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Structural complexity at and around the Triassic-Jurassic GSSP at Kuhjoch, Northern Calcareous Alps, Austria
No full textOne of the key requirements for a Global Stratotype Section and Point (GSSP) is the absence of tectonic disturbance. The GSSP for the Triassic–Jurassic system boundary was recently defined at Kuhjoch, Northern Calcareous Alps, Austria. New field observations in the area of the Triassic–Jurassic boundary GSSP site demonstrate that the overturned, tight, and almost upright Karwendel syncline was formed at semibrittle deformation conditions, confirmed by axial planar foliation. Tight to isoclinal folds at various scales were related to a tectonic transport to the north. Brittle faulting occurred before and after folding as confirmed by tilt tests (the rotation of structural data by the average bedding). Foliation is ubiquitous in the incompetent units, including the Kendlbach Formation at the GSSP. A reverse fault (inferred to be formed as a normal fault before folding) crosscuts the GSSP sections, results in the partial tectonic omission of the Schattwald Beds, and thus makes it impossible to measure a complete and continuous stratigraphic section across the whole Kendlbach Formation. Based on these observations, the Kuhjoch sections do not fulfil the specific requirement for a GSSP regarding the absence of tectonic disturbances near boundary level
The iron isotopic composition of subglacial streams draining the Greenland ice sheet
No full textIn this study, we present the first measurements of iron (Fe) stable isotopic composition (δ56Fe) of subglacial streams draining the Greenland Ice Sheet (GIS). We measure the δ56Fe values [(δ56Fe, ‰ = (56Fe/54Fe)sample/(56Fe/54Fe)standard − 1) × 103] of both dissolved and suspended sediment Fe in subglacial outflows from five distinct land-terminating glaciers. Suspended sediments have δ56Fe values that lie within the crustal array (δ56Fe ∼ 0‰). In contrast, the δ56Fe values of dissolved Fe in subglacial outflows are consistently less than 0‰, reaching a minimum of −2.1‰ in the outflow from the Russell Glacier. The δ56Fe values of dissolved Fe vary geographically and on daily time scales. Major element chemistry and mineral saturation state modeling suggest that incongruent silicate weathering and sulfide oxidation are the likely drivers of subglacial stream Fe chemistry, and that the extent of chemical weathering influences the δ56Fe of dissolved Fe. The largest difference in δ56Fe between dissolved and suspended load is −2.1‰, and occurs in the subglacial system from the Russell glacier (southwest GIS). Major element chemistry indicates this outflow to be the least chemically weathered, while more mature subglacial systems (i.e., that exhibit greater extents of subglacial weathering) have dissolved loads with δ56Fe that are indistinguishable from suspended sediments (Δ56Fesuspended-dissolved ∼ 0‰). Ultimately, the dissolved Fe generated in some subglacial systems from the GIS is a previously unrecognized source of isotopically light Fe into the hydrosphere. The data illustrate that the dissolved Fe supplied by subglacial weathering can have variable δ56Fe values depending on the degree of chemical weathering. Thus, Fe isotopes have potential as a proxy for subglacial chemical weathering intensity or mode. Finally, based on our regional Fe concentration measurements from each glacial outflow, we estimate a flux weighted continental scale dissolved iron export of 2.1 Gg Fe yr−1 to the coastal ocean, which is within the range of previous estimates
In situ Raman characterization of minerals and degradation processes in a variety of cultural and geological heritage sites
No full textWe test the capabilities of in situ Raman spectroscopy for non-destructive analysis of degradation processes in invaluable masterpieces, as well as for the characterization of minerals and prehistoric rock-art in caves. To this end, we have studied the mechanism of decay suffered by the 15th-century limestone sculptures that decorate the retro-choir of Burgos Cathedral (N Spain). In situ Raman probe detected hydrated sulfate and nitrate minerals on the sculptures, which are responsible for the decay of the original limestone. In addition, in situ Raman analyses were performed on unique speleothems in El Soplao Cave (Cantabria, N Spain) and in the Gruta de las Maravillas (Aracena, SW Spain). Unusual cave minerals were detected in El Soplao Cave, such as hydromagnesite (Mg5(CO3)4(OH)2·4H2O), as well as ferromanganese oxides in the black biogenic speleothems recently discovered in this cavern. In the Gruta de las Maravillas, gypsum (CaSO4·2H2O) was identified for the first time, as part of the oldest cave materials, so providing additional evidence of hypogenic mechanisms that occurred in this cave during earlier stages of its formation. Finally, we present preliminary analyses of several cave paintings in the renowned “Polychrome Hall” of Altamira Cave (Cantabria, N. Spain). Hematite (Fe2O3) is the most abundant mineral phase, which provides the characteristic ochre-reddish color to the Altamira bison and deer paintings. Thus, portable Raman spectroscopy is demonstrated to be an analytical technique compatible with preserving our cultural and natural heritage, since the analysis does not require physical contact between the Raman head and the analyzed items
Converted phases from sharp 1000 km depth mid-mantle heterogeneity beneath Western Europe
No full textUntil recently, most of the lower mantle was generally considered to be well-mixed with strong heterogeneity restricted to the lowermost several hundred kilometres above the core–mantle boundary, known as the D″D″ layer. However several recent studies have started to hint at a potential change in Earth's structure at mid-mantle depths beneath the transition zone.
