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Comprehensive Framework for Sustainability Assessment of Ecosystem Services and Land Use Change
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A Study on the Analysis and Prediction of Thermochemical Conversion Processes of Solid Carbonaceous Fuels Based on Detailed Chemical Kinetic Models
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Study on ensuring early growth and stability of sago palm in southern Sumatra, Indonesia
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Oxidation of Platina(II)corrole to Platina(IV)corrole
No full textRecently, the aromaticity and antiaromaticity of organometallacycles have received much attention to understand the cyclic electronic delocalization through d orbitals on the metal center. Here, we prepared a Pd(II) platina(II)corrole bipyridyl complex, which was converted to the corresponding stable Pt(IV) complex upon oxidation with iodobenzene dichloride. Oxidation of the platinum center did not result in the C–C bond formation between two pyrrole units via reductive elimination. The X-ray diffraction analysis of these complexes elucidated their nonplanar molecular structures. The nonaromatic nature of platina(II)- and platina(IV)corroles was revealed by 1H NMR analysis and NICS calculations.journal articl
