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    Electrically Switched Cesium Ion Exchange

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    This report discusses the results of work to develop Electrically Switched Ion Exchange (ESIX) for separations of ions from waste streams relevant to DOE site clean-up. ESIX combines ion exchange and electrochemistry to provide a selective, reversible method for radionuclide separation that lowers costs and minimizes secondary waste generation typically associated with conventional ion exchange. In the ESIX process, an electroactive ion exchange film is deposited onto. a high surface area electrode, and ion uptake and elution are controlled directly by modulating the potential of the film. As a result, the production of secondary waste is minimized, since the large volumes of solution associated with elution, wash, and regeneration cycles typical of standard ion exchange are not needed for the ESIX process. The document is presented in two parts: Part I, the Summary Report, discusses the objectives of the project, describes the ESIX concept and the approach taken, and summarizes the major results; Part II, the Technology Description, provides a technical description of the experimental procedures and in-depth discussions on modeling, case studies, and cost comparisons between ESIX and currently used technologies

    Refining and End Use Study of Coal Liquids

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    This report summarizes revisions to the design basis for the linear programing refining model that is being used in the Refining and End Use Study of Coal Liquids. This revision primarily reflects the addition of data for the upgrading of direct coal liquids

    Direct Aromaization of Methane

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    The thermal decomposition of methane offers significant potential as a means of producing higher unsaturated and aromatic hydrocarbons when the extent of reaction is limited. Work in the literature previous to this project had shown that cooling the product and reacting gases as the reaction proceeds would significantly reduce or eliminate the formation of solid carbon or heavier (Clo+) materials. This project studied the effect and optimization of the quenching process as a means of increasing the amount of value added products during the pyrolysis of methane. A reactor was designed to rapidly quench the free-radical combustion reaction so as to maximize the yield of aromatics. The use of free-radical generators and catalysts were studied as a means of lowering the reaction temperature. A lower reaction temperature would have the benefits of more rapid quenching as well as a more feasible commercial process due to savings realized in energy and material of construction costs. It was the goal of the project to identify promising routes from methane to higher hydrocarbons based on the pyrolysis of methane

    Direct Fast-Neutron Detection: A Progress Report

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    It is widely acknowledged that Mure neutron-detection technologies will need to offer increased performance at lower cost. One clear route toward these goals is rapid and direct detection of fast neutrons prior to moderation. This report describes progress to date in an effort to achieve such neutron detection via proton recoil within plastic scintillator. Since recording proton-recoil events is of little practical use without a means to discriminate effectively against gamma-ray interactions, the present effort is concentrated on demonstrating a method that distinguishes between pulse types. The proposed method exploits the substantial difference in the speed of fission neutrons and gamma-ray photons. Should this effort ultimately prove successful, the resulting. technology would make a valuable contribution toward meeting the neutron-detection needs of the next century. This report describes the detailed investigations that have been part of Pacific Northwest National Laborato@s efforts to demonstrate direct fast-neutron detection in the laboratory. Our initial approach used a single, solid piece of scintillator along with the electronics needed for pulse-type differentiation. Work to date has led to the conclusion that faster scintillator and/or faster electronics will be necessary before satisfactory gamma-ray discrimination is achieved with this approach. Acquisition and testing of both faster scintillator and faster electronics are currently in progress. The "advanced" approach to direct fast-neutron detection uses a scintillating assembly with an overall density that is lower than that of ordinary plastic scintillator. The lower average density leads to longer interaction times for both neutrons and gamma rays, allowing easier discrimination. The modeling, optimization, and design of detection systems using this approach are described in detail

    A Guidance Document for Kentucky's Oil and Gas Operations

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    This technical report is a summary of the progress made for "A Guidance Document for Kentucky's Oil and Gas Operators". During this quarter, the document received continued review and editing in an elec-tronic format to satisfy the United States Department of Energy (DOE). Comments received from oil and gas operators reviewing this document prompted contact to be made with the United States Environmental Protection Agency (USEPA) to develop an addendum section to provide better explanation of USEPA requirements for Class II injection wells in Kentucky

    Reactivation of an Idle Lease to Increase Heavy Oil Recovery through Application of Conventional Steam Drive Technology in a Low Dip Slope and Basin Reservoir in the Midway-Sunset Field, San Jaoquin Basin, California

