eJournal MAPEKI (Masyarakat Peneliti Kayu Indonesia)
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Simultaneous Saccharification and Fermentation of Oil Palm Empty Fruit Bunch Fiber Kraft Pulp to Produce Ethanol
The effects of substrate concentration on ethanol production from simultaneous saccharification and fermentation (SSF) of oil palm empty fruit bunch (EFB) kraft pulp by cellulase and Saccharomyces cerevisiae MK 1 were studied. Substrate concentration was varied from 10 to 20%. Cellulase was added at 4 g-1 substrate, while the yeast inoculum was 10% (w v-1). The SSF process was carried out at 37°C, pH 4.5, 100 rpm for 76 hours. Ethanol production were obtained after 24 hours, however, ethanol concentration was decreased after 60 hours of fermentation. The highest ethanol concentration was obtained from samples with substrate concentration of 15% (w v-1). A much higher ethanol concentration was produced when that particular substrate was supplemented with 2% of sugar
Pengaruh Durasi Steam terhadap Kualitas Arang Aktif Limbah Sagu (The Effect of Steam Duration on Quality and Characteristics of Activated Charcoal of Sago Waste)
Sago waste is a potential biomass that can be used as active charcoal raw material. The objectives of this research were to know the effect of steam duration on quality and characteristics of activated charcoal of sago waste. Carbonization process was carried out at 400 ⁰C for four hours, then activation was carried out at 100 ml bar steam pressure, at a temperature of 800 ⁰C with variations of steam duration 60, 80 and 100 minutes and activation without steam, only heating for 60 minutes. The proximate test used the SNI standard, observed the functional group using Fourier Transform Infrared Spectrophotometer (FTIR) and observed the active charcoal structure using X-ray diffraction (XRD). The results showed that the yield, moisture content, volatile, ash content, fixed carbon, iodine absorption of activated charcoal of sago bark and sago soft core were, respectively, 39.22–84.10%, 4.63–6.39%, 3.03–5.06%, 7.74–33.43%, 61.54–88.63%, 158.60–972.60 mg g-1. XRD analyzes showed that the degree of crystalline activated charcoal of sago bark waste with the highest steam time of 100 minutes (35.98%) compared with the degree of crystalline other activated charcoal is only about 20.57-7.30%. FTIR spectroscopy results from activated charcoal of sago waste also identified nitrogen compounds such as NO2 at wave numbers 1370-1390 cm-1; 1530-1560 cm-1; 1620-1660 cm-1 and phosphorus compounds such as P-S at 200-500 cm-1 wave number; P=S at the wave number 500-850 cm-1
Perbandingan Sifat Bahan Baku dan Pulp Kraft Geronggang (Cratoxylon arborescen) Alam dan Tanaman (Comparison the Properties of Raw Material and Kraft Pulp from Nature and Plantation of Geronggang Wood (Cratoxylon arborescen))
Geronggang (Cratoxylum arborescen) is one of local wood in Riau peatlands has potential as raw material for pulp. This study aims to compare properties of raw material and kraft pulp from nature and plantation of geronggang wood. The parameters observed were chemical properties, fibers dimension, and pulp properties. The comparison of the both geronggang properties were analyzed using T test. The results indicated that both geronggang wood nature and plantation showed similar chemical properties in term of extractives, cellulose, and hemicellulose, and fiber dimensions except lignin content. Kraft properties of both geronggang woods also have similar results of yield and Kappa number, except lignin content
Aktivitas Antioksidan dan Tabir Surya Ekstrak Daun Gyrinops versteegii (Antioxidant activity and Sunscreen of Gyrinops versteegii Leaf Extract)
The aim of this study was to determine the yield and phytochemicals, antioxidant activity, and sunscreen of the Gyrinops versteegii leaf extracts. The leaf simplicia was extracted using soxhletation method with multilevel polarities of solvent (n-hexane, ethyl acetate, and metanol). The analysis of phytochemical extracts has been carried out the qualitatively and quantitatively. The antioxidant activity testing was performed in vitro through the effective concentration (EC50) extract in capturing DPPH radicals. Sunscreen activity has been done through testing sun protection factor (SPF). The result showed that the yield of n-hexane extract, ethyl acetate, and methanol extracts were 7.83, 5.46, and 6.77% respectively. The phytochemical analysis showed that the ethyl acetate and methanol extracts were strongly detected containing antioxidant compounds such as p-hydroquinone, flavonoid, and tannins with the total phenol of the ethyl acetate and methanol extracts were 3.40 and 4.27% respectively. The n-hexane extract detected contains weakly the antioxidant compounds with the total phenol was 0.45%. The methanol extract is the highest antioxidant activity (EC50 14.46 μg ml-1) and has ultra sunscreen activity (SPF>15)
