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    The degree of soil fertility in the drainage basin of Râul Alb stream, Dâmboviţa county, up to the point it meets Bărbuleţu stream, expressed through the soil reaction and the supply of nutrients (organic matter, Nitrogen, Phosphorus and Potassium)

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    The field research took place in the interval 2019-2020, in the higher drainage basin of Râul Alb stream, located in the north-western part of Dâmboviţa County, the analysis covering an area of 4034 ha. The research into the complex phenomena of erosion in the analyzed area was based on a pedological study, which consisted in performing 46 pedological profiles in representative areas of the analyzed region. After centralizing the results, it was noted that 59.42% of the entire analyzed area display a low alkaline reaction, at least at the level of the upper layer, because of its CaCO3 content, which exacerbates the risk of landslide. From the point of view of the supply of nutrients (humus), most of the soils have a low and extremely low supply of these elements at the level of the upper layer, namely 73.42% of the analyzed area; as for the nitrogen supply, 26,68% of the entire surface of the drainage basin display severe shortages of this element. The situation is really serious in the case of the supply of mobile phosphorus in the soil, 3280.27 ha of the analyzed surface are low and very low in phosphorus, namely 76.20%, while the levels of potassium supply in the soils in the higher drainage basin of Râul Alb stream are mostly moderate and good, only 620.85 ha (14.42%) are extremely low and low in potassium supply

    Heavy metals assessment in the major stages of winemaking: Chemometric analysis and impacts on human health and environment

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    Wine contamination with heavy metals may pose long-term human health risks and environmental damages. This study evaluated the frequently detected heavy metals (HMs): Cr-Chromium, Fe-Iron, Cu-Copper, Mn-Manganese, Ni-Nickel and Zn-Zinc in the winemaking stages of white (Grasă de Cotnari) and red (Fetească neagră) wine varieties. Samples from wines and wastewaters were collected at eight different winemaking stages and HMs quantification was done by high-resolution continuum source atomic absorption spectrometry. Results showed that, in white wines Pb, Cu and Cr concentrations decreased during winemaking processes, while in red wines only Pb and Cu levels were reduced. A progressive increment was observed for Ni and Fe in white wines and for Cr, Ni and Fe in red wines, during winemaking. In the final winemaking stage of white wines, Fe and Mn concentrations were 3826 and 1493 μg/L, respectively, while in red wines, 1136 and 1256 μg/L, respectively. Analysis of wines consumption safety was performed according to the estimated daily intake (EDI) and target hazard quotients (THQ). EDI values of the analysed white wines ranged from 0.0032 to 6.2217, and for red wines from 0.0004 to 2.6919. THQ values below 1 suggested that moderate wine consumption does not have negative impacts on human health

    The influence of treatments with various phytosanitary products (fungicides) on the attack of some phytopathogenic fungi on barley harvest, Donau variety, in 2020 pedoclimatic conditions of the eastern Baragan

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    This study aims at monitoring the dynamics of the occurrence and evolution of the attack of some pathogenic agents to barley, among which we mention: mildew (Blummeria graminis f.sp. hordei), leaf stripe (Pyrenophora graminea) and barley’s rust (Puccinia hordei). Also, the influence of applying these fungicides on the production was monitored, as compared to the untreated control variant. For this study, an experiment with 6 treatment variants was created, in which the following phytosanitary products were used: AMISTAR (azoxystrobin 250 g/l), EVOLUS (prochloraz 320 g/l, tebuconazole 160 g/l, proquinazid 40g/l); FALCON PRO (prothioconazol 53 g/l, spiroxamine 224 g/l, tebuconazole 148 g/l), TOPSIN 500 SC (thiophanate-methyl 500 g/l), ORIUS 25 EW (250 g/l tebuconazole) and DITHANE M 45 (mancozeb 80%). The treatment variants were the following V1- AMISTAR 0.75 L/HA - 1 treatment applied at spike’s release - 13.05.2020, V2- EVOLUS 0.75 L/HA - 1 treatment applied at spike’s release - 13.05.2020, V3- FALCON PRO 0.6 L/HA 1 treatment applied at spike’s release - 13.05.2020, V4- TOPSIN 500 SC 1.0 L/HA + DITHANE M 45 2 KG/HA - 1 treatment applied at spike’s release - 13.05.2020, V5- ORIUS 25 EW 0.5 L/HA 1 + DITHANE M 45 2 KG/HA - 1 treatment applied at spike’s release - 13.05.2020, V6 - ORIUS 25 EW 0.5 L/HA + TOPSIN 500 SC 1.0 L/HA - 1 treatment applied at spike’s release - 13.05.2020, V7 - Untreated control variant. The experiment was placed in Latin square, the 7 variants being placed in 7 repetitions. The experiment was performed in the absence of irrigation. 2020 had been one of the draughtiest years in the last 3 decades, this fact leading to a poorer presence of the attack of the pathogenic agents specific to barley. The first two leaves placed under the spike had been analysed for the above. Among the pathogenic agents under monitoring, poor attacks produced by Pyrenophora graminea fungus which produces barley leaf stripe disease were observed. No attacks by Blumeria and Puccinia fungi were observed

