MAKARA Journal of Technology
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MECHANICAL AND THERMAL PROPERTIES OF POLYPROPYLENE REINFORCED BY CALCINED AND UNCALCINED ZEOLITE
Get PDFThis study was carried out to compare mechanical and thermal properties of polypropylene (PP) reinforced with uncalcined and calcined zeolites. The PP samples were reinforced with zeolites at various quantities of 2, 4, and 6 (wt %). The comparison of the two types of zeolite was based on mechanical properties, including tensile strength, elongation at break, and Young’s modulus, and thermal characteristics analyzed using DSC, and DTA/TGA technique. The results obtained clearly revealed that both zeolites were able to significantly increase tensile strength and Young’s modulus of the samples, with calcined zeolite was found to work better. Addition of calcined zeolite was found to result in increased fracture elongation of the samples reinforced with up to 4 wt% zeolite but decreased sharply for the sample reinforced with 6 wt% zeolite, while for the samples reinforced with uncalcined zeolite, no consistent trend was observed. Thermal analyses demonstrated that the samples reinforced with calcined zeolite are more resistant to thermal treatment than those reinforced with uncalcined zeolite, as indicated by their higher decomposition temperature. DSC analysis revealed that there was no significant difference of the melting points of the samples was observed, but the effect of the quantity of zeolite on enthalphy was quite evident, in which the enthalpies of the samples reinforced with calcined zeolites were relatively lower than those of the samples reinforced with uncalcined zeolites. Keywords: PP, PP-g-MA, zeolite, analysis, mechanical, therma
WORST CASE OF RELATIVE DISTURBANCE GAIN ARRAY FOR UNCERTAIN DISTILLATION SYSTEM
Get PDFThis article discusses the constrained nonlinear optimization formulation for calculating the worst case of lower and upper bounds of relative disturbance gain array (RDGA) for uncertain process models. The proposed approach seeks the minimum and maximum values of the relative disturbance gains subject to the constraints in which the process and disturbance gains are within their uncertainty ranges. RDGA ranges are useful for control structure determination and the related robustness, as they provide information regarding the sensitivity to gain uncertainties. The proposed method is demonstrated by ternary distillation column case study. Closed loop simulation results support the analysis based on the proposed method. It is shown that for a particular degree of uncertainties, the range of process gain determinant should not include zero to ensure the successfulness of the calculation. For the distillation system being studied, the maximum allowable α is 0.339 to avoid the singularity of matrix K.Keywords: distillation control, relative disturbance gain array, relative gain arra
Agricultural Drought Pattern in West Java Using Thermal Vegetation Index from Modis-Terra Satellite
Get PDFThis study examines agricultural drought paddy fields in West Java. The aims of this research are to know the pattern and distribution of paddy field drought in West Java and the correlation between drought and the physical characteristics. The agricultural drought is obtained from TVI (Thermal Vegetation Index) model. TVI is derived from MODIS Terra satellite image, which is the ratio between the LST (Land Surface Temperature) and EVI (Enhanced Vegetation Index). Physical factors studied are rainfall, l slope, geomorphology, soil drainage, and irrigation areas. The most severe drought occurred in September 2006 because of El Nino, covering 806,564 ha, and distributed in almost all West Java Province while the lowest occurred in September 2010 because of La Nina, covering 101,959 ha, and mostly distributed in Subang and Indramayu district. Spatial distribution of drought in 2000-2011 has the same pattern. At the start of the dry season (May) drought occurred in the north (along the coast) then expanded to the east / south in the middle of the dry season (July-August) and then increased further to the west at the end of the dry season (September). Incidence of drought has correlation with the physical condition of the area, but the most influential is the rainfall based on Chi-square test.Keywords: agricultural drought, EVI, LST, MODIS, TV
Observation of Photovoltaic Effect and Single-photon Detection in Nanowire Silicon pn-junction
Get PDFWe study nanowire silicon pin and pn-junctions at room and low temperature. Photovoltaic effects are observed for both devices at room temperature. At low temperature, nanowire pn-junction devices show their ability to detect single photon. This ability was not been observed for pin devices. Phosphorus-boron dopant cluster in the depletion region is considered to have the main role for single-photon detection capability. Fundamental mechanism of dopant-based single-photon detection in nanowire pn-junction is described in details.Keywords: dopant cluster, nanowire pn-junction, single dopant, single photo
BIODIESEL PRODUCTION FROM WASTE COOKING OIL USING HYDRODINAMIC CAVITATION
Get PDFThe aim of this research was to study biodiesel production from low cost feedstock of waste cooking oil (WCO) using hydrodynamic cavitation apparatus. A two-step processes esterification process and transesterification process using hydrodynamic cavitation for the production of biodiesel from WCO is presented. The first step is acid-catalyzed esteri-fication process for reducing free fatty acid (FFA) content of WCO and followed by base-catalyzed transesterification process for converting WCO to biodiesel as the second step. The result of esterification process with methanol to oil molar ratio of 5 and temperature of 60 oC showed that the initial acid value of WCO of 3.9 mg KOH/g can be decreased to 1.81 mg KOH/g in 120 minutes. The highest yield of biodiesel in transesterification process of 89.4% obtained at reaction time of 150 minutes with methanol to oil molar ratio of 6. The biodiesel produced in the experiment was analyzed by gas chromatography-mass spectrometry (GC-MS), which showed that it mainly contained five fatty acid methyl esters. In addition, the properties of biodiesel showed that all of the fuel properties met the Indonesian National Standard (INS) No. 04-7182-2006 for biodiesel. Keywords: biodiesel, hydrodynamic cavitation, transesterification, wasted cooking oi