Keragaman Genetik Pertumbuhan dan Hubungannya dengan Penetrasi Pilodyn pada Uji Provenansi-Keturunan Jabon (Neolamarkcia cadamba (Roxb) Bosser) di Parung Panjang, Bogor) (Genetic Variation of Growth and Its Relationship with Pilodyn Penetration on Provenance-Progeny Trial of Jabon (Neolamarkcia cadamba (Roxb) Bosser) at Parung Panjang, Bogor)
Jabon (Neolamarkcia cadamba (Roxb) Bosser) is a fast growing and preferred species as material for various wood industries. However, the growth and quality information of its wood is still limited. This study aims to assess the characteristics of growth, physical properties of wood, genetic parameters of growth and physical properties of wood, and its relationship with pilodyn penetration on provenance-progeny trial of jabon in Parung Panjang, Bogor. Measurement of growth characteristics was performed on height and diameter at breadst height (DBH), whereas the physical properties of wood (density, specific gravity, and moisture content) were performed using core samples (destructive methods) and density estimation with pilodyn (nondestructive method). Statistical analysis explains that there are significant differences between provenances in height, diameter, pilodyn penetration, density, and specific gravity, except for moisture content. The mean of plant survival percentage of 36 months old jabon was 52.8%. The relationship between growth character and the physical properties of wood with pilodyn penetration is negative and weak, except in moisture content, positive but weak. The estimation of individual heritability value ranges from 0.011 to 0.183, while heritability of the family ranges from 0.017 to 0.308
Physical-Mechanical Properties and Bonding Mechanism of Corn Stalks Particleboard with Citric Acid Adhesive
As a natural fiber and agricultural by-product, corn stalks (Zea mays saccharata) is considered as an alternative raw material to produce particleboard. Corn stalks is a good source of lignocelluloses, renewable and low cost. This research was aimed to investigate the characteristics of corn stalk particleboard with citric acid as adhesive. This study also evaluated bonding mechanism particle with citric acid and the bonds between celluloses derived corn stalk with citric acid. The boards were manufactured under the hot pressing temperature 200 oC for 10 min. The citric acid concentration was varied in 0, 15, 20 and 25 wt%. The board size and target density were (25 x 25 x 0.9) mm3 and 0.8 g.cm‑3. Results showed that the physical properties of particleboards improved with increasing citric acid concentration up to 20 wt%. At the optimum citric acid content of 20 wt% could provide particleboards with the modulus of rupture, modulus of elasticity and internal bonding satisfied the requirement of the 13 type of the JIS A 5908 (2003) standard. Infrared (IR) spectral analysis from board which manufactured from isolated cellulose was mixed citric acid and pressed on temperature 200 oC showed the presence of ester linkages that the carboxyl and hydroxyl groups of citric acid had reacted with the hydroxyl groups of corn stalk cellulose
Aktivitas Antirayap Ekstrak Daun Pepaya dan Kumis Kucing (Antitermite Activities of Leaf Extracts of Pepaya and Kumis Kucing)
Antitermite activities of leaf hexane extract of cat whiskers (Orthosiphon sp.) leaves, ethyl acetate, and ethanol- toluene extracts of pepaya (Carica sp.) leaves were investigated in several concentrations (1, 5, 10, and 15%, weight based) that be impregnated to filter papers againts the dry-wood termites Cryptotermes sp. After impregnation, filter papers were dried into oven at 60 °C for 3 hours, then were tested to termites for 4 weeks. The results showed that treatment concentration could obtain the highest termites mortality level, no weight loss and the lowest damage level. Ethyl acetate extract of papaya leaves exhibited the highest termites mortality (91.2%) at concentration of 10%. This concentration also showed the lowest weight loss (0%) and the highest antifeedant activity (antifeedant coefficient of 100%). Ethyl acetate extract of papaya leaves exhibited the lowest of LC50 value (7844.20 μg ml-1 ). Antitermitic activity showed a trend more repellent than toxic. Fatty acid such as hexadecanoic acid, linolenic acid, octadecanoic acid and steroid compounds that detected by GC-MS were estimated to play a role as antitermite agents. Thus, the application of ethyl acetate extract of papaya leaves at concentration of 10% was recommended to the next experiment by using solid wood impregnation
