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Methods of Studying Early Theropod Flight
The study of early theropod flight involves avialans as well as other pennaraptorans. It requires
the study of anatomy that is familiar to the modern ornithologist, but also very different and alien.
Early theropod flight therefore necessitates study methods that can incorporate what we know about
sophisticated powered and unpowered flight in living birds while being mindful of the differences
between them and the earliest theropod "yers. In this chapter we will survey key methods and
approaches, covering their best-practice applications along the timeline of early theropod flight
evolution and priorities for future method development
Joint Inversion of High‐Frequency Receiver Functions and Surface‐Wave Dispersion: Case Study in the Parnaíba Basin of Northeast Brazil
We assess the performance of the joint inversion of receiver functions (RF) and surface‐wave dispersion in the characterization of the sedimentary package comprising the Parnaíba basin. This procedure is routinely utilized in passive‐source crustal studies to retrieve S‐wave velocity variations with depth, and has seldom been used with higher‐frequency datasets to investigate fine sedimentary structure. The Parnaíba basin is a Paleozoic cratonic basin composed of five supersequences, accumulating ∼3.5 km of sedimentary rocks interbedded by Late Cretaceous diabase sills. The dataset used for this research was acquired between 2015 and 2017 through deployment of 10 short‐period and one broadband seismic stations distributed along an approximately 100‐kilometer‐long linear array in the center of the basin. The deployment was carried out under the Parnaíba Basin Analysis Project, a multi‐institutional and multidisciplinary effort funded by BP Energy do Brasil. High‐frequency RFs (f<4.8 Hz) were calculated from deconvolution of teleseismic P waveforms (30°<Δ<90°) after rotation into the great‐circle path, whereas high‐frequency dispersion curves (0.25–2 Hz) were obtained through multiple filter analysis of empirical Green’s functions developed from cross‐correlation (ZZ component) and stacking (six months) of time–frequency‐normalized ambient seismic noise recordings. S‐wave velocity–depth profiles down to ∼5 km depth were developed through an iterative, linearized joint inversion approach. Comparison to independent active‐source seismic profiles overlapping with our passive‐source seismic line reveals the inverted velocity models successfully retrieve sedimentary thickness (top of the Cambrian), sedimentary velocity structure, and depth to the Cenozoic sedimentary sequence. In addition, high‐velocity zones at depths ranging from 1.5 to 2.5 km are observed in the inverted velocity–depth profiles, which are interpreted as due to the Late Cretaceous sills interbedding the basin’s sedimentary rocks. The relative low cost of our approach makes it ideal for basic characterization of relatively unknown sedimentary basins
The global melt inclusion C/Ba array: mantle variability, melting process, or degassing?
The Earth’s mantle holds more carbon than its oceans, atmosphere and con- tinents combined, yet the distribution of carbon within the mantle remains uncertain. Our best constraints on the distribution of carbon within the up- per mantle are derived from the carbon-trace element systematics of ultra- depleted glasses and melt inclusions from mid-ocean ridge basalts. How- ever, carbon-trace element systematics are susceptible to modification by crustal processes, including concurrent degassing and mixing, and melt in- clusion decrepitation. In this study we explore how the influence of these processes varies systematically with both the mantle source and melting pro- cess, thereby modulating both global and local carbon-trace element trends.
We supplement the existing melt inclusion data from Iceland with four new datasets, significantly enhancing the spatial and geochemical coverage of melt inclusion datasets from the island. Within the combined Iceland dataset there is significant variation in melt inclusion C/Ba ratio, which is tightly correlated with trace element enrichment. The trends in C/Ba- Ba space displayed by our new data coincide with the same trends in data compiled from global ocean islands and mid-ocean ridges, forming a global array. The overall structure of the global C/Ba-Ba array is not a property of the source, instead it is controlled by CO2 vapour loss pre- and post-melt inclusion entrapment; i.e., the array is a consequence of degassing creating near-constant maximum melt-inclusion carbon contents over many orders of magnitude of Ba concentration.
