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    Determination of mineral abundances in samples from the Exploratory Studies Facility, Yucca Mountain, Nevada, using x-ray diffraction

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    Tuff samples collected from the Exploratory Studies Facility (ESF) were X-rayed to estimate relative mineral abundances. X-ray analysis was performed on sub-samples of specimens collected from both the Single Heater Test (SHT) and Drift Scale Heater Test (MT) that were used for thermomechanical measurements, as well as samples collected from cores retrieved from boreholes in the Drift Scale Test Area. The abundance of minerals that could affect the behavior of the host rock at repository relevant temperatures is of particular interest. These minerals include cristobalite, which undergoes a phase transition and volume change at elevated temperature (-250 {degree}C), and smectite and clinoptilolite that can dehydrate at elevated temperature with accompanying volume reduction. In addition, the spatial distribution of Si02 polymorphs and secondary minerals may provide evidence for deducing past fluid pathways. The mineral abundances tabulated here include data reported previously in three milestone reports but reanalyzed, as well as previously unreported data

    Increasing Waterflood Reserves in the Wilmington Oil Field Through Improved Reservoir Characterization and Reservoir Management

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    The objectives of this quarterly report are to summarize the work conducted under each task during the reporting period January - March 1997 and to report all technical data and findings as specified in the "Federal Assistance Reporting Checklist". The main objective of this project is the transfer of technologies, methodologies, and findings developed and applied in this project to other operators of Slope and Basin Clastic Reservoirs. This project will study methods to identify sands with high remaining oil saturation and to recomplete existing wells using advanced completion technology

    Feasibility of Optimizing Recovery and Reserves from a Mature and Geological Complex Multiple Turbidite Offshore California Reservoir Through the Drilling and Completion of a Trilateral Horizontal Well

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    The main objective of this project is to devise an effective redevelopment strategy to combat producibility problems related to the Repetto turbidite sequences of the Carpinteria Field. The lack of adequate reservoir characterization, high-water cut production, and scaling problems have in the past contributed to the field's low productivity. To improve productivity and enhance recoverable reserves, the following specific goals are proposed: ° Develop an integrated database of all existing data from work done by the former ownership group. ° Expand reservoir drainage and reduce sand problems through horizontal well drilling and completion. ° Operate and validate reservoirs conceptual model by incorporating new data from the proposed trilateral well. ° Transfer methodologies employed in geologic modeling and drilling multilateral wells to other operators with similar reservoirs

    Economic Recovery of Oil Trapped at Fan Margins Using High Angle Wells Multiple Hydraulic Fractures

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    This project attempts to demonstrate the effectiveness of exploiting thin-layered, low-energy deposits at the distal margin of a prograding turbidite complex through the use of hydraulically fractured horizontal or high-angle wells. The combination of a horizontal or high-angle well and hydraulic fracturing will allow greater pay exposure than can be achieved with conventional vertical wells while maintaining vertical communication between thin interbedded layers and the wellbore. A high-angle well will be drilled in the fan-margin portion of a slope-basin clastic reservoir and will be completed with multiple hydraulic-fracture treatments. Geologic modeling, reservoir characterization, and fine-grid reservoir simulation will be used to select the well location and orientation. Design parameters for the hydraulic-fracture treatments will be determined, in part, by fracturing an existing test well. Fracture azimuth will be predicted by passive seismic monitoring of a fracture-stimulation treatment in the test well using logging tools in an offset well

    Task 2.3 - Review and Assessment of Results From the Comprehensive Characterization of Toxic Emissions From Coal-Fired Power Plants

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    To help meet the requirements of the 1990 Clean Air Act Amendments, the U.S. Department of Energy (DOE) sponsored Phase I of a study entitled "Comprehensive Characterization of Toxic - Emissions from Coal-Fired Power Plants" in 1992. Final reports which detail air toxic emissions from eight power plants (nine conilgurations) were completed by the contractors. The Energy & Environmental Research Center (EERC) served as an independent third-party reviewer of these reports; it has completed the activities as outlined for the initial review process and has prepared two reports. The fiist report, entitled "A Comprehensive Assessment of Toxic Emissions from Coal-Fired Power Plants: Phase I Results from the U.S. Department of Energy Study" was published in September 1996 and is available to the public and private sectors through the U. S. Department of Energy (DOE) Federal Energy Technology Center (FETC) at Pittsburgh. This report surnmar izes and evaluates the stack emission data. The second report prepared by the EERC, entitled "A Comprehensive Assessment of Toxic Emission from Coal-Fired Power Plants: Statistical Correlations from the Combined DOE and EPRI Field Test Data," details empirical correlations derived horn the Phase I DOE data and the Electric Power Research Institute (EPIU) PISCES (Power Plant Integrated Systems: Chemical Emissions Studies) data. The objective of the project was to provide an independent review of the Phase I data, evaluate the scientific validity of the conclusions, identify significant correlations between emissions and fuel or process parameters, compare the data with available data from EPRI studies, make recommendations for future studies, and complete a combined report that summarizes Phase I, Phase II, and EPRI findings

