2090 research outputs found

    Struktura hlorogenske kiseline: spektroskopski i kvantno-mehanički pristup

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    The aim of this work is to examine the performance of the MN12-SX method to reproduce various spectra of chlorogenic acid (5CQA). The most stable conformers of 5CQA in the gaseous and solvated states were determined. In both conformers the carboxylic hydrogen is not oriented towards the carboxylic oxygen, but towards the adjacent hydroxyl group. This occurrence is a consequence of strong, directed hydrogen bonds in the quinic moiety. MN12-SX shows excellent performance in reproducing the vibrational and NMR specra of 5CQA, but fails in simulating the UV spectrum. This shortcoming of the method can be attributed to neglecting the Hartree-Fock exchange while modeling long-range interactions.Cilj ovog rada je da se ispitaju mogućnosti metode MN12-SX da reprodukuje različite vrste spektara hlorogenske kiseline (5CQA). Određeni su najstabilniji konformeri 5CQA u gasovitoj i solvatisanoj fazi. Karakteristično za oba konformera je to da karboksilni vodoniknije okrenut ka karboksilnom kiseoniku, već ka kiseoniku susedne hidroksilne grupe, što je posledica jakih, usmerenih vodoničnih veza u hininskom delu. MN12-SX odlično reprodukuje vibracione i NMR spektre 5CQA, ali podbacuje u simuliranju UV spektra. Ova mana metode može se pripisati zanemarivanju Hartri-Fokove izmene na velikim međuatomskim rastojanjima

    Najznačajniji problemi u obrazovanju, nauci i proizvodnji hrane

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    U ovom radu razmatraju se osnovni problemi u obrazovanju, nauci i proizvodnji hrane. Govori se o odnosu između obrazovanja i nauke, ekspanziji i kvalitetu visokog obrazovanja, globalizaciji i viskom obrazovanju i na kraju Bolonjskom procesu. Zatim, obrađeno je stanje, problemi i perspektiva naučnoistraživačkog rada, izdvjanja sredstava za nauku, razvoju biotehnoloških istraživanja, “odlivu mozgova” i vrednovanju naučnog rada. Na kraju, ukazuje se na probleme obezbeđenja dovoljnih količina hrane, sadašnjem stanju, globalnom statusu i ekološkim posledicama gajenja genetički modifikovanih biljaka

    Izračunavanje i praćenje dinamike organske materije u zemljištu pomoću modela

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    The changes in soil organic carbon stock can occur following land use or land management change or with climatic change. Carbon models were used for the prediction of changes in C stock on agricultural soils. The efficiency of RothC, DNDC and ICBM model was tested against C content of soil samples from experimental field “Plodoredi” within 3-year and 2-years rotation. The measured value of the deposited C for 3-year rotation were better explained by the model RothC and ICBM, while the DNDC model and measured C deposited in 2-year rotation matched better. In the changed climate conditions, variable yields, narrow rotations without legumes and lack of fertilizer application level OM will be difficult to preserve at the current level.Smanjenje sadržaja organske materije (OM) zemljišta uslovljeno je promenom u načinu korišćenja zemljišta kao i agroekološkim uslovima. Za dugoročno praćenje dinamike organske materije koriste se kompjuterski modeli koji nakon validacije mogu da projektuju dinamiku OM na različitim nivoima. U radu su korišćeni podaci sa višegodišnjeg ogleda na Rimskim Šančevima kako bi izvršili evaluaciju 3 modela koji prate dinamiku OM: RothC, DNDC i ICBM i to za agroekološke uslove Vojvodine. Svi modeli su pokazali negativan trend - gubitk OM na ispitivanim parcelama tropolja i dvopolja

    Masa zrna po klasu linija dvoredog ječma (HordeumVulgare l. ) u zavisnosti od đubrenja azotom

