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    Sustainable Biocomposites Materials for Automotive Brake Pad Application: An Overview

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    Research into converting waste into viable eco-friendly products has gained global concern. Using natural fibres and pulverized metallic waste becomes necessary to reduce noxious environmental emissions due to indiscriminately occupying the land. This study reviews the literature in the broad area of green composites in search of materials that can be used in automotive brake pads. Materials made by biocomposite, rather than fossil fuels, will be favoured. A database containing the tribo-mechanical performance of numerous potential components for the future green composite was established using the technical details of bio-polymers and natural reinforcements. The development of materials with diverse compositions and varying proportions is now conceivable, and these materials can be permanently connected in fully regulated processes. This explanation demonstrates that all of these variables affect friction coefficient, resistance to wear from friction and high temperatures, and the operating life of brake pads to varying degrees. In this study, renewable materials for the matrix and reinforcement are screened to determine which have sufficient strength, coefficient of friction, wear resistance properties, and reasonable costs, making them a feasible option for a green composite. The most significant, intriguing, and unusual materials used in manufacturing brake pads are gathered in this review, which also analyzes how they affect the tribological characteristics of the pads

    Sustainable utilization of value-added products from the catalytic and non-catalytic pyrolysis of motor car scrap tire: Suitability of produced char for energy generation and sugar mill wastewater treatment

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    Clean fuel and sustainable energy utilization are essential requirements to address the impacts of global warming and climate change. In this study, the pyrolysis of motor car scrap tire was investigated in a fabricated cylindrical stainless steel reactor, operated at 450, 500, and 550 ◦C for 50 min with or without the addition of a catalyst. The catalytic condition yielded maximum char of 59% w/w obtained at 450 ◦C. The addition of the catalyst also enhanced oil yield up to 33% w/ w at 500 ◦C while the maximum gas fraction of 44% w/w was obtained under the non-catalytic condition, at 550 ◦C. The TGA/DSC analysis showed that the pyrolysis char had a specific heat capacity (Cp) of 35 J/g.K, relating to its high thermal stability for applications in furnaces, reactors, and heat construction materials. The char, after chemical activation, with the XRD analysis, showed that the produced activated carbon (AC) has a good crystalline structure (with high interplanar distances). The BET analysis revealed that the AC has a high surface area of 1065 m2/ g (average pore diameter of 3.36 nm) which enhanced the adsorption capacity of the AC to about 90 % efficiency for the removal of the heavy metal, cadmium, from sugar mill wastewater

    Whistleblowing and interpretation, addressing organizational challenges: a conceptual reflection from Nigeria

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    Purpose – This study aims to explore the effect of whistleblowing and interpretation among practitioners in the Nigerian economy. The research puts a premium on understanding the relevance and critical issues in its practices and developing an improved model for the effective practice of whistleblowing and interpretation in Nigeria. Design/methodology/approach – This study adopted a conceptual approach, relying on extant literature to understand the management of whistleblowing incidents and identify the managers’ and other stakeholders’ responsibility in the whistleblowing process. It applied systems dynamics conceptual modelling and presented an improvement approach to addressing the complexities associated with whistleblowing and interpretation among Nigerian organizations. Findings – This study contributed to the extant literature by developing a model for proper management of whistleblowing in the Nigerian context and enhancing the robust practice of whistleblowing and interpretation in Nigeria. The findings highlighted critical factors such as managers’ skills development, legal system support, institutional stakeholders’ function and ethical balance as key factors to effective whistleblowing management and interpretation. This implies that the act of identifying and developing responses to an emerging case of whistleblowing requires a process of developing underpinning assumptions, engagement and consideration of stakeholders’ interests while driving the sustenance of organizational focus. Originality/value – This study emphasized the departure from absolute best practice to developing idea approaches that reflect stakeholders’ interests and the context of whistleblowing and interpretation. While the study acknowledges limitations in the sole focus on the Nigerian private sector and the Nigerian economic background, it recommends further exploration of whistleblowing and its interpretation on a comparative approach, to improving the current understanding of the topic