The Physical and Mechanical Properties of Glulam Made from Pine and Jabon Woods
Wood from plantation forests can be used to make glued laminated lumber (glulam) products for structural applications. Wood from two species, namely pine (Pinus merkusii) and jabon (Anthocephalus cadamba), and polyurethane and tannin mahogany adhesives (glue spread 200 g m-2) were used to manufacture glulams. The aim of this research was to determine the physical and mechanical properties of glulam made from pine and jabon woods. Wood densities of pine and jabon were 0.71 and 0.43 g cm-3, respectively. The glulams consisted of three layers of the same wood species, and samples were (3×6×120) cm3 in thickness, width, and length, respectively. The physical and mechanical properties of glulam were tested according to Japanese Agricultural Standard (JAS) 234-2007. The results showed that glulam made from pine met the standard for modulus of elasticity and modulus of rupture (MOR) values. Glulam made from jabon wood fulfilled the standard for MOR, shear strength, and hot- and cold-water delamination tests. In the formaldehyde emission test, jabon glulam fulfilled the F*** (low emission) standard and pine glulam met the F**** (very low emission) standard according to JAS 234-2007
Peningkatan Sifat Papan Partikel Sengon dengan Perlakuan Perendaman Air Dingin (Improvement the Properties of Particleboard Made from Sengon with Cold Water Immersion Treatment)
The objectives of this research is to evaluate the physical and mechanical properties of particle board made from sengon and mangium woods treated with cold water immersion. Particles of sengon and mangium immersed in cold water for 24 hours. The particles of sengon and mangium are combined with a ratio of 100: 0; 0: 100; 75:25; and 50:50. Particle boards are made in size (30x30x0,9) cm3 with target densities of 0.7 g cm-3. The particle board was binded with methylene diphenyl diisocyanate (MDI) adhesive at 10% content and hot press at 140 °C with 25 kgf cm-2 for 7 minutes. The physical and mechanical properties of particle board are evaluated according to JIS A 5908-2003 standard. The physical and mechanical properties of particle board were much affected by particle combination and cold water immersion treatment. The physical (i.e density, moisture content, water absorption (WA), and thickness swelling (TS)) and mechanical properties (ie. modulus of elasticity (MOE), modulus of rupture (MOR), and internal bonding (IB)) were evaluated. The results showed that cold water immersion improved dimensional stability (WA and TS) of particle board obtained. However, some mechanical properties decreased
Aplikasi Serat Kapuk dan Balsa dengan Perlakuan Alkali sebagai Bahan Penguat Komposit (Alkaline Treated-Kapok and Balsa Fibers for Composite Reinforcement)
Natural fibers of kapok and balsa can be potential renewable raw material for reinforced polymer composite. Alkaline treatment carried out in the present works was intended to develop the physical and chemical properties of the fibers before its application in reinforced composites preparation. The treatments involve of using NaOH at the concentration of 2, 4, 6, 8 and 10%. The change of morphological characteristics, crystallinity index, functional groups, and water contact angle were analyzed by using SEM, FTIR, XRD and contact angle analyzer, respectively. Upon alkaline treatments, the fibers were clean, flatten, and the surface tended to be rough. Defibrillation occurred at higher alkaline concentration. Alkaline treatment on the fibers shifted and changed the peak absorption intensity of -OH, C-O, C=C and C=O. Up to 8% NaOH concentration, alkaline treatment increased the crystallinity of the fibers, however decreased when the concentration of NaOH reaching 10%. Alkaline treatment on the fibers removed lignin, hemicellulose, and waxy substance of the fiber surface, increased surface roughness, and therefore is expected to create better interfacial adhesion