1,722,063 research outputs found
American Medical Associaiton Symposium Prospects for the Control of Poliomyelitis -- 1955 -- Poliomyelitis, Conferences/Committees -- letter, 1955-05-26
Letter from Bauer, W. W. to Sabin, Albert B. dated 1955-05-26.Sabin Collection Fair Use Policy</a
VINYLLITHIUM - DYNAMIC BEHAVIOR IN TETRAHYDROFURAN SOLUTION AND COMPREHENSIVE ANALYSIS OF NMR SPIN-SPIN COUPLING-CONSTANTS
Vinyllithium (ViLi; isotopically labeled with Li-6) is an 8:1 tetramer/dimer equilibrium in tetrahydrofuran-d8 (THF-d8) at -90-degrees-C (1.6 M solution). In the presence of equilmolar amounts of TMEDA (tetramethylethylenediamine), the tetramer:dimer ratio is 1:13 in THF-d8 at -80-degrees-C (1.9 M solution). Dynamic NMR phenomena are observed in the ViLi tetramer: at -90-degrees-C in THF-d8, a 'static' aggregate is found, whereas at -60 -degrees-C rapid intraaggregate exchange of the four lithium sites indicates a 'fluxional' tetramer. Within a 'static' tetramer, rapid tumbling of a monomer unit is deduced from C, Li and H, Li NMR coupling patterns. From tilts within cross peak multiplets in H-1, C-13 HETCOR spectra of ViLi (due to coupling with the passive Li-6 spin), it is concluded that the sign of 1J(C-13, Li-6) is positive. In a fully coupled heteronuclear Li-6, H-1 shift correlation experiment (FUCOUP), an intense and a weaker cross peak are observed between Li-6, H(gem) and Li-6, H(trans), respectively, of tetrameric ViLi. This is indicative of scalar Li-6, H-1 coupling. In a Li-6, H-1 FUCOUP spectrum with a small (36-degrees) H-1 mixing pulse ('beta-FUCOUP'), the tilt of the Li-6, H(trans) cross peak indicates the sign and magnitude of 2J(Li-6, H(gem)) to be +0.4Hz. Analogous to the tetramer, Li-6, H-1 beta-FUCOUP of the dimer reveals 3J(Li-6, H(trans)) to be +0.4 Hz. The C-13, C-13 coupling constant in vinyllithium is extraordinarily small (dimer, 35.0 Hz; tetramer, 36.3 Hz). Likewise,the one-bond C-13, H-1 coupling constant 1J(C1, H(gem)) is the lowest reported so far for monosubstituted ethylenes (dimer, 91.7 Hz; tetramer, 93.2 Hz). By combination of C-13 gated decoupled and C-13, H-1 beta-FUCOUP data, extreme numbers are also found for geminal 2J(C-13, H-1) coupling constants: dimer, 2J(C1, H(cis)) = +13.5 HZ; 2J(C1, H(trans) = -5.9 Hz; 2J(C2, H(gem)) = -10.5 Hz; tetramer, 2J(C1, H(cis)) = +13.5 HZ; 2J(C1, H(trans)) = -6.1 HZ; 2J(C2,H(gem)) = -12.1 Hz
Going Beyond Counting First Authors in Author Co-citation Analysis
The present study examines one of the fundamental aspects of author co-citation analysis (ACA) - the way co-citation
counts are defined. Co-citation counting provides the data on which all subsequent statistical analyses and mappings
are based, and we compare ACA results based on two different types of co-citation counting - the traditional type that
only counts the first one among a cited work's authors on the one hand and a non-traditional type that takes into
account the first 5 authors of a cited work on the other hand. Results indicate that the picture produced through this non-traditional author co-citation counting contains more coherent author groups and is therefore considerably clearer. However, this picture represents fewer specialties in the research field being studied than that produced through the traditional first-author co-citation counting when the same number of top-ranked authors is selected and analyzed. Reasons for these effects are discussed
Variations on the Author
“Variations on the Author” discusses two of Eduardo Coutinho’s recent films (Um Dia na Vida, from 2010, and Últimas Conversas, posthumously released in 2015) and their contribution to the general question of documentary authorship. The director’s filmography is characterized by a consistent yet self-effacing form of authorial self-inscription: Coutinho often features as an interviewer that rather than express opinions propels discourses; an interviewer that is good at listening. This mode of self-inscription characterizes him as an author who is not expressive but who is nonetheless markedly present on the screen. In Um Dia na Vida, however, Coutinho is completely absent form the image, while Últimas Conversas, on the contrary, includes a confessional prologue that moves the director from the margins to the center of his films. This article examines the ways in which these works stand out in the filmography of a director who offers new insights into the notion of cinematic authorship
Appropriate Similarity Measures for Author Cocitation Analysis
We provide a number of new insights into the methodological discussion about author cocitation analysis. We first argue that the use of the Pearson correlation for measuring the similarity between authors’ cocitation profiles is not very satisfactory. We then discuss what kind of similarity measures may be used as an alternative to the Pearson correlation. We consider three similarity measures in particular. One is the well-known cosine. The other two similarity measures have not been used before in the bibliometric literature. Finally, we show by means of an example that our findings have a high practical relevance.information science;Pearson correlation;cosine;similarity measure;author cocitation analysis
Trivializable sub-Riemannian structures on spheres
We classify the trivializable sub-Riemannian structures on odd-dimensional spheres S-N that are induced by a Clifford module structure of RN+1. The underlying bracket generating distribution is of step two and spanned by a set of global linear vector fields X-1, ... , X-m. As a result we show that such structures only exist in the cases where N = 3, 7, 15. The corresponding hypo-elliptic sub-Laplacians Delta(sub) are defined as the (negative) sum of squares of the vector fields X-j. In the case of a trivializable rank four distribution on S-7 and a trivializable rank eight distribution on S-15 we obtain a part of the spectrum of Delta(sub). We also remark that in both cases there is a relation between the eigenfunctions and Jacobi polynomials. (C) 2012 Elsevier Masson SAS. All rights reserved
Dispelling the Myths Behind First-author Citation Counts
We conducted a full-scale evaluative citation analysis study of scholars in the XML research field to explore just how different from each other author rankings resulting from different citation counting methods actually are, and to demonstrate the capability of emerging data and tools on the Web in supporting more realistic citation counting methods. Our results contest some common arguments for the continued
use of first-author citation counts in the evaluation of scholars, such as high correlations between author rankings by first-author citation counts and other citation
counting methods, and high costs of using more realistic citation counting methods that are not well-supported by the ISI databases. It is argued that increasingly available digital full text research papers make it possible for citation analysis studies to go beyond what the ISI databases have directly supported and to employ more
sophisticated methods
koamabayili/VECTRON-author-checklist: VECTRON author checklist
We have done our best to complete the author checklist relating to the use of animals in the hut study. Note that the objective for the hut study was to evaluate the IRS treatment applications for residual efficacy against Anopheles mosquitoes, including the local An. coluzzii mosquito population. Cows were only used to attract mosquitoes into the huts and no tests were carried out directly on the cows. The author checklist is intended for use with studies where experiments are carried out on animals, which is why we have had such difficulty in completing this for the hut study, as many of the questions do not relate to how the cows were used
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