On Iceland, extremely high C/Ba (>100) and C/Nb (>1000) ratios are found in melt inclusions from the most depleted eruptions. The high C/Ba and C/Nb ratios are unlikely to be either analytical artefacts, or to be the product of extreme fractionation of the most incompatible elements during silicate melting. Whilst high C/Ba and C/Nb ratios could be generated by regassing of melt inclusions by CO2 vapour, or by mantle melting occurring in the presence of residual graphite, we suggest the high values most likely derive from an intrinsically high C/Ba and C/Nb mantle component that makes up a small fraction of the Icelandic mantle
Hysteresis of natural magnetite ensembles: Micromagnetics of silicate-hosted magnetite inclusions based on focused-ion-beam nanotomography
Three‐dimensional geometries of silicate‐hosted magnetic inclusions from the Harcus intrusion, South Australia have been determined using focused‐ion‐beam nanotomography (FIB‐nt). By developing an effective workflow, the geometries were reconstructed for magnetic particles in a plagioclase (162) and a pyroxene (282), respectively. For each inclusion, micromagnetic modelling using MERRILL provided averaged hysteresis loops and backfield remanence curves of 20 equidistributed field directions together with average Ms, Mrs, Hc, and Hcr. The micromagnetic structures within each silicate are single‐domain, single‐vortex, multi‐vortex and multi‐domain states. They have been analyzed using domain‐state diagnostic plots, such as the Day plot and the Néel plot. SD particles can be subdivided into groups with dominant uniaxial anisotropy (Mrs/Ms∼0.5 and 10<Hc<100mT) and mixed uniaxial/multiaxial anisotropy (Mrs/Ms∼0.7 and 10<Hc<30mT). Most single‐vortex particles lie on a trend with 0<Mrs/Ms<0.1and 0<Hc<10mT, while others display a broad range of intermediate Mrs/Ms and Hc values. Single‐vortex and multi‐vortex states do not plot on systematic grain‐size trends. Instead, the multi‐component mixture of domain states within each silicate spans the entire range of natural variability seen in bulk samples. This questions the interpretation of bulk average hysteresis parameters in terms of grain size alone. FIB‐nt combined with large‐scale micromagnetic simulations provides a more complete characterization of silicate‐hosted carriers of stable magnetic remanence. This approach will improve the understanding of single‐crystal paleomagnetism, and enable primary paleomagnetic data to be extracted from ancient rocks
Late Miocene to late Pleistocene geomagnetic secular variation at high northern latitudes
We report a palaeomagnetic study of Icelandic lavas of late Miocene to late Pliocene age to test the geocentric axial dipole hypothesis at high northern latitudes. Cores were sampled from 125 sites in the Fljótsdalur valley in eastern Iceland, and hand samples were taken for 17 new incremental heating 40Ar/39Ar age determinations. 96 per cent of the cores were oriented using both a Brunton compass and a sun compass. Comparison of the magnetic and sun azimuths reveals deviations of ±5°, ±10° and ±20°, respectively, for 42, 16 and 3 per cent of the data points, indicating that core sampling intended for palaeosecular variation (PSV) studies at high northern latitudes should be oriented by sun. A total of 1279 independent specimens were subjected to AF- and thermal-demagnetization for palaeodirectional analysis, and well-grouped site mean directions were obtained for 123 sites of which 113 were found to be independent sites. Applying a selection criteria of k > 50 and N ≥ 5 (Nmean = 9.5), we obtain a combined grand mean direction for 46 normal and 53 reverse (for VGPlat > ±45°) polarity sites of declination = 5.6° and inclination = 77.5° that is not significantly different from that expected from a GAD field. The corresponding palaeomagnetic pole position (VGPlat = 86.3°N, VGPlon = 21.2°E, dp/dm = 4.0°/4.3°) is coincident with the North Pole within the 95 per cent confidence limits. An updated age model is constructed based on the 40Ar/39Ar ages, showing that the majority of the Fljótsdalur lavas fall within 2–7 Ma. We combine the Fljótsdalur data with existing data from the nearby Jökuldalur valley. The 154 palaeodirections are well-dispersed between 1 and 7 Ma and constitute a high-quality data set for PSV analysis. Our results partly support previous conclusions of a generally higher dispersion during reverse polarity intervals. However, when comparing our Matutayma data with Brunhes age data from Jan Mayen, we find no evidence of a higher VGP scatter during the Matuyama as previously suggested. When comparing our VGP scatter to the two commonly used models for VGP dispersion: Model G and TK03, we find a good fit for all 1–7 Ma VGP scatter data SB(1–7) to Model G, whereas SB(1–7) is not fitted by TK03, even when considering the uncertainty of SB(1–7). We also find that all VGP scatter estimates, except that for the Gilbert subset, are consistent with Model G, while the discrepancy with TK03 is generally larger
