Institutional Repository of Institute of Process Engineering, CAS (IPE-IR）
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Hollow multishelled structural ZnO fillers enhance the ionic conductivity of polymer electrolyte for lithium batteries
No full textComposite polymer electrolyte (CPE) with ceramic fillers has gained great attention for lithium batteries with high energy density and safety. However, the agglomeration of ceramic fillers and weak polymer-ceramic interaction induces limited ionic conductivity and hinders its implementation. Here, hollow multishelled structure (HoMS) ZnO with a size range of 700 similar to 900 nm is designed as fillers for polyethylene oxide (PEO)-based CPE. Strong chemical and mechanical interaction between PEO and ZnO HoMS enable a high ionic conductivity and good electrochemical and mechanical stability. Wherein, double-shelled ZnO HoMS exhibits a good ionic conductivity of 1.04 x 10(-4) S center dot cm(-1) and 1.2 x 10(-3) S center dot cm(-1) at 30 degrees C and 60 degrees C. Additionally, all-solid-state LiFePO4/Li full cell adopted with ZnO HoMS filled CPE exhibits a high initial specific capacity of 169 mAh center dot g(-1) and good cycling stability and withstands abuse test. The enhanced performance is due to that HoMS provides PEO with faster ion transport channels, more effective Lewis acid-based interaction sites, suppressed PEO crystallinity, and improved ionic conductivity
Recovery of tungsten and titanium from spent SCR catalyst by sulfuric acid leaching process
No full textThe widespread use of selective catalytic reduction (SCR) catalysts has resulted in a large accumulation of spent SCR catalysts. These spent catalysts present a significant risk of environmental hazards and potential for resource recovery. This paper presents a feasible process, which works using atmospheric pressure leaching, of tungsten and titanium recovery from spent SCR catalysts. In this new method, titanium and tungsten are simultaneously leached with sulfuric acid as the leaching agent. After hydrolysis and calcination, titanium-tungsten powder with low impurity and reconstructed pore properties was obtained. The optimal conditions for the leaching of Ti and W were as follows: temperature, 150 degrees C; reaction time, 60 min; H2SO4 concentration, 80 %; mass ratio of H2SO4/TiO2, 3:1; and diluted H2SO4 concentration, 20 % after reaction. With these optimum conditions, the leaching efficiency of Ti and W were found to be 95.92 % and 93.83 %, respectively. The ion speciation and reaction mechanism of W were studied by Raman spectroscopy, FTIR, and UV-vis. The formation of heteropolytungstate with a Keggin structure is essential for the synergistic leaching of Ti and W, as the heteropolytungstate can be stably dissolved in the acid solution. During the hydrolysis process, heteropolytungstate gradually decomposed into Ti4+ and WO42- due to the formation of insoluble Ti(OH)(4) from Ti4+ in the solution. This study demonstrated an effective method for synergistic recovery of titanium and tungsten from the spent SCR catalyst
Improving flotation separation of micro Si/SiC particles from silicon sawing waste by surface hydrophilic modification
No full textSilicon sawing waste (MSW) produced by mortar cutting causes serious environmental issues and a waste of highpurity silicon. The major obstacle in the recovery of high-purity silicon (Si) is the separation of microscale Si and silicon carbide (SiC) in MSW. In this study, micro Si/SiC in silicon sawing waste was separated effectively by bulk-oil flotation after surface hydrophilic modification of Si particles. The structural evolution of micro Si surface after wet oxidization in water and acid was characterized by FT-IR, TEM, and XPS. Specifically, the wet oxidization process reduced the contact angle from 63 +/- 0.3 degrees to 18.5 degrees of Si surface for the coating of an amorphous oxide with hydroxy groups on Si particles enhanced the wettability. The amorphous oxide layer with hydroxy coated on Si particles played a key role in enhancing the wettability of Si particles. The wet oxidization is essential to the subsequent flotation separation for the contact angle of SiC keeping at around 60.3 degrees. The wettability of silicon sawing waste was further examined by the absorption of diesel. The effects of pH value and solid concentration on separation efficiency were studied. The best result obtained was 95% in Si recovery and 97.1 wt% in Si purity
Gas/particle flow and pressure variation characteristics of Ende pulverized coal gasifier equipped with ejector