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    Kernel weight per spike in two-rowed barley is the main determinant of grain yield. Variability of kernel weight spike-1 was studied in three barley genotypes: G-3033, G-3021 and G-3070, grown over two years under four mineral nitrogen fertilization treatments, 0, 20, 40 and 60 kg N ha-1. The experiment was set up as a randomized block design in three replications. Kernel weight per spike significantly differed across the lines in both years regardless of N application rate. Increased nitrogen rates led to an increase in kernel weight per spike up to 40 kg N ha-1 in the first year, whereas the highest values for kernel weight per spike in the second year were obtained at 60 kg ha-1 N. The proportion of total phenotypic variability for kernel weight per spike was largely attributed to mineral nitrogen fertilization, considerably less to line and negligibly to the line x nitrogen interaction, suggesting that the value of the trait is significantly dependent on the cultural operations used.Masa zrna po klasu kod dvoredog ječma je komponenta prinosa koja u najvećoj meri određuje prinos zrna. U dvogodišnjem periodu analizirana je varijabilnost mase zrna po klasu kod tri linije ozimog dvoredog ječma: G-3033, G-3021 i G-3070, pri četiri nivoa ishrane mineralnim azotom: 0, 20, 40 and 60 kg N ha-1. Masa zrna po klasu se značajno razlikovala kod linija u obe godine nezavisno od nivoa primenjenog N. Povećane doze azota delovale su na povećanje mase zrna po klasu do nivoa 40 kg ha-1 N , dok je u drugoj godini najveća masa zrna po klasu zabeležena na tretmanu 60 kg ha-1 N. U ukupnoj fenotipskoj variajbilnosti za masu zrna po klasu najveći udeo pripadao je mineralnoj ishrani azotom, znatno manji liniji i neznatan interakciji linija x azot, što ukazuje da vrednost ove osobine u najvećoj meri zavisi od primenjene agrotehnike

    Uticaj fosfornih đubriva na prinos i sadržaj kadmijuma u krompiru

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    This study evaluated the effect of different types and rates of phosphorus fertilizers on yield and cadmium content of potato on a slightly alkaline alluvium soil. Results show that the highest yield was obtained under treatment with monoammonium phosphate (manufactured in Russia) and the lowest under Bulgarian TSP treatment. The highest total cadmium was found in potato tubers treated with Bulgarian diammonium phosphate, in contrast to the lowest measured values under Russian DAP treatment.U radu je ispitivan uticaj različitih vrsta i doza fosfornog đubriva na prinos i sadržaj kadmijuma u krompiru, na zemljištu tipa aluvijum, slabo alkalne reakcije. Dobijeni rezultati pokazuju da je primenom monoamonijum-fosfata (poreklom iz Rusije) ostvaren najveći prinos, dok je najmanji prinos postignut sa primenom bugarstkog TSP. Najveći sadržaj ukupnog kadmijuma u krtolama krompira utvrđen je primenom bugarskog diamonijum-fosfata, a najmanji primenom ruskog DAP-a

    Kvalitet mleka i osobine surutke dobijene pri proizvodnji Sjeničkog sira u industrijskim uslovima

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    Sjenica cheese is one of our best kinds of cheese from the group of white cheese in brine. Since the quality and overall value of the cheese depend on the quality and chemical composition of milk, before making cheese it is necessary to determine these parameters. Milk fat content in cow milk was 3.1%, protein 31.3%, dry matter 10.96%, casein 2.85%. Sheep milk of richer chemical composition had a dry matter 8.14%, fat 6.80%, protein 5.97%, casein 20.5%. Chemical composition of whey gauge the validity of keeping the process of making cheese. On the basis of dry matter content (cow whey 5.65% and sheep whey 7.5%), fat (cow whey 0.023%, sheep whey 0.62%), protein (cow whey 0.81% , sheep whey 1.44%), it is seen that the process of producing cheese is well managed with optimal utilization of milk ingredients.Sjenički sir je jedan od naših najboljih sireva iz grupe belih sireva u salamuri. Proizvodi se na individualnim gazdinstvima područja Sjeničko-pešterske visoravni. Sir se proizvodi od svežeg punomasnog kravljeg i očijeg mleka bez termičkog tretmana. Pošto kvalitet i opšte vrednosti sira zavise od kvaliteta i hemijskog sastava mleka , pre izrade sireva neophodno je odrediti te parametre. Sadržaj mlečne masti kod kravljeg mleka bio je 3.1%, proteina 3.31%, suve materije 10.96%, kazeina 2.85%. Ovčije mleko koje je bogatijeg hemijskog sastava imalo je suve materije 18.14%, masti 6.80%, proteina 5.97%, kazeina 5.20%. Na osnovu sadržaja suve materije (5.65% kravlja i 7.05% ovčja ) , masti ( 0.23% kravlja; 0.62% ovčija), proteina ( 0.81% kravlja, 1.44% ovčja), kod surutke vidi se da je proces proizvodnje sireva dobro vođen uz optimalnu iskorišćenost sastojaka mleka