THE EFFECT OF SIZE AND CRUMB RUBBER COMPOSITION AS A FILLER WITH COMPATIBILIZER PP-g-MA IN POLYPROPYLENE BLENDS AND SIR-20 COMPOUND ON MECHANICAL AND THERMAL PROPERTIES
Get PDFHaving been researched the development of thermoplastic elastomer material of polypropylene and natural rubber SIR-20 compound with Crumb Rubber as the filler. Reinforced polypropylene with size 60 mesh with 1 mm, and the composition of the Crumb rubber (30, 40, and 50) wt%. Observed mechanical properties are tensile strength, fracture elongation, Young's modulus, tear strength and impact strength. Thermal properties are analyzed by DSC and DTA/TGA. It is acquired that for the size of 60 mesh crumb rubber tensile strength, fracture elongation, Young’s modulus, tear strength and impact strength are bigger than 1mm size. The addition of 60 mesh crumb rubber increases but it decreases by adding of 50 weight%. While for crumb rubber 1 mm tensile strength, fracture elongation, tear strength and impact strength decreas. Based on analysis of DSC that the addition of crumb rubber does not make a difference boiling point significantly between samples containing crumb rubber and polypropylene Analysis TGA/DTA to an increase in enthalpy and decomposition temperature with the addition of crumb rubber used and thermal stability.Keywords: compound SIR-20, crumb rubber, mechanical, polypropylene, PP-g-MA, thermal propertie
Biodiesel Reactor Design with Glycerol Separation to Increase Biodiesel Production Yield
Get PDFThe study consisted of reactor design used for transesterification process, effect of glycerol separation ontransesterification reaction, determination of biodiesel quality, and mass balance analysis. The reactor was designed byintegrating circulated pump/stirrer, static mixer, and sprayer that intensify the reaction in the outer tank reactor. The objective was to reduce the use of methanol in excess and to shorten the processing time. The results showed that thereactor that applied the glycerol separation was able to compensate for the decreased use of the reactant methanol from 6:1 to 5:1 molar ratio, and changed the mass balance in the product, including: (i) the increase of biodiesel productionfrom 42.37% to 49.34%, and (ii) the reduction of methanol in excess from 42.37% to 32.89%. The results suggested that the efficiency of biodiesel production could be increased with the glycerol separation engineering.Keywords: biodiesel, design, glycerol phase separation, reacto
Biological Pretreatment of Oil Palm Frond Fiber Using White-Rot Fungi for Enzymatic Saccharification
Get PDFOil palm frond is one type of lignocellulosic biomass abundantly and daily available in Indonesia. It contains cellulose which can be converted to glucose, and further processed to produce different kinds of value –added products. The aim of this research is to study the effects of biological pretreatment of oil palm frond (OPF) fiber using Phanerochaete chrysosporium and Trametes versicolor on the enzymatic saccharification of the biomass. The OPF fiber (40-60 mesh sizes) was inoculated with cultures of the two fungi and incubated at 27 °C for 4 weeks. The samples were taken after 1, 2, 3, and 4 weeks of incubation. Chemical components of the biomass after pretreatment were analyzed. The saccharification of the pretreated samples using cellulase and β-glucosidase was performed in a water bath shaker at 50 °C for 48 hours. The concentration of reducing sugar increased with increasing of incubation time, either in those pretreated with culture of P. chrysosporium or with T. versicolor. Pretreatment of OPF fiber using single culture of T. versicolor for 4 weeks gave the highest reducing sugar yield (12.61% of dry biomass).Keywords: enzymatic saccharification, oil palm frond, reducing sugar, white-rot fung
Influences of Surface Morphology of Nanostructured Rutile TiO2 Nanorods/Nanoflowers as Photoelectrode on the Performance of Dye-sensitized Solar Cell
Get PDFAligned Rutile TiO2 nanorods (r-TNRs) and TiO2 nanoflowers (r-TNFs) were successfully prepared by hydrothermal method. Using hydrochloric acid (HCl) as chelating agent and titanium butoxide (TBOT) as precursor, aligned r-TNRs with r-TNFs were successfully growth onto fluorine-doped tin oxide (FTO) with different morphologies. The influences of surface morphologies to the rutile based Dye-sensitized solar cell (DSC) efficiency are discussed. The highest light-to-electric energy conversion efficiency, 1.80% is achieved using different concentration under simulated solar light illumination of 100 mWcm-2 (1.5 AM).Keywords: dye sensitized solar cell, hydrothermal, nanoflower, nanorod, TiO
IMPROVEMENT OF HIGH TEMPERATURE OXIDATION OF LOW CARBON STEEL EXPOSED TO ETHANOL COMBUSTION PRODUCT AT 700 °C BY HOT-DIP ALUMINIZING COATING
Get PDFLow carbon steel (AISI 1005) was coated by hot-dipping into a molten Al-10% Si bath at 700 °C for 18s. After hotdipping treatment, the coating layers consisted of Al, Si, FeAl3, τ5-Fe2Al8Si, and Fe2Al5. The bare steel and thealuminized steel were isothermally oxidized at 700 °C in ethanol combustion product at atmospheric pressure for 49 h. The aluminized steel shows good performance in high temperature oxidation because the formation of Al2O3 layer on the coating surface. The growth of iron oxide nodules on the surface coating was accelerated by rapid outward diffusion of Fe-ions due to the presence of H2O-vapour generated by ethanol combustion. Thus, the oxidation rate of aluminized steel increased, resulting in a substantial mass-gain as the oxidation time increased. After longer exposure, the τ1-(Al,Si)5Fe3 phase was completely transformed to the FeAl in the outer layer. The FeAl formed near the steel substrate was due to Fe-atoms diffusing into the Fe2Al5 layer when the time and temperature increased.Keywords: aluminized steel, ethanol combustion product, low carbon stee