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    Socio-Ecological impacts of Water Hyacinth, Eichhornia crassipes (MART.) in Lake Tana, Gulf of Gorgora, Ethiopia

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    Water hyacinth is one of the aggressive alien aquatic macrophyte threatening biodiversity, economic development and human wellbeing. Currently, the macrophyte has invaded Lake Tana and its catchment causing several socio-ecological impacts. So far, there is limited information on socio-ecological impact of water hyacinth in Lake Tana specifically gulf of Gorgora. Therefore, the main aim of this study was to assess socio-ecological impact of water hyacinth in Lake Tana gulf of Gorgora, located in North West of Ethiopia from November 2019 to January 2020. Two sampling sites (infested and non-infested) were identified based on infestation of water hyacinth. A total of 30 water and 12 water hyacinth samples were collected with a survey of 50 individuals. Results revealed that water quality, phytoplankton diversity, fishing, navigation, health condition of local people, recreational and aesthetic value were impacted negatively due to infestation. Conversely, higher accumulation of toxic heavy metals and dissolved metallic ions in the root, stem and leaf of the macrophyte impacted positively. Infestation of the macrophyte significantly affected water quality and species diversity of Lake Tana. In the infested site; DO (3.3 to 4.5), SRP (0.012 to 0.023 mg L-1), TP (0.24 to 0.28 mg L-1), NO3-N (0.74 to 0.97 mg L-1) and TN (2.1 to 3.2 mg L-1) were significantly (p < 0.01) lower than non-infested site. Generally, infestation of water hyacinth negatively impacted the society and the ecology in Lake Tana catchment. Therefore, continuous monitoring and management of the macrophyte is required

    Substrate-Induced pH Changes and Process Stability of Anaerobic Digestion of Shea Waste

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    Shea butter extraction involves the generation of waste of environmental concern. To help find a solution to the management of this waste, and to search for an alternative source of energy, this study was carried out to investigate the potential of shea waste in generating methane gas through anaerobic digestion. At high concentrations, volatile fatty acids produce a low pH, which may inhibit hydrolysis, thereby affecting the stability of the anaerobic digestion process. The influence of pH changes on process stability (or otherwise) was also investigated. The study involved two fermentation processes: mono-fermentation and co-fermentation involving a mix of shea waste and cattle dung. The mono-fermentation investigations comprised six treatments - three organic dry matter concentrations of 7%, 5% and 3%, combined with two hydraulic retention times of 30 and 60 days. The co-fermentation investigations comprised three treatments of shea waste and cattle manure mix in proportions (by volume) of 50:50, 75:25 and 90:10. The results showed that changes in pH were a good parameter for indicating process instability. The results also showed that monofermentation of shea waste was not a viable option in anaerobic digestion for biogas production, whilst only the substrate with 50% cattle manure in the co-fermentation trials showed process stability, producing biogas with adequate methane content

    Missing Observations in Split-Plot Central Composite Designs: The Loss in Relative A-, G-, and V- Efficiency

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    The trace (A), maximum average prediction variance (G), and integrated average prediction variance (V) criteria are experimental design evaluation criteria, which are based on precision of estimates of parameters and responses. Central Composite Designs (CCD) conducted within a split-plot structure (split-plot CCDs) consists of factorial (\u1d453), whole-plot axial (\u1d6fc), subplot axial (\u1d6fd), and center (\u1d450) points, each of which play different role in model estimation. This work studies relative A-, G- and V-efficiency losses due to missing pairs of observations in split-plot CCDs under different ratios (d) of whole-plot and sub-plot error variances. Three candidate designs of different sizes were considered and for each of the criteria, relative efficiency functions were formulated and used to investigate the efficiency of each of the designs when some observations were missing relative to the full one. Maximum A-efficiency losses of 19.1, 10.6, and 15.7% were observed at \u1d451 = 0.5, due to missing pairs \u1d453\u1d453, \u1d6fd\u1d6fd, and \u1d453\u1d6fd, respectively, indicating a negative effect on the precision of estimates of model parameters of these designs. However, missing observations of the pairs-\u1d450\u1d450, \u1d6fc\u1d6fc, \u1d6fc\u1d450, \u1d453\u1d450, and \u1d453\u1d6fc did not exhibit any negative effect on these designs' relative A-efficiency. Maximum G- and V-efficiency losses of 10.1,16.1,0.1% and 0.1, 1.1, 0.2%, were observed, respectively, at \u1d451 = 0.5, when the pairs-\u1d453\u1d453, \u1d6fd\u1d6fd, \u1d450\u1d450, were missing, indicating a significant increase in the designs' maximum and average variances of prediction. In all, the efficiency losses become insignificant as d increases. Thus, the study has identified the positive impact of correlated observations on efficiency of experimental designs

