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    Study of Provenance and Site Variability on Calorific Value and Other Fuel Properties of Teak Stem

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    Currently  Perum Perhutani has  conducted  efforts  to  improve  the   productivity  of  teak  forest  by   provenance  trial. However, only a few  studies have so  far considered the  variation of these main  fuel  properties of wood under the  influence of external factors such as location and provenance. On the  other side, the  huge amount of waste was regularly generated from primary  and secondary  wood processings.  Therefore, in  this  research, the  calorific  value  and other fuel  properties  were investigated and related to provenance and growth site. This research used the  stem wood and bark of five provenances (1 to 5) of teaks that  were planted at  three sites  of Perhutani stand (Bojonegoro, Ngawi, Ciamis). The fuel  characterisctics of bark were only evaluated  at  Ciamis  site.  Compared  to  bark, wood generally had lower values  in  ash content, volatile  matter content, and density,  but  had higher values in fixed  carbon content, calorific  value, and Fuelwood Value Index levels. The caloric  values of  teak  wood and  bark were 4,191~4,520 cal/g  and 3,545~3,939 cal/g,  respectively.  Provenance and site interaction had significant effect to the ash content, density, and calorific value in wood. The samples from  Ciamis site (code Ft) had the  highest level  in  calorific  value. However, the  relation  between calorific  value and density  is  not  clear in  this experiment. With regard to bark, provenance 3 (Ft) showed the  best energy properties

    The Characterization of Black-streaked Heartwood in Teak: Inter-tree Variation

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    The objective of  this  study was to  investigate the  variation in the  color and chemical characteristics of  black-streaked heartwood of teak and explore the relationship of these chemical properties with the  degree of blackening. The samples used were outer heartwood parts from  11  trees with  black streaks both  thin  and thick and 7  trees with  normal heartwoods for comparison.  The colorimetric  analysis in  CIEL*a*b*  system was used to  determine  the  brightness  values (L*)  of  black- streaked heartwood of teak ranging from  40~49 and a thick portion produced appreciably higher average values of extractive contents including  n-hexane,  ethyl acetate, and total  extractive  content as well as tectoquinone contents and pH values but lower squalene content compared to those in normal wood. The degree of blackening in the  black-streaked  heartwood was highly correlated to its extractive contents, especially the  ethyl acetate soluble extractive content (r = −0.94) while moderate correlations  were measured  between  the  brightness  index  and  tectoquinone content (negative)  and squalene (positive). Moreover, no  significant difference was found in the  ash and individual inorganic elements contents between the  group. The increase  in  pH   values  was observed  to  have  corresponded with  a decrease  in  brightness  (r  = -0.75).  Therefore,  the blackening was assumed to be  due to the  polymerization of quinones in weakly acidic condition

    Measurement of Microfibril Angle Using X-Ray Diffraction and Light Microscope on 5-year-old Super and Conventional Teak Wood

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    The long   harvest time  causes the   processing  industry  manufactured  from   teak  wood (Tectona  grandis L.  f.)  has experienced  a lot of declines. To overcome this  problem,  currently,  in Indonesia  many types  of fast-growing  teak  have been developed, one of which is Jati Unggul Nusantara (JUN). Trees that  are accelerated in growth, are likely to cause changes in their  anatomical  structure. The anatomical  structure of wood is one of the  basic  properties  that  greatly influences  the  use of wood as a raw  material. Even small changes in cell shape and size can change the  properties of wood as a raw  material. One of the  anatomical  structures of wood, namely the  ultramicroscopic  structure that  affects the  quality  of wood, is the  microfibril angle (MFA). The purpose of this  study is to determine  the  MFA of JUN at the  planned cutting  age of 5 years, compared to conventional teak at  the  same age. There are two  methods used, namely using X-Ray Diffraction (XRD) and measuring the elongation  of  the  pit  apertures slope of  the  fiber  cells using  a light  microscope,  which was obtained from  the  maceration process. As  a result, JUN's MFA is 22.09°, smaller than  the  conventional teak of 25.29°. This is because JUN was developed from  top  cuttings  so  although  still  young, it  already  reflects  the   characteristics  of  mature teak. The results of  the  MFA measurements on  JUN using two  methods (XRD and light microscope), resulted different values. It is different from  the  MFA measurement results on  conventional teak. It is recommended to  measure the MFA in JUN wood by  using XRD, because possibly, due to accelerated  growth, simple pits with an  oval shape turn  into circular. This difference causes the  results of the JUN MFA measurement using a light microscope based on the  pit apertures slope to be  inconsistent, subjective, and different results  in  other  pits   contained  in  the   fiber   even  though they  are  closely  associated. However,  in  conventional  teak, measurements using a light microscope are possible because the  shape of the  pit is oval so  that  the  slope of the  elongation of the  pit aperture can be  determined easily, and is more consistent with more uniform values in the  same individual fibe

