IR@NEIST - North East Institute of Science and Technology (CSIR)
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    339 research outputs found

    Sulphate behaviour from dissolution of gypsum in organic acids

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    The solubility of gypsum in organic acids namely acetic, oxalic, tartaric and succinic acids at low temperature (3

    Cleaning of Indian coals by agglomeration with xylene and hexane

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    A laboratory scale agglomeration process has been undertaken for cleaning Indian coals using oils namely, xylene and hexane. Maximum organic matter recovery for xylene has been found to be 91.9% whereas with hexane, the value is 54.7% on a dry basis. The highest ash rejection values with xylene (90.7%) and with hexane (89.7%) are almost same. Promising results for rejection of metals (Fe, Mg and Zn) have been observed. It has been found that xylene is more selective than hexane for the agglomeration process. Knowledge gained from this study will be helpful for technological advancement of this kind of work

    Novel synthesis of active metal oxide surface from a self-organising system of inorganic solids

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    Self-organising aqueous suspension of layers of cationic montmorillonite and anionic mixed metal layered hydroxides �MMLH. after thermal treatment at about 5008C gives active and well-dispersed layers of metal oxides over montmorillonite matrix exhibiting enhanced reactivity with gaseous reactants. Increased absorption of H2S by ZnO supported on montmorillonite matrix is given as an exampl

    Rhodium(I) carbonyl complexes of triphenylphosphine chalcogenides and their catalytic activity

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    Rhodium(I) carbonyl complexes [Rh(CO)2ClL] where L = Ph3PO, Ph3PS and Ph3PSe, were synthesized and characterized by elemental analysis, i.r. and by 1H-, 13C- and 31P-n.m.r. spectroscopy. The m(CO) band frequencies in the complexes follow the order: Ph3PO > Ph3PS > Ph3PSe, in keeping with the hard/soft nature of the interactions. The complexes undergo oxidative additions with electrophiles such as MeI, PhCH2Cl and I2 to give, e.g. [Rh(CO)(COMe)ClIL] which react with PPh3 to give trans-[Rh(CO)Cl(PPh3)2]. The catalytic activity of the [Rh(CO)2ClL] complexes in carbonylation of MeOH is higher than that of the well-known [Rh(CO)2I2]ÿ specie

    Adsorption of Cr(VI) by layered double hydroxides

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    Adsorption of Cr�VI. by various uncalcined and calcined layered double hydroxides �LDH. of Mg 13Al, Ni 13Al and Zn 13Cr types was investigated. Adsorption of Cr2O72y through ion exchange in uncalcined LDH is slower in rate and smaller in amount than in calcined one where the adsorption occurs via rehydration. The nature and content of bi- and trivalent metal ions in LDH influence the adsorption. Calcined Mg 13Al LDH with higher Al3q content in the precursor structure shows higher adsorption capacity. Adsorption is higher in the Mg 13Al LDH than in Ni 13Al and Zn 13Cr LDH. A two-step first-order rate kinetics was observed for the adsorption process which follows the Freundlich-type adsorption isotherm. The explanation of adsorption phenomenon has been supported by X-ray diffraction patterns. The pH of initial Cr2O72y solution has no affect on adsorption by calcined LDH. Release of Cr2O72y from the adsorbed product depends upon the type of anion in the aqueous phase and CO32y being the most effective ion. Calcination of the Cr2O72y adsorbed product up to 12508C has not resulted in the formation of Cr-immobilized phase

    A protocol for micropropagation of Alpinia galanga

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    Emerging buds of rhizome of Alpinia galanga Willd produced shoots and roots simultaneously when cultured in MS medium supplemented with kinetin 3.0 mg

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    IR@NEIST - North East Institute of Science and Technology (CSIR)
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