Here we present a continental-wide search of Europe and the North Atlantic for mid-mantle P-to-s wave converted phases. Our data set consists of close to 50,000 high quality receiver functions. These are combined in slowness and depth stacks to identify seismic discontinuities in the range of 800–1400 km depth to determine at which depths and in which tectonic settings these features exist. Receiver functions are computed in different frequency bands to resolve the sharpness of the observed discontinuities. We find most seismic velocity jumps are observed between 975–1050 km depth, localised beneath western Europe and Iceland. The shear wave velocity jumps are roughly 1–2.5% velocity increase with depth occurring over less than 8 km in width. The most robust observations are coincident with areas of active upwelling (under Iceland) and an elongate lateral low velocity anomaly imaged in recent tomographic models which has been interpreted as diverted plume material at depth.
The lack of any suggested phase change in a normal pyrolitic mantle composition at around 1000 km depth indicates the presence of regional chemical heterogeneity within the mid-mantle, potentially caused by diverted plume material. We hypothesise that our observations represent either a phase change within chemically distinct plume material itself, or are caused by small scale chemical heterogeneities entrained within the upwelling plume, either in the form of recycled basaltic material or deep sourced chemically distinct material from LLSVPs.
Our observations, which cannot be directly linked to an area of either active or ancient subduction, along with observations in other hotspot regions, suggest that such mid-mantle seismic features are not unique to subduction zones despite the large number of observations that have previously been made in such settings
An experimental model of episodic gas release through fracture of fluid confined within a pressurized elastic reservoir
No full textWe present new experiments that identify a mechanism for episodic release of gas from a pressurized, deformable reservoir confined by a clay seal, as a result of the transition from bulk deformation to channel growth through the clay. Air is injected into the center of a thin cylindrical cell initially filled with a mixture of bentonite clay and water. For sufficiently dry mixtures, the pressure initially increases with little volume change. On reaching the yield stress of the clay-water mixture, the lid of the cell then deforms elastically and an air-filled void forms in the center of the cell as the clay is driven radially outward. With continued supply of air, the pressure continues to increase until reaching the fracture strength of the clay. A fracture-like channel then forms and migrates to the outer edge of the cell, enabling the air to escape. The pressure then falls, and the clay flows back toward the center of the cell and seals the channel so the cycle can repeat. The phenomena may be relevant at mud volcanoes
Fault mechanics and post-seismic deformation at Bam, SE Iran
No full textThe extent to which aseismic deformation relaxes co-seismic stress changes on a fault zone is fundamental to assessing the future seismic hazard following any earthquake, and in understanding the mechanical behaviour of faults. Here we use models of stress-driven afterslip and viscoelastic relaxation, in conjunction with post-seismic InSAR measurements, to show that there has been minimal release of co-seismic stress changes through post-seismic deformation following the 2003 Mw 6.6 Bam earthquake. Our analysis indicates the faults at Bam remain predominantly locked, suggesting that the co- plus interseismically accumulated elastic strain stored downdip of the 2003 rupture patch may be released in a future Mw 6 earthquake. Our observations and models also provide an opportunity to probe the growth of topography at Bam. We find that, for our modelled afterslip distribution to be consistent with forming the sharp step in the local topography over repeated earthquake cycles, and also to be consistent with the geodetic observations, requires either (1) far-field tectonic loading equivalent to a 2–10 MPa deviatoric stress acting across the fault system, which suggests it supports stresses 60–100 times less than classical views of static fault strength, or (2) that the fault surface has some form of mechanical anisotropy, potentially related to corrugations on the fault plane, that controls the sense of slip
A simple rule to determine which insolation cycles lead to interglacials
