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    Application of Advanced Reservoir Characterization, Simulation, and Production Optimization Strategies to Maximize Recovery in Slope, and Basin Clastic Reservoirs, West Texas (Delaware Basin)

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    The objective of this Class 3 project is to demonstrate that detailed reservoir characterization of slope and basin clastic reservoirs in sandstones of the Delaware Mountain Group in the Delaware Basin of West Texas and New Mexico is a cost effective way to recover a higher percentage of the original oil in place through strategic placement of infill wells and geologically based field development. Project objectives are divided into two main phases. The original objectives of the reservoir-characterization phase of the project were (1) to provide a detailed understanding of the architecture and heterogeneity of two representative fields of the Delaware Mountain Group, Geraldine Ford and Ford West, which produce from the Bell Canyon and Cherry Canyon Formations, respectively, (2) to chose a demonstration area in one of the fields, and (3) to simulate a CO 2 flood in the demonstration area. The Bureau's industry partner for the initial Phase 1 of the project was Conoco, Inc.. After the reservoir characterization and simulation of an area at the northern end of the Ford Geraldine unit were completed, Conoco decided not to proceed to Phase 2, installation of a CO 2 flood in the demonstration area. This decision by Conoco provides an opportunity for a more extensive field demonstration in East Ford field, with Orla Petco as the industry partner. East Ford field is immediately adjacent to the Ford Geraldine unit and produces from the same Ramsey sandstone channel. Phase 1 of the project has been expanded to include reservoir characterization of East Ford field. This additional reservoir-characterization task provides an excellent opportunity to test the transferability of the geologic model and log-interpretation methods developed during reservoir characterization of the Ford Geraldine unit to another Delaware sandstone field. The objectives of the implementation phase of the project remain the same, to (1) apply the knowledge gained from reservoir characterization and simulation studies to increase recovery from a demonstration area, (2) demonstrate that economically significant unrecovered oil can be recovered by a CO 2 flood of the demonstration area, and (3) test the accuracy of reservoir characterization and flow simulation as predictive tools in resource preservation of mature fields. The goal is to develop a geologically designed CO 2 flood and well-completion program in a representative Delaware Sandstone field that can serve as a model for other fields in the play. Through technology transfer, the knowledge gained in this study can be applied to increase production from more than 100 other Delaware Mountain Group reservoirs

    UNI Signaling 4.0 Security Addendum: Call for Straw Ballot

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    The ATM Forum UNI 4.0 Security Addendum has undergone 4 revisions and has been without substantive modifications for 3 ATM Forurn meetings. This contribution is intended to assist the ATM Forum CS Working Group in the process of bringing BTD-CS-UNI-SEC-O1 .04 DIUFT to Straw Ballot. This effort applies equally to its companion documen~ BTD-CS-PNNI-SEC-O 1.02 DRAFT. BTD-CS-UNI-SEC-01 .04 DRAFT is an addendum to UNI 4.0 Signaling that describes the additional procedures needed of ATM signaling to support the signaling-based securily message exchange protocol, and its 4 basic security mechanisms, authentication, confidentiality, integrity and access control for ATM VC/VPs. These services are specified in detail in ATM Forurn document af-sec-0100.000, which is currently in Final Ballot. The remaining identified work for BTD-CS-UNI-SEC-01 .04 DRAFT includes the resolution of the TBD items in the draft, and a review of the sections of the ATM Forum Security Specification V 1.0 af-sec- 0100.000, that are specifically referenced by BTD-CS-UNI-SEC-O 1.04 DRAFT. In support of this effort, this contribution includes the relevant baseline text of the referenced sections of that Security Specification

    Advanced Direct Liquefaction Concepts for PETC Generic Units - Phase II

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    Reported here are the results of Laboratory and Bench-Scale experiments and supporting technical and economic assessments conducted under DOE Contract No. DE-AC22-91PC9104O during the period October 1, 1996 to December 31, 1996. This contract is with the University of Kentucky Research Foundation which supports work with the University of Kentucky Center for Applied Energy Research, CONSOI+ Inc., LDP Associates, and Hydrocarbon Technologies, Inc. This work invoives the introduction into the basic two stage liquefaction process several novel concepts which include dispersed lower-cost catalysts, coal cleaning by oil agglomeration, and distillate hydrotreating and dewaxing

    Task 1.16 - Enhanced Mobility of Dense Nonaqueoius-Phase Liquids (DNAPLs) Using Dissolved Humic Acids