A Chronostratigraphic Framework for the Rise of the Ediacaran Macrobiota: New Constraints from Mistaken Point Ecological Reserve, Newfoundland
The Conception and St. John’s Groups of southeastern Newfoundland contain some of the oldest known fossils of the Ediacaran macrobiota. The Mistaken Point Ecological Reserve UNESCO World Heritage Site is an internationally recognized locality for such fossils and hosts early evidence for both total group metazoan body fossils and metazoan-style locomotion. The Mistaken Point Ecological Reserve sedimentary succession includes ∼1500 m of fossil-bearing strata containing numerous dateable volcanogenic horizons, and therefore offers a crucial window into the rise and diversification of early animals. Here we present six stratigraphically coherent radioisotopic ages derived from zircons from volcanic tuffites of the Conception and St. John’s Groups at Mistaken Point Ecological Reserve. The oldest architecturally complex macrofossils, from the upper Drook Formation, have an age of 574.17 ± 0.66 Ma (including tracer calibration and decay constant uncertainties). The youngest rangeomorph fossils from Mistaken Point Ecological Reserve, in the Fermeuse Formation, have a maximum age of 564.13 ± 0.65 Ma. Fossils of the famous “E” Surface are confirmed to be 565.00 ± 0.64 Ma, while exceptionally preserved specimens on the “Brasier” Surface in the Briscal Formation are dated at 567.63 ± 0.66 Ma. We use our new ages to construct an age-depth model for the sedimentary succession, constrain sedimentary accumulation rates, and convert stratigraphic fossil ranges into the time domain to facilitate integration with time-calibrated data from other successions. Combining this age model with compiled stratigraphic ranges for all named macrofossils within the Mistaken Point Ecological Reserve succession, spanning 76 discrete fossil-bearing horizons, enables recognition and interrogation of potential evolutionary signals. Peak taxonomic diversity is recognized within the Mistaken Point and Trepassey Formations, and uniterminal rangeomorphs with undisplayed branching architecture appear several million years before multiterminal, displayed forms. Together, our combined stratigraphic, paleontological, and geochronological approach offers a holistic, time-calibrated record of evolution during the mid−late Ediacaran Period and a framework within which to consider other geochemical, environmental, and evolutionary data sets
Morin-type transition in 5C pyrrhotite
We report the discovery of a low temperature spin-flop transition in 5C pyrrhotite at ~155 K that is similar to those seen in hematite at 260 K and FeS (troilite) at 440 K. The 5C crystal was produced by annealing a 4C pyrrhotite crystal at 875 K, to produce a change in the vacancy-ordering scheme that developed during cooling. The 5C structure is confirmed by single crystal x-ray diffraction and the stoichiometry and homogeneity by electron microprobe and SEM BSE mapping. RUS, heat capacity and magnetisation measurements from room temperature down to 2 K are reported. The transition is marked by a steep change in elastic properties at the transition temperature, a peak in the heat capacity and weak anomalies in measurements of magnetisation. Magnetic hysteresis loops and comparison with the magnetic properties of 4C pyrrhotite suggest that the transition involves a change in orientation of moments between two different antiferromagnetic structures, perpendicular to the crystallographic c-axis at high temperatures and parallel to the crystallographic c-axis at low temperatures. The proposed structures are consistent with a group theoretical treatment that also predicts a first order transition between the magnetic structures
Calcium isotopes in deep time: Potential and limitations