    The Effectiveness of Boron Preservatives to Prevent Dry-wood Termite Attack on Mahogany Sapwood

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    Mahogany wood  is utilized for many furniture products and construction purposes. The objective of this experiment was to  prevent  wood-destroying  insects  by   using  boron  preservatives  such as boric  acid  and borax.   Materials  used were mahogany  sapwood  planks  (19   years)  obtained  from   community  forest  in  Kali  Bawang  District,  Kulon  Progo.  Two preservation  methods,  i.e.,  hot-soaking  (1,   2,   and  3  hours) and  the   cold-soaking  (12,   24,   36,   and  48  hours)  in  5% concentration,  were used. The drywood termites  (Cryptotermes  cynocephalus Light)  were used for  observation.  The result showed that  the  retention  value ranges were 4.25  to 12.99  kg/m3  for cold-soaking  method and 3.09  to 9.53  kg/m3  for heat- soaking method. Mortaliy rate and mass loss  due to termite attacks ranged from  56.0  to 80.6  % (control values : 43.3%) and 850  to  1370  mg  (control values : 1930  mg). Significant interaction between soaking time and the  type of  preservative was observed to  discover its  effect on  the  levels of  retention (cold soaking) and mortality rate of  termites (hot  soaking). Boron preservatives tended to enhance the  repellent properties than  its toxicity

    Characteristics of Carbon from Oil Palm Shell Activated by Low Concentration of Zinc Chloride Activator

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    Currently, a large amount of oil palm shell has been dumped as waste from  palm oil processing  in Indonesia.  Using  a low  concentration  of  zinc   chloride  (ZnCl2),  thermal treatment during  pre-carbonization  was applied  in  the  preparation  of activated carbon from  oil palm shells at various temperatures and reaction durations. This study, therefore, aims to investigate the   physical  and chemical  characteristics  of  activated  carbon  prepared.  Oil palm  shells  collected  from   a plantation  in Palembang were carbonized by  two methods, one-stage carbonization (at 300°C for 3 hours) and two-stage carbonization (at 300°C for 3 hours, then  at  600°C for an  hour)  before chemical activation using ZnCl2, at  a concentration of 10  and 15%wt. Activation of oil palm shell charcoal was conducted at  600,  700,  and 800°C and reaction times  of 60,  120,  and 180  minutes. The results showed two-stage carbonization, high  temperature, and prolonged reaction time is bound to increase burn-off as well  as methylene blue adsorption, and decrease the  yield and volatile matter content of  the  activated carbon prepared. Meanwhile, high  ZnCl2  concentration increased the  ash content and the  methylene blue adsorption. In addition, the  two-stage carbonization  had higher iodine  adsorption  compared to the  one-stage  carbonization.  The activated  carbon with  high  iodine (769.3 mg/g) and methylene blue adsorption (133.7 mL/g) levels was obtained by  two-stage carbonization using 15%wt ZnCl2 at a temperature and reaction time of 800°C and 180 minutes, respectively

    The Natural Durability and Drying Properties of Ganitri Wood (Elaeocarpus sphaericus Schum)

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    Ganitri (Elaeocarpus sphaericus Schum.) is a fast-growing species that was majority planted in community-based forets in Java. This research aimed to evaluate the natural durability and drying properties of ganitri wood, hence the best uses of the wood can be achieved. The wood durability was tested in laboratory and field scales based on SNI 7207:2014  and ASTM D 1758-02 standards respectively, while the wood treatibilty evaluation used soaking method with 5% borax preservative. The wood drying property was assessed through oven drying at 100°C temperature based on Terazawa method. The resistance of the wood against subterranean termites Coptotermes curvignathus is classified as durability class IV. Ganitri wood was very easy to be preserved with the cold soaking method.  Boron retention in ganitri was 22.87 kg.m-³, while its penetration was 27.80 mm or 94.24%. Ganitri had rather poor drying properties, which was prone to surface check. The proper drying for ganitri wood was suggested using initial and final temperatures 53°C and 83°C, respectively, while the initial and final relative humidity were 85% and 30%

    Distribusi, Retensi, dan Penetrasi Bahan Pengawet Ekstrak Daun Tuba (Derris elliptica Benth) pada Kayu Kemiri dan Kayu Agathis (Distribution, Retention, and Penetration of Tuba Leaves Extract (Derris elliptica Benth) on Aleurites moluccana and Agathis Wood)