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    Chlorinated solvent contamination is widespread across the U.S. Department of Energy (DOE) complex and other industrial facilities. Because of the physical properties of dense nonaqueous-phase liquids (DNAPLs), current treatment technologies are generally incapable of completely removing contamination from the source area. Incomplete removal means that the residual DNAPL will persist as a long-term source of groundwater contamination. When DNALPs occur in the subsurface, they resist remediation, owing to low water volubility, high viscosity and interracial tension, and microbial recalcitrance. Because of their high density and polarity, they are usually found sorbed to aquifer solids or in pools on impermeable materials. Surfactants have been used with some success to reduce interracial tension between the aqueous and organic phases and improve volubility of DNAPLs. However, surfactants are expensive and toxic and exhibit an oxygen demand. An alternative is the use of dissolved humic acids in improving DNAPL mobilization and solubilization. Humic acids, a. natural form of organic carbon, are abundant, inexpensive, and nontoxic; biodegrade slowly (low oxygen demand); and have excellent mobilization properties. The present work is to establish the feasibility of using humates for enhancing DNAPL remediation

    Functions and Requirements for a Waste Conveyance Jet Pump for the Gunite and Associated Tanks at Oak Ridge National Laboratory

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    Since the mid 1940's, the U.S. Department of Defense (DOD) and the U.S. Department of Energy (DOE) have conducted research and development activities at the Oak Ridge National Laboratory (ORNL) in support of urgent national interests in the fields of nuclear weaponry and nuclear energy. Some of these activities resulted in radiologically hazardous waste being temporarily deposited at ORNL in Waste Area Grouping 1. At this location, waste is stored in several underground storage tanks, awaiting ultimate final disposal. There are tanks of two basic categories; one category is referred to as the "gunite" tanks, and the other category is `associated" tanks. The ORNL Gunite and Associated Tanks Treatability Study (GMT-TS) project was initiated in fiscal year (FY) 1994 to support a record of decision in selecting from seven different options of technologies for retrieval and remediation of these tanks. This decision process is part of a Comprehensive Environmental Response, Compensation, and Liability Act of 1980 (CERCLA), Remedial investigation and Feasibility Study (R1/FS) presented to DOE and the Tennessee Department of Environment and Conservation (TDEC). As part of this decision process, new waste retrieval technologies were evaluated at the 25-ft diameter gunite tanks in the North Tank Farm

    Valley-Fill Sandstones in the Kootenai Formation on the Crow Indian Reservation, South-Central Montana

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    Subsurface data continues to be collected, organized, and a digital database is being prepared for the project. An ACCESS database and PC-Arcview is being used to manage and interpret the data. Well data and base map data have been successfully imported into Arcview and customized to meet the needs of this project. Log tops and other data from about ¾ of the exploration wells in the area have been incorporated into the data base. All of the four 30" X 60" geologic quadrangles have been scanned to produce a digital surface geologic data base for the Crow Reservation and all are nearing completion. Formal technical review prior to publication has been completed for all the quadrangles; Billings, Bridger; Hardin, and Lodge Grass. Final GIS edits are being made before being forwarded to the Bureau's Publications Department. Field investigations were completed during the third quarter, 1997. With the help of a student field assistant from the Crow Tribe, the entire project area was inventoried for the presence of valley-fill deposits in the Kootenai Formation. Field inventory has resulted in the identification of nine exposures of thick valley-fill deposits. These appear to represent at least four major westward-trending valley systems. All the channel localities have been measured and described in detail and paleocurrent data has been collected from all but one locality. In addition, two stratigraphic sections were measured in areas where channels are absent. One channel has bee traced over a distance of about 60 miles and exhibits definite paleostructural control. An abstract describing this channel has been submitted and accepted for presentation at the Williston Basin Symposium in October, 1998

    Task 6.7.2 - Improved Corrosion Resistance of Alumina Refractories

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    In order to increase the efficiency of advanced coal-fired power systems, higher working, fluid temperatures must be reached. To protect some system surfaces, they are covered with corrosion-resistant refractories. Corrosion is the degradation of material surfaces or grain boundaries by chemical reactions with melts, liquids, or gases, causing loss of material and, consequently, a decrease in strength of the structure. In order to develop methods of reducing corrosion, the microstructure that is attacked must be identified along with the mechanism and rates of the attack. Once identified, methods for reducing corrosion rates can be developed. In order to determine the reactivity of a refractory to a slag, several tests have been developed. The most common are the cup slag test, drip slag test American Society for Testing and Materials ([ASTM] C768), gradient slag test, rotary slag test (ASTM C874)and the dip-and- spin test. Among these tests, the cup slag test is the only static test method and the most commonly used. Previous static testing at the University of North Dakota Energy & Environmental Research Center (EERC) has shown that alumina-based castable refractories are among the least expensive and most corrosion-resistant materials for the highest-temperature coal-fired power system applications