No full textThe pacing of glacial–interglacial cycles during the Quaternary period (the past 2.6 million years) is attributed to astronomically driven changes in high-latitude insolation. However, it has not been clear how astronomical forcing translates into the observed sequence of interglacials. Here we show that before one million years ago interglacials occurred when the energy related to summer insolation exceeded a simple threshold, about every 41,000 years. Over the past one million years, fewer of these insolation peaks resulted in deglaciation (that is, more insolation peaks were ‘skipped’), implying that the energy threshold for deglaciation had risen, which led to longer glacials. However, as a glacial lengthens, the energy needed for deglaciation decreases. A statistical model that combines these observations correctly predicts every complete deglaciation of the past million years and shows that the sequence of interglacials that has occurred is one of a small set of possibilities. The model accounts for the dominance of obliquity-paced glacial–interglacial cycles early in the Quaternary and for the change in their frequency about one million years ago. We propose that the appearance of larger ice sheets over the past million years was a consequence of an increase in the deglaciation threshold and in the number of skipped insolation peaks
Remobilization of crustal carbon dominates volcanic arc emissions
Full text linkThe flux of carbon into and out of Earth’s surface environment has implications for Earth’s climate and habitability. We compiled a global dataset for carbon and helium isotopes from volcanic arcs and demonstrated that the carbon isotope composition of mean global volcanic gas is considerably heavier, at -3.8 to -4.6 ‰, than the canonical Mid-Ocean-Ridge Basalt value of -6.0 ‰. The largest volcanic emitters outgas carbon with higher δ13C and are located in mature continental arcs that have accreted carbonate platforms, indicating that reworking of crustal limestone is an important source of volcanic carbon. The fractional burial of organic carbon is lower than traditionally determined from a global carbon isotope mass balance and may have varied over geological time, modulated by supercontinent formation and breakup
Interpreting granulite facies events through rare earth element partitioning arrays
No full textThe use of rare earth element (REE) partition coefficients is an increasingly common tool in metamorphic studies, linking the growth or modification of accessory mineral geochronometers to the bulk silicate mineral assemblage. The most commonly used mineral pair for the study of high-grade metamorphic rocks is zircon and garnet. The link from U–Pb ages provided by zircon to the P–T information recorded by garnet can be interpreted in relation to experimental data. The simplistic approach of taking the average REE abundances for zircon and garnet and comparing them directly to experimentally derived partition coefficients is imperfect, in that it cannot represent the complexity of a natural rock system. This study describes a method that uses all the zircon analyses from a sample, and compares them to different garnet compositions in the same rock. Using the most important REE values, it is possible to define zircon–garnet equilibrium using an array rather than an average. The array plot describes partitioning between zircon and garnet using DYb and DYb/DGd as the defining features of the relationship. This approach provides far more sensitivity to mineral reactions and diffusional processes, enabling a more detailed interpretation of metamorphic history of the sample
Assessing the activity of faults in continental interiors: Palaeoseismic insights from SE Kazakhstan
No full textThe presence of fault scarps is a first-order criterion for identifying active faults. Yet the preservation of these features depends on the recurrence interval between surface rupturing events, combined with the rates of erosional and depositional processes that act on the landscape. Within arid continental interiors single earthquake scarps can be preserved for thousands of years, and yet the interval between surface ruptures on faults in these regions may be much longer, such that the lack of evidence for surface faulting in the morphology may not preclude activity on those faults. In this study we investigate the 50 km-long ‘Toraigyr’ thrust fault in the northern Tien Shan. From palaeoseismological trenching we show that two surface rupturing earthquakes occurred in the last 39.9±2.7 ka39.9±2.7 ka BP, but only the most recent event (3.15–3.6 ka BP) has a clear morphological expression. We conclude that a landscape reset took place in between the two events, likely as a consequence of the climatic change at the end of the last glacial maximum. These findings illustrate that in the Tien Shan evidence for the most recent active faulting can be easily obliterated by climatic processes due to the long earthquake recurrence intervals. Our results illustrate the problems related to the assessment of active tectonic deformation and seismic hazard assessments in continental interior settings