    Sediment Quality of Orashi River at Four Oil Producing Communities of Nigeria

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    Bed Sediment samples were collected in the Dry Season from Orashi River at three sampling sites each located in Mmahu, Opuoma, Abacheke and Ogwu Aniocha communities. Physicochemical parameters, hydrocarbon and heavy metal (As, Cd, Fe and Pb) concentrations were determined with standard methods. Results showed that total petroleum hydrocarbon (TPH) ranged from 0.11 \ub10.03 to 1.91 \ub10.25 mg/kg while total hydrocarbon content (THC) and oil and grease had ranges of 0.28 \ub10.06-2.98 \ub10.19 and 0.69 \ub10.09-3.60 \ub10.57 mg/kg respectively. The sediment samples were classified as unpolluted in terms of TPH. Mean values for pH had a range of 4.33 \ub10.22 - 6.60 \ub10.52 while the texture of most samples was sandy. Mean organic carbon contents ranged from 0.58\ub10.07 to 3.15\ub10.66 % and mean total nitrogen and total phosphorus had ranges of 0.30\ub10.00 -2.77\ub10.46 and 17.34\ub11.65 - 29.48\ub11.63 mg/kg respectively. Mean Mg concentrations were significantly higher (P<0.05) than the concentrations of other exchangeable bases and mean As concentration had a range of 1.175\ub10.086-1.291\ub10.335 mg/kg. Mean Cd concentrations ranged from 0.948\ub10.072 to 3.120\ub10.131 mg/kg while mean Fe and Pb concentrations had ranges of 57.324\ub110.530-159.707\ub141.192 and 1.300\ub10.295-7.462\ub10.861 mg/kg respectively. As and Pb values were lower than the sediment quality guidelines (SQG) but Cd values were higher than the guidelines in all sites. Contamination factors (CFs) for As and Pb indicated low contamination while CFs for Cd indicated moderate to considerable contamination. Geo-accumulation index (Igeo) values for As and Pb at all sites and that of Cd at one site indicated unpolluted, Igeo values for Cd at all other sites ranged between 0.210 and 1.571 indicating unpolluted to moderately polluted status

    Synthesis and Characterization of Silver Nanoparticles from Ashyranthus aspera Extract for Antimicrobial Activity Studies

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    Development of biologically inspired experimental processes for the synthesis of nanoparticles is evolving into an important branch of nanotechnology. Plant-mediated synthesis of nanomaterials has been increasingly gaining popularity due to its eco-friendly nature and cost-effectiveness. In the present study, we were synthesized silver (Ag) nanoparticles using aqueous extracts of fresh leaves of Ashyranthus aspera medicinal plants as bio-reducing agents. UV-Vis spectrometer used to monitor the reduction of Ag ions and the formation of AgNPs in the medium. UV-Vis spectra and visual observation showed that the color of the fresh leaf extracts of Ashyranthus aspera turned into grayish-brown respectively, after treatment with Ag precursors. XRD and SEM have been used to investigate the morphology of prepared AgNPs. The peaks in the XRD pattern are associated with that of the Face-Centered-Cubic (FCC) form of metallic silver. TGA/DTA results associated with weight loss and exothermic reaction due to the desorption of chemisorbed water. FTIR was performed to identify the functional groups which form a layer covering AgNPs and stabilize the AgNPs in the medium. Moreover, silver nanoparticles using aqueous leaf extracts of Ashyranthus aspera were separately tested for their antibacterial activity against Gram-positive bacteria ( Staphylococcus aureus ) and Gram-negative bacteria ( Enterobacter ). The results showed that the bacterial growth was inhibited by the extracts containing AgNPs Nanoparticles. The biosynthesized nanoparticle was prepared from Ashyranthus aspera leaf extracts exhibits potential applications as broad-spectrum antimicrobial agents

    Comprehensive Assessment of Sanitary Landfills in Edo State of Nigeria for Waste Management and Pollution Control

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    The aim of this study is to comprehensively assess the need for Sanitary landfills in Edo state for management of waste, control of pollution for sustainable manufacturing system using concurrent triangulation design. The concurrent triangulation design is in two phases, Phase 1 using quantitative analysis, descriptive statistics while phase 2 used the qualitative analysis using thematic selection. Final results collected from the merger of results from phase 1 and phase 2 showed the Regression analysis results had a T-test value of -0.4615 at P value significant of 0.000 obtained for Sanitary landfill in the model and was less than 5% level of significance indicating that there is a significant relationship between Sanitary landfilling and pollution control. The Durbin Watson result of 1.955 showed that the model is reliable with absence of serial auto correlation. A coefficient of - 0.346 showed that 1% increase in sanitary landfilling activities results in 34.6% decrease in environmental pollution. Hence Sanitary landfilling for waste management has proved to sustain manufacturing system, control environmental pollution and reduce waste

    Synthesis and Olfactory Characteristics of Hydroxyether Derivatives of Methyl Eugenol