    High Temperature High Pressure Thermodynamic Measurements for Coal Model Compounds

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    The overall objective of this project is to develop a better thermodynamic model for predicting properties of high-boiling coal derived liquids, especially the phase equilibria of different fractions at elevated temperatures and pressures. The development of such a model requires data on vapor-liquid equilibria (VLE), enthalpy, and heat capacity which would be experimentally determined for binary systems of coal model compounds and compiled into a database. The data will be used to refine existing models such as UNIQUAC and UNIFAC. The flow VLE apparatus designed and built for a previous project was upgraded and recalibrated for data measurements for thk project. The modifications include better and more accurate sampling technique and addition of a digital recorder to monitor temperature, pressure and liquid level inside the VLE cell. VLE data measurements for system benzene-ethylbenzene have been completed. The vapor and liquid samples were analysed using the Perkin-Elmer Autosystem gas chromatography

    Task 2.10 - Advanced Sampling and Analysis of Fine Particulates

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    The objectives of this study are to develop a sampling method to capture the fine particulate and classiyi the particulate according to their size and chemistry. When developing the sampling method, two criteria need to be met: 1) the particulate are randomly dispersed on the sampling media and 2) the sampling media can be put directly into a scanning electron microscope (SEM) for analysis to prevent any alteration of the particulate. Several methods for the sampling and analysis of fine particulate are to be tested. Each sampling test will be analyzed using the FPT technique for collecting the size, shape, and chemical composition of 1500 to 2000 individual fine particulate. The FPT data will be classified using cluster analysis and principal component analysis to provide a classification system for these particles. As reported previously, particulate samples were collected using the advanced hybrid particulate collector (AHPC) on the inlet port of the particulate test combustor (PTC) when the Absaloka coal was burned in early April. The samples were collected at the inlet rather than the outlet port because of the loading that was expected and the temperature at which the PTC was run. Samples at the inlet were expected to see a much greater particulate loading than at the outlet because of the efficiency of the particulate collection device on the PTC. Also, polycarbonate filters cannot withstand temperatures above 230oC for long periods of time; therefore, a quick loading time was required. The samples were briefly scanned and photographed using the SEM to determine the best particulate loading time. The particulate were too close together on the 20- and 30-second polycarbonate filters to be able to analyze individual particles. The particle dispersion on the vitreous carbon substrate appeared to be the best of the four samples. Aerosols were produced from pure 1.0 M aqueous solutions of NaCl, Na2S04, (NHq)2SOo, NHqNO~, and K20 (KOH) using a Tri-Jet Model 3460 aerosol generator and collected by direct impingement on a vitreous carbon substrate. Because NaCl is the normal aerosol produced with the generator, it was briefly examined using SEM to determine the degree of dispersion. Good dispersion with nearly all particulate size below 2 pm and the majority in the O.1-pm range was achieved with a substrate collection time of 2-3 minutes. The brief examination also demonstrated that the sample could be introduced directly into the SEM for analysis with no prior carbon coating or other preparation and that charging of the sample was minimal

    Task 2.0 - Air Quality Assessment, Control, and Analytical Methods Subtask 2.11 - Lactic Acid FGD Additives From Sugar Beet Wastewater

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    Organic buffers maintain the pH of the scrubber slurry in flue gas desulfurization (FGD) as the SO2 dissolves at the air-liquid interface. Inexpensive acids with an appropriate pKa are required for this application. The pKa of lactic acid (3.86) is between that of the interface and the recirculating slurry and will make soluble calcium ion available in large amounts. Currently lactic acid is somewhat expensive for this use, but this project will develop a new source of inexpensive lactate. Microbial action during the storage and processing of sugar beets forms lactic acid in concentrations as high 14 g/L in the processing water. The concentrations are lower than those occurring in conventional fermentation production of lactic acids, but since a considerable amount of water is involved in the processing of sugar beets in the Red River Valley (1 million gallons/day), a substantial amount of lactic acid or calcium lactate could be recovered as a by- product for use in FGD and other applications

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