No full textEnde pulverized coal gasifier (EPCG), as a typical representative of circulating fluidized bed gasifier, has been widely used in gasification field. The return conduit of EPCG is generally not equipped with a feedback control device (FCD), which tends to result in a low solid circulation rate (G(s)) and high unburned combustibles in fly ash. To address these issues, a new technique using the ejector as the FCD was designed to provide a stable pressure barrier and improve solid circulation. Preliminary thermal experiments demonstrated the feasibility of improving the EPCG with injector system. Currently, the specific mechanisms that contribute to further optimize this technology have not been systematically studied. Considering the large impact of ejector operation on solid circulation rate and stability as well as syngas production, this work adopts a gas/particle 1:15 cold EPCG bench to investigate the gas/particle flow and pressure variation characteristics before and after ejector operation and under different working medium pressures (P-p). When the ejector operates at the design pressure P-s = 0.187 MPa, the outlet pressure of the return conduit is slightly larger than the furnace bottom pressure, thus preventing the reverse gas flow at the furnace bottom. The particle velocity and concentration distribution in the furnace are basically consistent with that without the ejector, showing a similar central spout region and near-wall annulus flow region. As P-p increases from 0.04 to 0.24 MPa, the average particle velocity in the return conduit increases from 0.95 to 2.4 m/s, the particle concentration decreases from 0.088 to 0.051, and the solid circulation rate increases from 0.37 to 0.53 kg/h. The ejector outlet pressure gradually increases, the inlet pressure decreases, and the pressure barrier provided by the ejector rises from 1052 to 3640 Pa. When P-p is 0.12 MPa, the ratio of G(N2)/G(air) is 0.91%, which can achieve the purpose of continuous and stable pressurization with a small amount of nitrogen
Gas/particle flow and pressure variation characteristics of Ende pulverized coal gasifier equipped with ejector
No full textEnde pulverized coal gasifier (EPCG), as a typical representative of circulating fluidized bed gasifier, has been widely used in gasification field. The return conduit of EPCG is generally not equipped with a feedback control device (FCD), which tends to result in a low solid circulation rate (G(s)) and high unburned combustibles in fly ash. To address these issues, a new technique using the ejector as the FCD was designed to provide a stable pressure barrier and improve solid circulation. Preliminary thermal experiments demonstrated the feasibility of improving the EPCG with injector system. Currently, the specific mechanisms that contribute to further optimize this technology have not been systematically studied. Considering the large impact of ejector operation on solid circulation rate and stability as well as syngas production, this work adopts a gas/particle 1:15 cold EPCG bench to investigate the gas/particle flow and pressure variation characteristics before and after ejector operation and under different working medium pressures (P-p). When the ejector operates at the design pressure P-s = 0.187 MPa, the outlet pressure of the return conduit is slightly larger than the furnace bottom pressure, thus preventing the reverse gas flow at the furnace bottom. The particle velocity and concentration distribution in the furnace are basically consistent with that without the ejector, showing a similar central spout region and near-wall annulus flow region. As P-p increases from 0.04 to 0.24 MPa, the average particle velocity in the return conduit increases from 0.95 to 2.4 m/s, the particle concentration decreases from 0.088 to 0.051, and the solid circulation rate increases from 0.37 to 0.53 kg/h. The ejector outlet pressure gradually increases, the inlet pressure decreases, and the pressure barrier provided by the ejector rises from 1052 to 3640 Pa. When P-p is 0.12 MPa, the ratio of G(N2)/G(air) is 0.91%, which can achieve the purpose of continuous and stable pressurization with a small amount of nitrogen
Introducing High-Valence Iridium Single Atoms into Bimetal Phosphides toward High-Efficiency Oxygen Evolution and Overall Water Splitting