    Resonant fractional order differential equation with twodimensional kernel on the half-line

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    This paper derives existence results for a resonant fractional order differential equation with two-dimensional kernel on the half-line using coincidence degree theory. Fractional calculus of Riemann-Liouville type is adopted in the study. The results obtained are illustrated with an example

    Satisfaction with Maintenance of the Public Sector Employee Housing Schemes in Lagos State, Nigeria

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    The Public sector employee housing is a kind of housing arrangement, which accentuates the role of the employer (government as well as its agencies) in assisting to deliver housing, mainly for the public sector workers. However, not much is known of the occupants’ satisfaction with the maintenance features of housing provided through this scheme in a large metropolitan area such as Lagos State. This study investigated the Maintenance Satisfaction features in nine public-sector employee housing estates in Lagos state, Nigeria. A cross-sectional survey research design involving quantitative research approach was adopted. The survey was carried out between September, 2020 and March, 2021. Using stratified sampling technique, the estates were grouped into the local government area. Cluster sampling was used to select the local government area. Also, purposive sampling technique was used to select 688 housing units in the nine purposively selected housing estates. 500 copies of the administered questionnaire were correctly filled and returned by the participants and the information were subjected to descriptive statistics. Statistical package for Social Science(SPSS) was used to analyze the data. The results pointed out that the respondents were most satisfied with the promptness of response to security issues in the estate, frequency of collection and disposal of refuse, frequency of maintenance of power supply facilities and least satisfied with the frequency of maintenance of roads within the estate, frequency of maintenance of drainage facilities and frequency of fumigation of the estate environment. Therefore, to improve maintenance satisfaction of inhabitants in public sector employee housing schemes, the key stakeholders such as the architects, builders and so on should give priority attention to the key features that ensure residents’ satisfaction

    DEMOCRACY, FEDERALISM AND GOVERNANCE IN NIGERIA

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    Nigeria became one of the federal societies under the supervision of the British colonial government in 1954. Federalism and democracy ceased when the military government usurped and suspended the Republican Constitution in 1966. The periods of military rule witnessed over-centralization of power at the centre, while the federating states became Lilliputians. The usurpation of jurisdictional competencies and centralization of power made the federating states and local governments default on their socio-economic responsibilities. The paper aims to elucidate the intricate relationship between federalism and democracy in Nigeria, shedding light on the repercussions of their erosion during military rule. Through a comprehensive review of historical events and constitutional changes, this study examined the consequences of over-centralization and jurisdictional encroachments during military governance. The paper revealed that the institutionalization of federalism once embraced without due consideration, led to detrimental adjustments and crises during military rule, significantly impeding socio-economic and political development. The paper concluded that democracy and federalism are twins ‘brothers’ and will remain relevant and last long when Nigerian leaders, particularly elected representatives, undertake constitutional reforms that prioritized power devolution to states and local governments. This adjustment, rooted in justice and fairness, will rejuvenate the symbiotic relationship between democracy and federalism, ensuring lasting relevance

    Dynamic Retention Strategies for Mitigating Health Workers Brain Drain

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    The departure of skilled health workers from Sub-Saharan Africa, Asia, and the Pacific poses a significant challenge for the global health workforce, exacerbating healthcare accessibility issues, labour shortages, and vulnerabilities within healthcare systems worldwide. This study aims to identify brain drain drivers and propose dynamic retention strategies tailored to the unique circumstances of each region, relying solely on secondary data. Drawing upon the Push-Pull and Social Exchange Theory frameworks, the study reviews existing literature, and it was revealed that there is an interplay of push factors, such as low pay, limited professional development opportunities, and challenging working conditions, alongside pull factors, including better income prospects and career advancement opportunities. This study advocates for dynamic retention strategies like enhancing employee engagement, implementing flexible work arrangements, promoting work-life balance, offering competitive compensation, facilitating professional development, and fostering supportive work environments tailored to each region's circumstances were imperative to mitigate the health workers brain drain syndrome. It also suggests the importance of strategic, context-specific interventions in mitigating brain drain and ensuring sustainable healthcare delivery worldwide and ongoing research and evaluation to assess their effectiveness. This can be achieved through collaborative efforts of stakeholders towards safeguarding the global health workforce and promoting equitable access to healthcare services for all