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    Methyl eugenol is a naturally occurring substance found in the essential oils of several plant species. It is a cheap and abundant material with a rather limited interest as perfuming ingredient. This research investigated the structure-odour relationship of methyl eugenol and its derivatives, focusing on the chemical transformation of the double bond to hydroxyether derivatives in a controlled manner. Two derivatives 2-(4-ethyl-3-methoxybenzyl)oxirane (68.8% yield) and 1-(3,4-dimethoxyphenyl)-3-ethoxypropan-2-ol (63.58% yield), were synthesized from methyl eugenol. This research found that the odour characteristic of 2-(4-ethyl-3-methoxybenzyl)oxirane[floral, fresh, slight lime and sweet]compounds, is clearly different from the odours of the 1-(3,4-dimethoxyphenyl)-3-ethoxypropan-2-ol [Glue-like, pungent, and Caramel-like]. It is evident from our observations that double bond substitution and functional alteration of the methyl eugenol modifies the perceived odour of methyl eugenol derivative. Thus, structural modification overall led to an increase in odour potency

    Effect of Fermentation, Germination and Combined Germination-Fermentation Processing Methods on the Nutrient and Anti-nutrient Contents of Quality Protein Maize (QPM) Seeds

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    Cereals remain the major components of traditional complementary foods but possess antinutritional factors in addition to nutrients. High antinutrient content have been linked to poor quality complementary foods and high level of undernutrition among children less than two years. Hence, this study examined the effect of fermentation, germination and combined germination-fermentation processing methods on the nutrient and antinutrient contents of Quality Protein Maize (QPM). Maize seeds were fermented and germinated for 72 hours. A batch of the germinated seeds was further fermented for 24 and 48 hours separately. The raw and processed maize seeds were chemically analysed for proximate, mineral (calcium, iron and zinc) and antinutrient (phytate, tannin, oxalate, saponin, polyphenol and hemaglutinnin) composition. ANOVA was used to detect significant differences. Result showed that the crude protein content of raw QPM seeds increased significantly from 10.04% to 10.44% after fermentation while it decreased to 9.12% following germination (72 hours)-fermentation (48 hours). Crude fat content decreased significantly with the treatments (4.70-3.20%). Calcium (10.38-4.23mg/100g) and iron (3.70-1.90mg/100g) contents decreased significantly with all the methods. Germination and combined germination-fermentation reduced more antinutrients in maize compared to fermentation. Fermented seeds had the least tannin (28-27.5 mg/100g) and phytate (967.5-828.5 mg/100g) reduction while the oxalate (590-646 mg/100g), saponin (425-545 mg/100g) and hemaglutinnin (17.31-19.53 mg/100g) contents increased. Germination-fermentation (24 hours) decreased phytate content by > 90% and retained more iron (79 vs 61%) and zinc (80 vs 74%) than fermentation. Combined germination-fermentation (24 hours) was more effective in antinutrient reduction in Quality Protein Maize seeds

    Determination of Optimal Number of Servers at Network Queuing Nodes to Reduce Waiting Time in a Tertiary Institution Clinic in Bida, Nigeria

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    In this paper, a network queuing model that determines optimal numbers of servers at the nodes of the school clinic network queuing system to reduce waiting time of the patients has been presented. The relevant data was collected for a period four weeks, through direct observations and interviews. The number of arrivals and departures were also obtained. The total expected waiting time of the patient in the current system before modification was 50minutes with total number of 10 servers in all the nodes, while the total new expected waiting time of patient in the system after modification was reduced to 19 minutes with total number of 17 servers in all the nodes. The study has determined optimal number of servers at the nodes of the school clinic network system. Results from this study is an important information to the management of the school clinic for proper planning and better service delivery

    Screening of Fungi Isolates from Kaduna Refinery Effluent and Romi River and Their Potential for Bioremediation

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    The operation of Kaduna Refinery and Petrochemical Company (KRPC) has increased effluent generation with consequent effects on water quality and habitat since it is discharged into nearby receiving water body. These effluents contain heavy metals and other toxicants. Samples were collected from the effluent discharge point of the Kaduna Refinery and Petrochemical Company (KRPC) and from Romi River located at Kaduna South Local Government Area of Kaduna state. Standard methods were used to analyze the physicochemical parameters and heavy metals of the effluents. A total of 14 fungi isolates were identified from the samples. These fungi isolates were screened for their bioremediation potential on some toxic components in refinery effluent and were identified using molecular techniques. Four fungi isolates ( Chrysosporium tropicum , Aspergillus flavus , Aspergillus niger and Rhizopus oryzae ) were selected for bioremediation. Carbon (IV) oxide evolution increased progressively during the period of bioremediation. There was a noticeable decline in the phenol, lead, cadmium and nickel in the entire bioremediation medium. There was a positive correlation between phenol and cadmium with a coefficient of 0.969. Consortia of fungi isolated from the refinery effluent and Romi River samples were effective in the bioremediation of refinery effluent. The mixed consortium of four fungi showed the most efficacies in the bioremediation of refinery effluent in terms of phenol, oil and grease, cadmium, lead and cadmium reduction. Kaduna Refinery and Petrochemical Corporation (KRPC) should adopt bioremediation as one of the techniques in treating effluents before being discharged into receiving water bodie

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