No full textSingle atoms are superior electrocatalysts having high atomic utilization and amazing activity for water oxidation and splitting. Herein, this work reports a thermal reduction method to introduce high-valence iridium (Ir) single atoms into bimetal phosphide (FeNiP) nanoparticles toward high-efficiency oxygen evolution reaction (OER) and overall water splitting. The presence of high-valence single Ir atoms (Ir4+) and their synergistic interaction with Ni3+ species as well as the disproportionation of Ni3+ assisted by Fe collectively contribute to the exceptional OER performance. In specific, at appropriate Ir/Ni and Fe/Ni ratios, the as-prepared Ir-doped FeNiP (Ir-25-Fe16Ni100P64) nanoparticles at a mass loading of only 35 mu g cm(-2) show the overpotential as low as 232 mV at 10 mA cm(-2) and activity as high as 1.86 A mg(-1) at 1.5 V versus RHE for OER in 1.0 m KOH. Computational simulations confirm the vital role of high-valence Ir to weaken the adsorption of OER intermediates, favorable for accelerating OER kinetics. Impressively, a Pt/C||Ir-25-Fe16Ni100P64 two-electrode alkaline electrolyzer affords a current density of 10 mA cm(-2) at a low cell voltage of 1.42 V, along with satisfied stability. An AA battery with a nominal voltage of 1.5 V can drive overall water splitting with obvious bubbles released
Adsorption and immobilization of phosphorus from eutrophic seawater and sediment using attapulgite - Behavior and mechanism
No full textThe adsorption behavior of phosphorus on raw sediment (RS), attapulgite (AT), purified attapulgite (PAT) and AT/PAT-amended sediments conforms to the Langmuir, pseudo first-order kinetics and liquid film diffusion model. The adsorption process is spontaneous and monolayer adsorption, and the adsorption rate is mainly controlled by liquid film diffusion. The addition of attapulgite improved the adsorption capacity of phosphorus in the sediments of mariculture ponds. The results of long-term sediment core incubation showed that the average reduction rates of total phosphorus (TP) and soluble reactive phosphorus (SRP) in overlying water and SRP in pore water by adding 20% purified attapulgite (S/PAT20) were 62.11%, 70.83% and 56.32% respectively, and the phosphorus flux in sediments decreased by 53.81%. The addition of attapulgite reduces the risk of phosphorus release in sediments, and changes sediments from "source" to "pool". The specific surface area and pore volume of PAT increased to 203.254 cm(2)/g and 0.395 cm(3)/g respectively, but the phosphorus adsorption capacity was only increased by 2 times compared with AT (1431.3-2671.8 mg P/kg), indicating that the changes of mineral structure and chemical composition jointly determine the phosphorus adsorption effect. Adsorption mechanisms include physical adsorption, surface chemical precipitation, ligand effects, electrostatic attraction and ion exchange. Therefore, seeking modification methods with low energy consumption, low production cost, no damage to rod crystal, expansion of pore volume, increase of hydroxyl and other functional groups, and great retention of effective components are issues that need to be considered to improve the phosphorus adsorption capacity of attapulgite
Adsorption and immobilization of phosphorus from eutrophic seawater and sediment using attapulgite - Behavior and mechanism
No full textThe adsorption behavior of phosphorus on raw sediment (RS), attapulgite (AT), purified attapulgite (PAT) and AT/PAT-amended sediments conforms to the Langmuir, pseudo first-order kinetics and liquid film diffusion model. The adsorption process is spontaneous and monolayer adsorption, and the adsorption rate is mainly controlled by liquid film diffusion. The addition of attapulgite improved the adsorption capacity of phosphorus in the sediments of mariculture ponds. The results of long-term sediment core incubation showed that the average reduction rates of total phosphorus (TP) and soluble reactive phosphorus (SRP) in overlying water and SRP in pore water by adding 20% purified attapulgite (S/PAT20) were 62.11%, 70.83% and 56.32% respectively, and the phosphorus flux in sediments decreased by 53.81%. The addition of attapulgite reduces the risk of phosphorus release in sediments, and changes sediments from "source" to "pool". The specific surface area and pore volume of PAT increased to 203.254 cm(2)/g and 0.395 cm(3)/g respectively, but the phosphorus adsorption capacity was only increased by 2 times compared with AT (1431.3-2671.8 mg P/kg), indicating that the changes of mineral structure and chemical composition jointly determine the phosphorus adsorption effect. Adsorption mechanisms include physical adsorption, surface chemical precipitation, ligand effects, electrostatic attraction and ion exchange. Therefore, seeking modification methods with low energy consumption, low production cost, no damage to rod crystal, expansion of pore volume, increase of hydroxyl and other functional groups, and great retention of effective components are issues that need to be considered to improve the phosphorus adsorption capacity of attapulgite