Calcium is an essential element in the biogeochemical cycles that regulate the long-term climate state of Earth. The removal of CO2 from the ocean-atmosphere system is controlled by the burial of carbonate sediments (CaCO3), ultimately linking the global calcium and carbon cycles. This fundamental link has driven the development of the stable calcium isotope proxy with application to both ancient skeletal and non-skeletal bulk carbonate sediments. Calcium isotope ratios (δ44/40Ca) have been used to track long-term changes in seawater chemistry (e.g., aragonite vs. calcite seas) and to elucidate short-term climatic perturbations associated with mass extinction events. However, developments in the calcium isotope proxy have shown that δ44/40Ca values in carbonate minerals also are sensitive to changes in precipitation rates, mineralogy and diagenesis, thereby complicating the application of the proxy to the reconstruction of global cycles. First, inorganic carbonate precipitation experiments have demonstrated that carbonate δ44/40Ca values are sensitive to precipitation rates with higher rates generally leading to larger fractionation. Second, δ44/40Ca values are sensitive to carbonate mineralogy with inorganic aragonite and calcite being on average ~ 1.5‰ and ~ 0.9‰ depleted relative to contemporaneous seawater, respectively. The effects of both changes in carbonate mineralogy and precipitation rates affect primary and secondary minerals, but are particularly pronounced during carbonate diagenesis where relatively slow rates of recrystallization and neomorphism can lead to significant changes in bulk sediment δ44/40Ca values. Third, changes in faunal composition expressed in skeletal fossil archives can lead to large changes in carbonate δ44/40Ca values that are decoupled from changes in global cycles. Nevertheless, when these factors are appropriately considered the application of calcium isotopes in ancient carbonate sediments becomes a powerful tool for understanding biogeochemical processes that operate over many scales; from diagenetic changes within the sediment pore-space, to regional changes across ancient carbonate platforms, and to global changes in seawater chemistry through time. Importantly, the processes that contribute to variability in carbonate δ44/40Ca values are likely to impact other carbonate-bound proxies, highlighting the potential for calcium isotopes as a hint to better understand the variability of other isotope systems
Metamorphic evolution of the Great Slave Lake shear zone
The Paleoproterozoic Great Slave Lake shear zone (GSLsz) is a crustal‐scale strike‐slip structure, with a total length >1000 km and a width of ~25 km, that separates the Archean Rae and Slave cratons. The range of metamorphic rocks now exposed at the surface encompasses granulite facies mylonite through to lower‐greenschist facies ultramylonite and cataclasite, providing a potential type example of fault‐zone structure in the middle and lower crust. However, the metamorphic evolution of the units remains poorly quantified, hindering detailed structural and tectonic interpretations. Here, we use phase equilibria modelling and thermobarometry to determine the metamorphic conditions recorded by pelitic, mafic, and felsic GSLsz mylonites. Samples from the entire range of granulite–greenschist facies units preserve evidence for nested clockwise pressure–temperature paths that are consistent with a single orogenic cycle. Our findings indicate that the northern Rae margin underwent pervasive crustal thickening with peak pressures in metasedimentary rocks reaching ~1.1 GPa. The crustal thermal gradient at the onset of thickening was ~650ºC GPa‐1, whereas, the final stages of equilibrium recorded by fine‐grained matrix minerals in all samples collectively define a metamorphic field gradient of ~1000ºC GPa‐1. Deformation microstructures are consistent with the main phase of dextral shear having been synchronous with or following peak metamorphism. The history of metamorphism and exhumation of the GSLsz is consistent with the Sibson‐Scholz model for shear zones, with a narrowing of the deforming zone and the progressive overprinting of higher‐grade assemblages during exhumation through shallower crustal levels
Thermal behaviour of iron arsenides under non-oxidising conditions
Fe2As has been studied in situ by synchrotron powder X-ray diffraction (PXRD) over the range of temperatures 25–850 °C and under a neutral atmosphere to understand its thermal behavior, which is potentially important for gold extraction. For the first time, incongruent high-temperature reactions of Fe2As are observed as it breaks down and the existence of a previously undiscovered high-temperature FeAs phase with an NiAs-type structure has been determined experimentally. No evidence has been found for the existence of the high-temperature Fe3As2 phase. Hence, the previously published phase diagram for the Fe–As system has to be modified accordingly