1,723,791 research outputs found

    Formation of Ice Ih Clusters in Solid-Phase Glacial Water with Low Concentrations of Ca2⁺ and Mg2⁺ Ions

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    This study explores the structural and chemical interactions between glacial water, ice Ih, and hydration clusters of divalent cations (Ca2⁺ and Mg2⁺). Ice Ih, with its hexagonal lattice and tetrahedral bonding network, is incompatible with the hydration shells of Ca2⁺ and Mg2⁺, which adopt octahedral geometries in aqueous solutions. During freezing, these hydration clusters become disordered, causing distortions in the ice structure. Slow freezing reduces these distortions, while rapid freezing traps ions in amorphous regions, preventing proper alignment of hydration clusters. Through advanced techniques such as chemical and isotopic analysis, computational modeling, and electrical impedance spectroscopy, this study examines ion exclusion mechanisms and water-clustering behaviors. The results show that both ions are largely excluded from the solid phase during freezing, with Mg2⁺ exhibiting stronger exclusion due to its smaller ionic radius and greater hydration energy. This study also highlights the role of sediments in modulating ion patterns in glacial ice. This work deepens our understanding of ion–ice interactions, offering insights for cryochemistry, hydrology, and environmental science. The integration of experimental and computational methods provides new perspectives on divalent cations’ role in modifying ice’s crystalline structure and explains isotopic variability in glacial waters

    Linked collectors and determiners for: Two new species of Sonerila Roxb. (Melastomataceae) from Laos.

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    Natural history specimen data linked to collectors and determiners held within, "Two new species of Sonerila Roxb. (Melastomataceae) from Laos". Claims or attributions were made on Bionomia by volunteer Scribes, <a href="http://bionomia.net/dataset/4e0dadd2-0530-4ab7-8314-3a0b1576ea27">https://bionomia.net/dataset/4e0dadd2-0530-4ab7-8314-3a0b1576ea27</a> using specimen data from the dataset aggregated by the Global Biodiversity Information Facility, <a href="https://gbif.org/dataset/4e0dadd2-0530-4ab7-8314-3a0b1576ea27">https://gbif.org/dataset/4e0dadd2-0530-4ab7-8314-3a0b1576ea27</a>. Formatted as a Frictionless Data package

    凝固性非ニュートン流体の粘弾性および粘塑弾性体の力学的解析

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    研究課題/領域番号:X46070------8314, 研究期間(年度): 1971出典:研究課題「凝固性非ニュートン流体の粘弾性および粘塑弾性体の力学的解析」課題番号 X46070------8314 (KAKEN:科学研究費助成事業データベース(国立情報学研究所)) (https://kaken.nii.ac.jp/ja/grant/KAKENHI-PROJECT-X46070------8314/)を加工して作成金沢大学工学部research repor

    Influence of Zn2⁺ Concentration on Ceramic Coatings for Corrosion Protection of Magnesium-Lithium Alloys

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    This study investigates the enhancement of corrosion resistance in magnesium-lithium alloys through plasma electrolytic oxidation (PEO) coatings incorporating ZnF2 via in situ synthesis. By adjusting Zn2⁺ concentrations (4–16 g/L) in a zirconium salt-based electrolyte, ceramic coatings with tailored ZnF2 content, thickness, and porosity were fabricated. The optimal Zn2⁺ concentration of 12 g/L yielded a ZnF2-rich coating with isolated pores and enhanced densification (inner layer resistance Ri = 3.01 × 104 Ω⋅cm2), achieving a corrosion current density (icorr) of 4.42 × 10−8 A/cm2 and polarization resistance (Rp) of 8.5 × 105 Ω⋅cm2, representing a 354-fold improvement over untreated LA103Z. Higher Zn2⁺ concentrations (16 g/L) induced interconnected pores and ZnO formation, degrading corrosion resistance. Long-term immersion (168 h in 3.5 wt% NaCl) confirmed the durability of Zn12 coatings (mass loss: 0.6 mg), while Zn4 and Zn16 coatings exhibited severe localized corrosion. The study demonstrates that balancing Zn2⁺ concentration optimizes ZnF2 passivation and pore isolation, offering a scalable strategy for Mg-Li alloy protection in corrosive environments

    Medienökologie

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    Ganguin S, Sander U. Medienökologie. In: Mikos L, Wegener C, eds. Qualitative Medienforschung. Ein Handbuch. UTB. Vol 8314. Konstanz: UVK Verlagsgesellschaft mbH; 2005: 134-140

    Going Beyond Counting First Authors in Author Co-citation Analysis

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    The present study examines one of the fundamental aspects of author co-citation analysis (ACA) - the way co-citation counts are defined. Co-citation counting provides the data on which all subsequent statistical analyses and mappings are based, and we compare ACA results based on two different types of co-citation counting - the traditional type that only counts the first one among a cited work's authors on the one hand and a non-traditional type that takes into account the first 5 authors of a cited work on the other hand. Results indicate that the picture produced through this non-traditional author co-citation counting contains more coherent author groups and is therefore considerably clearer. However, this picture represents fewer specialties in the research field being studied than that produced through the traditional first-author co-citation counting when the same number of top-ranked authors is selected and analyzed. Reasons for these effects are discussed

    Variations on the Author

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    “Variations on the Author” discusses two of Eduardo Coutinho’s recent films (Um Dia na Vida, from 2010, and Últimas Conversas, posthumously released in 2015) and their contribution to the general question of documentary authorship. The director’s filmography is characterized by a consistent yet self-effacing form of authorial self-inscription: Coutinho often features as an interviewer that rather than express opinions propels discourses; an interviewer that is good at listening. This mode of self-inscription characterizes him as an author who is not expressive but who is nonetheless markedly present on the screen. In Um Dia na Vida, however, Coutinho is completely absent form the image, while Últimas Conversas, on the contrary, includes a confessional prologue that moves the director from the margins to the center of his films. This article examines the ways in which these works stand out in the filmography of a director who offers new insights into the notion of cinematic authorship

    Appropriate Similarity Measures for Author Cocitation Analysis

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    We provide a number of new insights into the methodological discussion about author cocitation analysis. We first argue that the use of the Pearson correlation for measuring the similarity between authors’ cocitation profiles is not very satisfactory. We then discuss what kind of similarity measures may be used as an alternative to the Pearson correlation. We consider three similarity measures in particular. One is the well-known cosine. The other two similarity measures have not been used before in the bibliometric literature. Finally, we show by means of an example that our findings have a high practical relevance.information science;Pearson correlation;cosine;similarity measure;author cocitation analysis

    Dispelling the Myths Behind First-author Citation Counts

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    We conducted a full-scale evaluative citation analysis study of scholars in the XML research field to explore just how different from each other author rankings resulting from different citation counting methods actually are, and to demonstrate the capability of emerging data and tools on the Web in supporting more realistic citation counting methods. Our results contest some common arguments for the continued use of first-author citation counts in the evaluation of scholars, such as high correlations between author rankings by first-author citation counts and other citation counting methods, and high costs of using more realistic citation counting methods that are not well-supported by the ISI databases. It is argued that increasingly available digital full text research papers make it possible for citation analysis studies to go beyond what the ISI databases have directly supported and to employ more sophisticated methods
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