1,140 research outputs found

    Object-oriented programming using C++

    No full text
    This book is an excellent start for the professional programmer who wants to master C++ for use in an object-oriented environment. No knowledge of C is required. The author completes instruction in C++ in the first four chapters before moving on to a demonstration of its outstanding contributions to object-oriented methodology

    Temperature dependence of the muon and proton hyperfine constants of an \alpha‐muonium‐substituted methyl radical

    No full text
    Muon hyperfine constants A_μ have been measured by transverse field μSR for (CH3)3Si\mbox\.CHMu in hexane from 167 K to 332 K. In addition, avoided level‐crossing resonance was used to determine \alpha‐proton coupling constants Ap over a similar range of temperatures. The two hyperfine constants can be described by a common temperature dependence, d|Ai|/ dT=1.4\times 10-3 MHz\,K-1, where Ai represents Ap or the reduced muon constant A^\prime_μ=0.3141A_μ. There is a small isotope effect (A^\prime_μ is 2.2 % larger than Ap) consistent with zero‐point motion in the anharmonic C–H bond stretch. The common temperature dependence is tentatively attributed to a coupled deviation of the C–H and C–Mu bonds out of the nodal plane of the p orbital containing the unpaired electron.Peer reviewedFinal article publishedMuon Spin RotationNodal PlaneEthylsilaneBond StretchDiamagnetic Signa

    Enolization of acetone in superheated water detected via radical formation

    No full text
    Peer reviewedMuoniated free radicals have been detected in muon-irradiated aqueous solutions of acetone at high temperatures and pressures. At temperatures below 250 °C, the radical product is consistent with muonium addition to the keto form of acetone. However, at higher temperatures, a different radical was detected, which is attributed to muonium addition to the enol form. Muon hyperfine coupling constants have been determined for both radicals over a wide range of temperatures, significantly extending the range of conditions under which these radicals and the keto−enol equilibrium have been studied.Final article publishe

    The C++ programming language

    No full text
    The new C++11 standard allows programmers to express ideas more clearly, simply, and directly, and to write faster, more efficient code. Bjarne Stroustrup, the designer and original implementer of C++, has updated his definitive reference and tutorial for everyone who uses the language and needs to understand its latest version. The C++ Programming Language, Fourth Edition, delivers meticulous, richly explained, and integrated coverage of the entire language—its facilities, abstraction mechanisms, standard libraries, and key design techniques. Throughout, Stroustrup presents concise, “pure C++11” examples, which have been carefully crafted to clarify both usage and program design. To promote deeper understanding, the author provides extensive cross-references, both within the book and to the ISO standard

    Detection of the muoniated methyl radical

    No full text
    The muoniated methyl radical has been detected in a sample of liquid ketene irradiated with positive muons. The muon and proton hyperfine coupling constants were measured at 184 K by transverse field muon spin rotation and avoided muon level-crossing resonance, respectively. After correction for the differing magnetic moments, the muon hyperfine constant is only 3% larger than that of the proton. This small isotope effect can be attributed to zero-point motion in the anharmonic C-H (C-Mu) stretch.Peer reviewedFinal article publishe

    Evolution of the G+C content frontier in the rat cytomegalovirus genome

    No full text
    Within the 230138 bp of the rat cytomegalovirus (RCMV) genome, the G+C content changes abruptly at position 142644, constituting a G+C content frontier. To the left of this point, overall G+C content is 69.2%, and to the right it is only 47.6%. A region of extremely low G+C content (33.8%) is found in the 5 kb immediately to the right of the frontier, in which there are no predicted coding sequences. To the right of position 147501, the G+C content rises and predicted coding sequences reappear. However, these genes are much shorter (average 848bp, 50% G+C) than those in the left two-thirds of the genome (average 1462bp, 70% G+C). Whole genome alignment of several viruses indicates that the initial ultra-low G+C region appeared in the common ancestor of the genera Cytomegalovirus and Muromegalovirus, and that the lowering of G+C in the right third has been a subsequent process in the lineage leading to RCMV. The left two-thirds of RCMV has stop codon occurrences at 67.5% of their expected level, based on a modified Markov chain model of stop codon distribution, and the corresponding figure for the right third is 78%. Therefore, despite heavy mutation pressure, selective constraint has operated in the right third of the RCMV genome to maintain a degree of gene length unusual for such low G+C sequences

    Data Structures, Algorithms & Software Principles In C

    No full text
    Using C, this book develops the concepts and theory of data structures and algorithm analysis in a gradual, step-by-step manner, proceeding from concrete examples to abstract principles. Standish covers a wide range of both traditional and contemporary software engineering topics. The text also includes an introduction to object-oriented programming using C++. By introducing recurring themes such as levels of abstraction, recursion, efficiency, representation and trade-offs, the author unifies the material throughout. Mathematical foundations can be incorporated at a variety of depths, allowing the appropriate amount of math for each user

    Intramolecular motion and isotope effects in muonium‐substituted chloroalkyl radicals

    No full text
    Muon irradiation of pure liquid 3‐chloropropene, CH2=CH-CH2Cl, yields a primary radical, \dot\mboxCH2-CHMu-CH2Cl, and a secondary radical, MuCH2-\rm\dot\mboxCH-CH2Cl. 2‐methyl‐3‐chloropropene yields only the tertiary radical, MuCH2-\rm\dot\mboxC(CH3)-CH2Cl. These three chloroalkyl radicals have been characterized by μSR and μLCR, and the hyperfine coupling constants (hfcs) have been determined over a range of temperatures, either in the pure liquid precursor or in concentrated solution. The temperature variation of the hfcs has been analyzed to obtain estimates of the barrier to internal rotation about the C_\alpha-C_\beta axis for various alkyl groups, and also their minimum energy conformations, i.e. their orientations with respect to the axis of the 2p_z orbital of the unpaired electron. The tertiary radical is particularly interesting because all three methyl‐like groups, -CH3,-CH2Cl and -CH2Mu, are represented. The results can be compared to electron spin resonance data for analogous radicals, to provide information on the effects of Mu substitution for H.Peer reviewedFinal article publishedfESRIsotope EffectRotational BarrierElectron Spin Resonance DataMinimum Energy Conformatio
    corecore