    C02 Huff-n-Puff Process in a Light Oil shallow Shelf Carbonate Reservoir

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    The principal objective of this CO2 Huff-n-Puff (H-n-P) project is to determine the feasibility and practicality of the technology in a waterflooded shallow shelf carbonate environment. The results of parametric simulation of the CO2 H-n-P process, coupled with the Central Vacuum Unit (CVU) reservoir characterization components will be used to determine if this process is technically and economically feasible for field implementation. The technology transfer objective of the project is to disseminate the knowledge gained through an innovative plan in support of the Department of Energy's (DOE) objective of increasing domestic oil production and deferring the abandonment of shallow shelf carbonate (SSC) reservoirs. Tasks associated with this objective are carried out in what is considered a timely effort for near-term goals

    In Situ Void Fraction and Gas Volume in Hanford Tank 241-SY-101 as Measured with the Void Fraction Instrument

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    The void fraction instrument (WI) was deployed in Tank 241-SY-101 three times in 1998 to confm and locate the retained gas (void) postulated to be causing the accelerating waste level rise observed since 1995. The design, operation, and data reduction model of the WI are described along with validation testing and potential sources of uncertainty. The test plans, field observations and void measurements are described in detail, including the total gas volume calculations and the gas volume model. Based on 1998 data, the void fraction averaged 0.013 i 0.001 in the mixed slurry and 0.30 ~ 0.04 in the crust. This gives gas volumes (at standard pressure and temperature) of 87 t 9 scm in the slurry and 138 ~ 22 scm in the crust for a total retained gas volume of221 *25 scm. This represents an increase of about 74 scm in the crust and a decrease of about 34 scm in the slurry from 1994/95 results. The overall conclusion is that the gas retention is occurring mainly in the crust layer and there is very little gas in the mixed slurry and loosely settled layers below. New insights on crust behavior are also revealed

    Task 2.8 - Mercury Speciation and Capture in Scubber Solutions

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    U.S. Environmental Protection Agency (EPA) investigation into health risks associated with mercury emissions from utility steam generators, municipal waste combustion units, and other sources was mandated by the Clean Air Act Amendments (CAAA) of 1990. In anticipation of mercury emission regulation, attention has been focused on quantification of mercury emissions, which require verifiable sampling and analytical techniques. Several sampling and analytical methods are currently under the final stages of development as well as a variety of emission control methods. In particular, wet scrubber systems designed for S2 control in coal-fired utilities have been targeted for mercury control. Conventional wet-scrubbers remove mercury in a variety of soluble oxidized forms. Oxidized mercury is highly water-soluble and can be removed by scrubber slurry, theoretically limited only by gas-film mass transfer. However, since some oxidized mercury forms such as HgClz are borh soluble and volatile, the final fate of mercury trapped in scrubber solutions is unclear. Elemental mercury is not water-soluble, remaining in the vapor state at temperatures through pollution control devices and exiting the stack into the environment. However, notable exceptions to this rule exist. Depending on the type of mercury-sampling method used, an increase ofs 10% in elemental mercury concentrations across wet scrubbers has been metiured but is yet unconllrmed. Also, significant amounts of elemental mercury (metallic form) have been removed during wet scrubber maintenance. In addition, questions concerning 1) the initial speciation between oxidized and elemental forms of mercury in flue gas from coal- fired boilers and 2) the effects of scrubber slurry composition and pH on the mercury species have been raised

    Overview of the Target Systems for the Spallation Neutron Source

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    The technologies that are being utilized to design and build the target systems for a state-of-the-art accelerator- based neutron source, the Spallation Neutron Source (SNS), are discussed. Emphasis is given to the technology issues that present the greatest challenges. The present facility configuration, ongoing analysis, and planned research and development program are also described

    Quarterly Technical Progress Report

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    Methane oxidative coupling experiments were conducted in a porous gamma alumina membrane reactor using Mn-W-Na/SiOz catalyst, and its performance was compared with a packed reactor. By varying the helium flow rate and keeping the temperature, methane flow rate, and oxygen flow rate constant, the membrane reactor gave 10% higher Cz yield and 30% higher C2 selectivity than the co-feed reactor operated at the same methane conversion. At similar C2 yield and C2 selectivity, the methane conversion of the membrane reactor was 15% lower than that of a co-feed reactor. By varying the oxygen flow rate and keeping the temperature, methane flow rate, and helium flow rate constant, at the same methane conversion, the membrane reactor gave about 3% higher C2 yield and C2 selectivity than the co-feed reactor. Higher helium flow rate gave higher C2 selectivity and yield, whereas changing methane flow rate did not significantly affect the reactor performance

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    SciTec Connect (Office of Scientific and Technical Information - OSTI, U.S. Department of Energy)
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