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    Wood preservation is carried out to increase the service life of wood with low natural durability. Factors such as wood structure, preservatives, and methods of preservation influence the preservation processes. The aim of this study was to evaluate retention, penetration, and distribution of tuba (Derris elliptica) leaves extract into the candlenut wood (Aleurites molluccana) and agathis (Agathis sp.) wood structures. The wood samples were treated with hot and cold soaking. The duration of hot soaking were 3, 5, and 7 hours, while for cold soaking were 3, 5, and 7 days. The result showed that the highest retention of extract was achieved by cold soaking for 7 days at 9.4 kg m-3, and the lowest retention was achieved by hot soaking for 3 hours at 1.9 kg m‑3. The highest penetration occured by cold soaking for 7 days at 8.08 mm and the lowest was that with hot soaking for 3 hours at 2.81 mm. However, the distribution of the extract in the agathis wood structures could not be detected by stereo microscope. In the the case of the candlenut wood, the extract was distributed in the parenchyma cell

    Identifikasi Senyawa Ekstraktif Kayu Cendana Papua dan Potensinya Sebagai Pengusir Nyamuk

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    Penelitian ini bertujuan untuk mengidentifikasi komponen kimia dari kayu cendana Papua (Flindersia sp.) dan menganalisa potensi pemanfaatannya sebagai pengusir nyamuk.  Metode eksperimen yang dilakukan adalah analisis fitokimia kualitatif, analisis GCMS Pirolisis, dan uji mortalitas nyamuk untuk menginvestigasi sifat anti-nyamuk dari jenis kayu ini berdasarkan SNI 06-3566-1994. Hasil analisis fitokimia menunjukkan adanya komponen fitokimia seperti alkaloid, saponin, flavonoid, terpenoid, glikosida dan fenolik. Analisis GCMS pirolisis mengindikasikan bahwa diantara 43 senyawa kimia, butylated hydroxyanisole (5,37%), carbamic acid (5,30%), 2,4 imidazolidinedione (2,13%) and hydrazin (1,23%) adalah senyawa yang berperan dalam mengusir nyamuk. Uji mortalitas nyamuk menggunakan sampel uji dengan komposisi serbuk cendana Papua dan tempurung kelapa sebesar 50:50 menunjukkan tingkat kematian nyamuk tertinggi (55,6%). Hal ini mengindikasikan bahwa jenis kayu ini berpotensi untuk dijadikan sebagai bahan kimia alami pengusir nyamuk

    Sifat-Sifat Arang Aktif Kulit Batang Sagu Hasil Karbonisasi Hidrotermal

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    Kulit batang sagu merupakan salah satu limbah padat pengolahan tepung sagu (Metroxylon sp) yang berpotensi digunakan sebagai bahan baku arang aktif. Tujuan penelitian ini untuk mengetahui sifat-sifat arang aktif kulit batang sagu yang dibuat melalui metode karbonisasi hidrotermal dan aktivasi steam. Pembuatan arang aktif didahului dengan pembuatan prekursor (bahan awal pembuatan arang aktif) melalui metode hidrotermal pada suhu 250 °C dan dilanjutkan dengan aktivasi pada suhu 800 °C selama 0, 60, 80, dan 100 menit. Pengujian proximat dan daya jerap iodin menggunakan standar SNI dan pengamatan struktur arang aktif menggunakan X-ray diffraction (XRD). Hasil penelitian menunjukkan bahwa rendemen 45,90-55,70%, kadar air 5,82-7,06%, zat terbang 5,66-9,40%, kadar abu 12,24-14,54%, karbon terikat 78,36-79,80%, daya jerap iodin 455,59-759,86 mg.g-1, dan derajat kristalinitas 31,66-38,81%. Arang aktif terbaik adalah arang aktif kulit sagu perlakuan steaming 80 menit yang memiliki daya jerap iodin sesuai dengan SNI 06-3730-1995 yaitu ≥750 mg.g-1.

    Antifungal and Antioxidant Activities of Lipophilic Compounds from Swietenia mahagoni (l.) Jacq. Leaves

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    The investigation on the n-hexane lipophilic extractives of Swietenia mahagoni, alongside the antifungal and antioxidant properties was conducted. The leaf sample was collected from 2- and 3-years-old trees in Perhutani enterprise of Temanggung, Central Java, Indonesia. In addition, the antifungal activity was tested using the white-rot of Phanerochaete chrysosporium, while the antioxidant property involved the DPPH (1,1-diphenyl-2-picrylhydrazyl) method. The results show antifungal of 28.6% and 37.5% growth inhibition in 2- and 3 -years-old leaf, respectively, while 21.7% and 25.4% antioxidant activity were also recorded. Furthermore, the GC-MS results showed the domination of S. mahagoni leaf by fatty acids and hydo-carbons, while the terpenoids and steroids were in minor quantities. These components possibly exhibit growth inhibitory and antioxidant effects against P. chrysosporium and DPPH radicals, respectively

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