, and [13.4] OmegaOmega = 2 - X3Pi2^{3} Pi_2 transition. Least squares fits of the measured rotational lines yielded molecular constants for the ground and excited states. The ground state symmetry and the bond length r0_0 of the YP molecule have been determined to be a X3Pi2^{3} Pi_2 state and 2.4413 AAAA respectively in this work. A molecular orbital energy level diagram has been used to help the assignment of the observed electronic states. This work represents the first experimental investigation of the spectrum of the YP molecule.Made available in DSpace on 2016-01-05T20:04:33Z (GMT). No. of bitstreams: 3 810.pdf: 17485 bytes, checksum: 98e8b711e6857182357039c2c438f5ab (MD5) 297270.pptx: 1776837 bytes, checksum: 402b4836a9268184b2be815646e9a43b (MD5) license.txt: 4813 bytes, checksum: 715c4321821a960fa1a1e91d2ac7ebce (MD5) Previous issue date: 2

    A note on Condorcet consistency and the median voter

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    We discuss to which extent the median voter theorem extends to the domain of single-peaked preferences on median spaces. After observing that on this domain a Condorcet winner need not exist, we show that if a Condorcet winner does exist, then it coincides with the median alternative ('the median voter'). Based on this result, we propose two non-cooperative games that implement the unique strategy-proof social choice rule on this domain. --

    居港權引發的憲法爭論

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    通過對香港居民在內地所生子女的居港權訴訟的分析,本書探討香港與中國內地關係的法律和憲法問題。該案件在香港法院的訴訟及全國人大常委會的隨後解釋在香港受到極大的關注,並引起了很大的爭論。香港法院與人大常委會解釋法律的不同方式正是香港憲制中的兩種不同法律制度衝突的生動寫照。 在本書中,香港知名的法律專家和律師對該案件有關問題進行分析討論,並對解決這些問題,特別是《基本法》的解釋問題,提出一個可行的方法。本書同時收錄公眾對該案的迴響及有關的法律文件,藉以為香港特區第一個重大的憲法危機提供一個歷史記錄

    Meningite por Haemophilus Influenzae: aspectos selecionados.

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    Trabalho de Conclusão de Curso - Universidade Federal de Santa Catarina, Centro de Ciências da Saúde, Departamento de Pediatria, Curso de Medicina, Florianópolis, 198

    The dispersion characteristics of the waves propagating in a spinning single-walled carbon nanotube

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    As the nano-motor becomes a mechanical reality, its prototype can be envisaged as nano-sized rotating machinery at a situation, albeit for different purposes, like that in the first half of the 20th century during which rotor dynamics has contributed to boosting machine power capacity. Accordingly, we take the benefit of hindsight to develop a classical framework of vibration analysis. Essentially, the equations of motion are formulated to cope with both the special carbon-nanotube properties and the first author's previously developed spinning beam formalism, establishing a model satisfactorily verified by some available molecular dynamics (MD) data and classical spinning beam results extracted from the literature. The model is inexpensive based on continuum mechanics as an alternative to the less-flexible MD method for simulating wave motion of the spinning single-walled carbon nanotube, yielding several interesting phenomena, including the fall-off and splitting of the wave characteristic curves and the unexpected gyroscopic phase property. Potential applications are proposed
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