    Optimized synthesis of new N-mustards based on 2-mercaptobenzoxazole derivatives with antitumor activity

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    New di-( -chloroethyl)-amides of some acids derived from 2-mercaptobenzoxazole were prepared by reaction of the corresponding pivalic mixed anhydrides with di-( -chloroethyl)-amine. A study regarding the optimization of the chemical reactions was made for the case of di-( -chloroethyl)- amines. The quantum chemical analysis by Spartan’14 was made in order to establish the most stable configuration of the ground electronic states for the obtained chemical structures and some physicochemical parameters of N-mustards reported in this paper. Mercaptobenzoxazoles substituted in the side chain with the cytotoxic group show antitumor activity and they inhibit Ehrlich Ascites in an appreciable proportion compared to the drug I.O.B.-82, as our studies evidenced

    The effect of different techniques of maceration-fermentation on the phenolic composition of red wines

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    Grapes, the quintessential quality factor in winemaking, are found in certain areas of the globe where viticulture thrives. The quality of wine products is directly influenced by the quality of the grapes, their process technology, the care and the quality of the premises and equipment used, as well as the conditions for the storage and use of the wines. In most red wine-making processes, it is preferred that the maceration process is accompanied by the fermentation process, as increase in the alcohol content favours the intensification of the extraction process. For this reason, both processes are combined in a single technological operation known as maceration-fermentation. The largest amount of polyphenolic compounds of wine, anthocyanins and tannins comes from the solid parts of the grapes ‒ the skins and seeds, and these have a decisive influence on the phenolic character of wines. Maceration is a fractional extraction which leads to the dissolution of the useful components of the grapes, which give the flavour, colour and taste typical of red wine. The aim of this research was to analyse the effect of different techniques of macerationfermentation on the phenolic composition of red wines obtained from Merlot, Pinot noir and Cabernet Sauvignon grape varieties in Copou-Iasi vineyard compared to red wines obtained from the same varieties in Murfaltar vineyard, located in the northeast and south of Romania, respectively. Wines obtained by maceration-fermentation in rotating tanks have higher values of the Folin-Ciocâlteu index (wines obtained from Pinot noir) in contrast to those obtained by the classical maceration-fermentation technique (wines obtained from Merlot and Cabernet Sauvignon). Keywords: maceratio

    Observații privind dăunătorii semnalați în plantațiile de măr din cadrul SCDP Iași și protecția fitosanitară a acestora

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    The observations took place in 2021 in the apple plantations of Research Station for Fruit Growing Iași, (Northeast of Romania), where a complex program of phytosanitary treatments was applied, taking into account the biology and ecology of the pests found in the apple plantations. Varieties on which observations have been made regarding the application and effectiveness of phytosanitary treatments were Idared and Jonagold varieties grafted on rootstock MM106. The climatic conditions of 2021 favored the development of pathogens and pests. Under the conditions of withdrawal of a large number of active substances, the pest control is becoming increasingly difficult, so that in 2021 a number of 11 phytosanitary treatments were applied, the degree of attack of the pest Cydia Pomonella L. being between 2% for the treated variant and 45% for the untreated variant

    Product design in food industry. Application of QFD methodology for improvement of chocolate quality

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    Quality Function Development (QFD) is a systematic approach specific to quality management that facilitates product development by ensuring consumer requirements meeting ”customer voice”, these being taken into account from the design phase, then during the entire technological process, being reflected in the quality characteristics of the finished product. The purpose of this study was to apply the QFD methodology (House of Quality, HoQ) to improve the quality of products in the food industry, taking into account the technological process of chocolate (designing a new product that meets the requirements of consumers), thus providing a synthetic model. The working method consisted in the participation of a number of 200 chocolate consumers, aged between 20-24 years, who provided the list of consumer requirements, prioritizing and weighting them based on a standardized score from 1 to 5 points. The following stages were represented by the transposition of consumers' voice in quantifiable technical requirements, their correlation using predefined symbols, establishing the direction of improving the quality of the new product, assessing current competition and determination of target values. Following the analysis, the most important consumer requirements for chocolate were: the taste of cocoa (25%), the flavor (25%), the fine texture (20%), the small amount of sugar (15%) and an affordable price (15%). Thus, in order to meet consumer requirements, the replacement of sugar with coconut nectar sugar or dates powder as alternative sweetener led to a healthy product, but which will have a higher price compared to the products currently available on the market. However, applying the level II/ III of QFD methodology the low cost was provided by mitigation of price of raw material’s

    Seedbed preparation in difficult conditions

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