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    A previously idle portion of the Midway-Sunset field, the ARCO Western Energy Pru Fee property, is being brought back into commercial production through tight integration of geologic characterization, geostatistical modeling, reservoir simulation, and petroleum engineering. This property, shut-in over a decade ago as economically marginal using conventional cyclic steaming methods, has a 200-300 foot thick oil column in the Monarch Sand. However, the sand lacks effective steam barriers and has a thick water-saturation zone above the oil-water contact. These factors require an innovative approach to steam flood production design that will balance optimal total oil production against economically viable steam-oil ratios and production rates. The methods used in the Class III demonstration are accessible to most operators in the Midway-Sunset field and could be used to revitalize properties with declining production of heavy oils throughout the region. In January 1997 the project entered its second and main phase with the purpose of demonstrating whether steamflood can be a more effective mode of production of the heavy, viscous oils from the Monarch Sand reservoir than the more conventional cyclic steaming. The objective is not just to produce the pilot site within the Pru Fee property south of Taft, but to test which production parameters optimize total oil recovery at economically acceptable rates of production and production costs

    POC-Scale Testing of Oil Agglomeration Techniques and Equipment for Fine Coal Processing

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    The objective of this project is to develop and demonstrate a Proof-of-Concept (POC) scale oil agglomeration technology capable of increasing the recovery and improving the quality of fine coal strearrts. Two distinct agglomeration devices will be tested, namely, a conventional high shear mixer and a jet processor. To meet the overall objective an eleven task work plan has been designed. The work ranges from batch and continuous bench-scale testing through the design, commissioning and field testing of POC-scale agglomeration equipment

    Technical Assistance in Review of Source Term-Related Issues of Advanced Reactors

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    The distribution of iodine in containment during an AP-600 design-basis accident was evaluated using models in the "TRENDS" code. The AP-6003BE accident sequmce calculations showed that a pH >7 was maintained for at least 30 days. Because the pH was maintained at this level, most of the iodine was in the form of iodid~ only 3 x 10-3% was present as aqueous 12, and only 1 x 10< `/0 was present as J in the vapor phase

    Development of a Gas-Promoted Oil Agglomeration Process

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    Further agglomeration tests were conducted in a series of tests designed to determine the effects of various parameters on the size and structure of the agglomerates formed, the rate of agglomeration, coal recovery, and ash rejection. For this series of tests, finely ground Pittsburgh No. 8 coal has been agglomerated with i-octane in a closed mixing system with a controlled amount of air present to promote particle agglomeration. The present results provide further evidence of the role played by air. As the concentration of air in the system was increased from 4.5 to 18 v/w% based on the weight of coal, coal recovery and ash rejection both increased. The results also show that coal recovery and ash rejection were improved by increasing agitator speed. On the other hand, coal recovery was not affected by a change in solids concentration from 20 to 30 w/w%

    Phase III: Implementation and Operation of the Repository

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    The metadata catalog was brought online for public access May 14, 1998. Since then dozens of users have registered and began to access the system. The system was demonstrated at the AAPG annual meeting in Salt Lake City and the EAGE (European Association of Geoscientists and Engineers) annual meeting in Leipzig, Germany. Hart Publications and PTTC "NetworkNews" have published articles about the metadata catalog, and articles for the AAPG Explorer and GSA Today are being developed. A back-up system at AGI headquarters was established. In support of the metadata catalog system, a leased-line Internet connection and two servers were installed. Porting of the GeoTrek server software to the new systems has begun. The back-up system will be operational during the 3 rd quarter of 1998 and will serve the NGDRS needs during periods when access to the site in Houston is down. Additionally, experimentation with new data types and deployment schemes will be tested on the system at AGI. The NGDRS has picked-up additional endorsements from the American Association of State Geologists, the MMS Outer Continental Shelf Policy Committee, and a new endorsement is being formulated by the AAPG Core Preservation Committee for consideration by the AAPG Executive Committee. The Texas Bureau of Economic Geology (BEG) is currently geocoding the well locations for the metadata catalog. Also, they have solicited proposals for the development of a core inventory control system that will work hand-in-hand with GeoTrek. A contract for that system will probably be given during the 3 rd quarter of 1998. The Texas Railroad Commission proposes to test the application of GeoTrek for accessing data in a joint project with the BEG. Several data transfer projects are underway. Vastar has committed to the transfer of 2D Appalachian seismic lines to the NDGRS clearinghouse. Receiving repositories have been identified and the final preparations are being made for transfer to these public repositories. Discussions have been initiated with the State of Oregon concerning listing their 400 oil and gas well and 50 geothermal well cores and logs on the metadata catalog. Additionally, discussions continue with the Stapleton Development Corporation concerning the transfer of facilities in Denver for use as a central core repository. A letter of intent for the facility's transfer is being reviewed

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