    Microbial biotechnology for bioenergy: general overviews

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    Bioenergy technologies are environment-friendly, renewable, and a clean way of powering the global community. Bioenergy technology is an innovation that improves the quality of life by simply reducing water and air contamination; this also mitigates energy dependence through creation of renewable resources locally. Bioenergy sources include wind, water, geothermal, nuclear power, solar, and natural gases. The most interesting and important part of bioenergy is the environmental benefits as part of a global energy future, which are aided by microorganisms. The future of bioenergy, however, seems bright because recent global information in this field proved that more renewable energy capacity has been fixed globally than new fossil fuel and nuclear capacity combined. As the global population progressively increases, there is an everincreasing demand for clean energy. The only safe answer to this is sustainable energy, which will protect the earth from climate change and make it a good habitat for all living organisms. This chapter provides a general overview to microbial biotechnology for bioenergy, sources, and challenges of bioenergy, role of microorganisms in bioenergy generation, innovations in bioenergy, and the environmental conservation of bioenergy

    Cytotoxic and phytochemical screening of Solanum lycopersicum–Daucus carota hydroethanolic extract and in silico evaluation of its lycopene content as anticancer agent

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    This article explores the potential of a specific functional food mix containing lycopene, a pigment found in tomatoes, for its role in cervical cancer prevention and treatment. The article assesses the cytotoxic effects on cervical cancer cells and conducts molecular docking analysis to understand the biological activities and binding interactions of lycopene. The formulations are analysed for their phytochemical profile, and their in vitro antioxidant activities are evaluated using spectrophotometric methods. Cytotoxicity tests on cervical cancer cells demonstrate that the ethanol extract of tomatoes exhibits the highest cytotoxic inhibition (40.28%), while carrots show minimal cytotoxic effects. Moreover, the lycopene extract exhibits dose-dependent cytotoxicity, with the highest concentration (1,000 μg/mL) displaying remarkable inhibition (74.2%). Molecular docking analysis indicates favourable interactions between lycopene and the pro-apoptotic protein BAX 1, suggesting its potential to induce apoptosis in cervical cancer cells, but camptothecin demonstrated stronger interactions. Molecular dynamics simulations confirm the stability of lycopene–protein complexes throughout the 100 ns simulation, supporting their potential as anticancer agents. Overall, the study highlights the cytotoxic effects of tomato–carrot food extracts and lycopene on cervical cancer cells. Molecular docking reveals the potential of lycopene to induce apoptosis through interactions with BAX 1. The stability analysis of lycopene–protein complexes further supports its anticancer properties. These findings enhance our understanding of the molecularmechanisms underlying the anticancer effects of lycopene and provide insights for future research on novel chemopreventive strategies for cervical cancer. However, further in vivo and clinical studies are warranted to validate the efficacy and safety of lycopene-based interventions

    HIGHER FRACTIONAL ORDER p-LAPLACIAN BOUNDARY VALUE PROBLEM AT RESONANCE ON AN UNBOUNDED DOMAIN

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    In this work, we use the Ge and Ren extension of Mawhin’s coincidence degree theory to investigate the solvability of the p-Laplacian fractional order boundary value problem of the form (f ( a ( )))¢ p D0+x t ( , ( ), ( ), ( ), ( ), 0 ( )), (0, ), 1 0 2 0 3 0 = a Î +¥ + a- + a- + a- f t x t D + x t D

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