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    Multiple Mantle Melting and Metasomatism during the Initial Stages of Subduction: Multi-Geochemical and Os-Isotope Evidence from Well-Preserved Kızıldağ Ophiolite, southern Türkiye

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    The processes governing ophiolite formation and evolution remain incompletely understood. The K & imath;z & imath;lda & gbreve; ophiolite, a well-preserved remnant of the Neo-Tethyan oceanic lithosphere in the Anatolian region, southern T & uuml;rkiye, offers critical insights into subduction-related processes and geodynamics. This study presents new element data for mineral and whole-rock samples, combined with Re-Os isotopic compositions of mantle peridotites and associated crustal rocks and extrusives. Petrographic observations identify two distinct groups of peridotites: (1) those with very low modal clinopyroxene, interpreted as highly depleted harzburgites and preserving primary mineral assemblages, and (2) depleted harzburgites containing secondary clinopyroxene with elevated trace element contents, inferred to have crystallized from percolating melts and thus reflecting metasomatic modification. Spinel and orthopyroxene compositions indicate 17-25% degrees of partial melting, with evidence for melting in both garnet and spinel stability fields. However, mineral and whole-rock compositions also record subsequent cryptic and modal metasomatism. Crustal rocks and extrusives exhibit geochemical signatures transitional between fore-arc basalts and boninites, consistent with subduction initiation settings. Variations in Os isotope ratios (187Os/188Os) in crustal rocks further reveal melt-rock interactions and the incorporation of radiogenic Os from subducted oceanic crust. The integration of petrographic, geochemical, and isotopic data supports a four-stage tectonic model for subduction initiation and mantle wedge evolution, consistent with global models proposed for supra-subduction zone (SSZ) ophiolites, particularly those of the Tethyan domain. These findings provide new constraints on mantle melting, metasomatism, and subduction initiation processes and contribute to a broader understanding of SSZ mantle evolution in both regional and global contexts

    Stochastic Inversion-Driven Petrophysical Modelling in Sub-Tuning Reefal Carbonates: Soğucak Formation, Thrace Basin, Türkiye

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    Seismic inversion plays a critical role in populating subsurface properties into geomodel; however, its effectiveness is often constrained by the resolution limits of seismic data. This study evaluates the effectiveness of stochastic versus deterministic acoustic-impedance inversion for estimating total porosity (Φtotal), effective porosity (Φe) and permeability (K) in the complex reefal carbonates of the Soğucak formation, Deveçatağı oil field—northwestern Thrace Basin, Türkiye—whose thickness ranges from 2 to 57 m. The wedge model indicates a tuning thickness of 60 m in Soğucak formation which limits the vertical resolution of the deterministic inversion that directly affects the geomodel resolution. To address this challenge, a stochastic inversion was performed to resolve beds below the tuning thickness, using a high-resolution 1 millisecond (ms) vertical sampling grid and producing non-unique, fine-layered impedance realizations. Petrophysical relationships were established using 75 core plugs showing strong porosity–permeability trends that were cross-validated with wireline logs. These relationships were applied to acoustic-impedance volumes derived from both deterministic and stochastic inversion. Correlations at well locations used in the model are naturally higher due to constraints from acoustic-impedance logs; therefore, we emphasized blind-well correlations to assess predictive performance at locations without well control. Blind-well tests at W-2, W-4, W-6 and W-11 demonstrate valid predictive capability, with stochastic inversion achieving correlations of 0.65–0.73 compared to 0.45–0.52 for deterministic inversion, effectively resolving sub-tuning thickness beds and reliably predicting porosity and permeability. By overcoming the resolution limitations of deterministic inversion, stochastic inversion supported by robust petrophysical relationships—when applicable—provides a reliable and field-proven tool that can be adapted to carbonate reservoirs in diverse geological settings worldwide

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