    Proizvodnja mikrobnih belančevina za potrebe ishrane domaćih životinja

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    In the paper it is presented the importance of alternative systems to solve the protein deficit in the diet of farm animals, using a variety of microorganisms as producers of protein grown on waste organic substrates. Indicates to the biotechnological specificity of the microbial conversion of organic substrates into the feed with a high protein content, as well as the selection of the biological producers and row materials, which are used for the production. An important part of this work refers to proteins enrichment of coarse plant material (with increased content of cellulose, lignocellulose, starch, etc.) by direct cultivation of microorganisms on them, in order to improve their quality and digestibility by the domestic animals.U radu je prikazan značaj alternativnih sistema rešavanja proteinskog deficita u ishrani domaćih životinja, korišćenjem različitih mikroorganizama kao producenata proteina gajenih na otpadnim organskim supstratima. Ukazuje se na biotehnološke specifičnosti mikrobiološke konverzije organskih supstrata u stočnu hranu sa visokim sadržajem belančevina kao i na odabir bioloških producenata i sirovina koje se koriste za tu proizvodnju. Bitan deo ovog rada se odnosi na proteinizaciju grubih biljnih materijala (sa povećenim sadržajem celuloze, lignoceluloze, skroba i sl.) direktnim gajenjem mikroorganizama na njima, a u cilju poboljšanja njihovog kvaliteta i svarljivosti od strane domaćih životinja

    Racionalizacija đubrenja u cilju zaštite zemljišta

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    Application of fertilizers could influence the activation of desirable microbiological processes in field. In this experiment we applied methods with and without irrigation followed by addition of microbiologicam fertilizer NS Betafixin and mineral fertilizers in the amount 90, 120 150 and 180 kg N ha-1. Irrigation had positive effect. Fertilization by nitrogen in the interval of 150-180 kg ha-1 and application of NS Betafixin is the most desirable, as it provided the highest yeald of sugars. Application of NS Betafixin could reduce addition of fertilizers, which reduce field contamination with carriors of nutritients originated from fertilizers and increase diversity of microorganisms in the field.Primenom mikrobioloških đubriva može se uticati na aktiviranje poželjnih mikrobioloških procesa u zemljištu. U ogledu su bile zastupljene varijante sa i bez navodnjavanja uz đubrenje mikrobiološkim đubrivom NS Betafixin-om i mineralnim đubrivima u količini 90, 120, 150, 180 kg N ha-1. Navodnjavanje je imalo pozitivan efekat. Đubrenje azotom u intervalu 150-180 kg ha-1 i primena preparata NS Betafixin najprihvatljivije su, jer su na njima ostraveni najviši prinosi šećera. Primenom NS Betafixin-a može se smanjiti upotreba mineralnih đubriva, čime se smanjuje zagađivanje zemljišta nosačima hranljivih materija iz đubriva, a povećava se sadržaj i raznosvrsnost mikroorganizama u zemljištu

    The Effects of Different Substrates on the Quality of Seedlings and Yield in Organic Production of Lettuce

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    An experiment was conducted under glasshouse condition. Lettuce were sown in 5 different substrate: 100% earthworm; 60% earthworm + 40% potting soil; 85% earthwarm + 15% potting soil; 100% potting soil; certified organic substrate from the market (mix of white and black peat). The quality parameters of seedlings were noted: number of days from sowing to emergence, development of first leaf, total number of emerged plants. During vegetation are recorded dates about dynamics of growth. On the harvested yield were counted number of marketable and damaged leafs, diameter and height of head were determined and total weight of heads. Recorded results show that best substrate for production of seedlings of organic lettuce are mix of 60% earthwarm + 40% potting soil and commercial mix of white and black peats

    Osobine kvaliteta grožđa i vina sorte merlot (Vitis Vinifera L.) i klonova selekcionisanih u Srbiji

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    The third phase of individual clone selection of Merlot Cultivar was perfomed at Grocka vineyard, Republic of Serbia. The agrobiological traits and technological traits of three selected clones (022, 025 and 029) and variety (standard) were studied in the period 2009-2013. For all studied traits, except for grape yield, there was statistically significant difference among standard and clones. There was no significant difference between clones for any of the studied traits. The selected clones were characterized by good quality grapes and wines. Clone 025 has been found to have a good attributes for the production of high-quality red wines.Izvršena je selekcija trećeg vegetativnog potomstva klonova sorte Merlot u Gročanskom vinogorju, Republika Srbija. Ispitane su agrobiološke i tehnološke karakteristike grožđa i vina tri odabrana klona (022, 025 i 029) i sorte (standarda) u periodu od 2009 do 2013. godine. Standard i klonovi se statistički razlikuju po svim ispitivanim osobinama, osim po prinosu grožđa. Vina klonova se značajno ne razlikuju. Ispitivani klonovi se karakterišu dobrim kvalitetom grožđa i vina. Klon 025 je pokazao dobre odlike za proizvodnju vrhunskih crvenih vina

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