International Journal of Innovation in Mechanical Engineering and Advanced Materials (IJIMEAM)
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THE EFFECT OF ADDITION GREEN INHIBITOR D-GALACTOSE ON CORROSION RATE OF ALUMINUM ALLOY 5052 IN SULFURIC ACID (H2SO4) MEDIA
Get PDFAluminum alloy 5052 (Al5052) is one of the metals used as a bipolar plate in a Proton Exchange Membrane Fuel Cell (PEMFC) due to has its light mass and being easy to form, and, has high conductivity and resistivity properties. This material is prone to corrosion and current knowledge to protect its surface is currently lacking. The product of PEMFC produces electrical energy, hot steam (313 – 353 K), and water. These conditions have an impact on the degraded bipolar plate caused by the acidic nafion membrane. This increases the risk of corrosion on the cathode side of the bipolar plate. Coating with a green inhibitor using the electrophoretic deposition technique (EPD) is one way to deal with the corrosion that occurs. The analysis method used electrochemical with potentiodynamic polarization techniques, electrochemistry impedance spectroscopy (EIS), Fourier-transform infrared spectroscopy (FTIR) and scanning electron microscopy (SEM). In this study, green inhibitor D-galactose was used with a concentration of 0.5 – 1.5 g and an, EPD time of 15 – 45 minutes in 0.5 M sulfuric acid (H2SO4) media pH 1-4. Potentiodynamic polarization analysis at the lowest corrosion current value (Icorr) at demonstrates (the inhibitor concentration of 1.5 g with an and EPD time of 45 minutes) resulted corrosion rate of Al5052 before EPD was 0.0075 mmPY while the corrosion rate of Al5052 after EPD was 0.0041 mmPY with (inhibitors efficiency 45.2%). The FTIR spectrum, broad peak appeared in the range of 3000-3600 cm-1, which refers to the formation of hydrogen bonding of hydroxyl group. Methyl group of D-galactose also appear on 2918 cm-1 and 2850 cm-1 which attributed to =CH2 asymmetric stretch and −CH3 symmetric stretch, respectively. Carbonyl group on 1500 – 1700 cm-1 represent C=O bond of amide, and aldehyde. Peak 1097 – 1035 cm-1 which attributed to C-O were connected to the secondary and primary alcohols. The resistance value for Al5052 before and after EPD are 1.2 kΩ/cm2 after and 2.2 kΩ/cm2, respectively. Here we find that the resistance increases with the increasing concentration and time of EPD. The results cross section Al5052 within average 29.8 μm, and morphology with SEM Al5052 before EPD showed pitting corrosion. On the other hand, the image of Al5052 inhibitor coating 1.5 gr with EPD of 45 minutes shows a smooth surface and visible black lumps, suggesting Al5052 is successfully reduced a corrosion rate by the D-galactose. Our simple and robust method inferred a protection route towards a viable and physically stable green inhibitors
PLANNING STUDY OF HYBRID POWER PLANT SOLAR PV-DIESEL GENERATOR ON KODINGARE ISLAND, SINJAI REGENCY
Get PDFKodingare Island is located in Pulau Sembilan District, Sinjai Regency, one of nine islands. Currently, most people still rely on conventional energy from diesel power plants. The reason is that this island does not yet receive an electricity supply from the electricity grid due to the geographical limitations of the archipelago. It is known that the most potential renewable energy source on Kodingare Island is solar energy, with a potential for solar radiation reaching 5.86 kWh/m2/day. This research aims to analyze an innovation that combines PV and solar, where PV acts as the main electricity generator, while solar functions as a backup and additional energy source. The method used in this research uses simulation methods, layout modeling, and financial analysis using HOMER Pro simulation software to determine the potential and performance of hybrid power plants and SketchUp Pro software to produce three-dimensional layouts and economic and feasibility values obtained through financial analysis. Technical aspects include producing an electrical energy system of 37,029 Wh/year, consisting of PV of 32,981 Wh/year and solar of 4,048 Wh/year with energy consumption of 33,850 Wh/year. The required fuel consumption is 2,086 L/year, with excess electricity of 931 kWh/year and renewable energy penetration of 89.1%. From an economic perspective, planning this hybrid power system requires an investment of 258.290.000 IDR, O&M costs of 19.350.600 IDR, and the cost of energy value of 1,352/kWh IDR. In contrast, from the feasibility aspect of planning a hybrid electric power system, it is said to be feasible because it produces a Net Present Value of 9,870,151 IDR, is more significant than zero, the Profitability Index is 1.03 greater than one, the Internal Rate of Return is 8.90% greater than the credit interest rate of 8.43% and the Payback Period required for return of capital is nine years nine months
COMPARATIVE STUDY USING LOW COST ACETIC AND SULFURIC ACIDS ON ROASTING AND PEROXIDE FOR LEACHING PROCESS TO EXTRACT PB FROM GALENA
Get PDFExtraction of heavy metals from mineral concentrate applying leaching acids is a major issue due to simple, fast, and economical process. This article aims to present the application of acetic acid and sulfuric acid for lead (Pb) extraction from galena concentrate applying roasting (600oC and 60 min.) and peroxide oxidant (0.5 M) for 60 min. leaching process. Nowadays, lead has been broadly applied for batteries, besides for PVC tubes, chemicals, paint color, and alloys for joint. The peroxide increases the percentage of Pb extraction. This study shows the effect of acid concentrations (1.0 M, 1.5 M, and 2.0 M), temperatures (30, 50, and 70oC), and stirring speed (200, 400, and 600 rpm) on Pb extraction from galena. A particle size of galena ≤ 200 mesh after roasting has been used for leaching process. AAS has been used to determine Pb concentration in solution after leaching process. This study shows that acetic acid is a better leaching agent rather than sulfuric acid due to lead sulfate precipitation. Optimization result shows leaching with acetic acid achieved 35.64 ppm Pb extraction using 2.0 M acetic acid, 50oC, and stirring speed of 200 rpm. This study used low-cost acids as leaching agent for Pb recovery that can be viewed as a preliminary breakthrough in heavy metal recovery. The simple leaching technique looks promising for future application on heavy metal separation from mining mineral
EFFECT OF SiO2 AND ZnO NANOPARTICLES TO INCREASE REFRIGERATION MACHINE PERFORMANCE
Get PDFIn this investigation, the impact of silicon dioxide (SiO2) and zinc oxide (ZnO) nanoparticles on the performance of a refrigeration machine system was systematically examined. The focus was on evaluating the coefficient of performance (COP) concerning the utilization of a polyolester (POE) lubricant, R600a refrigerant, and distinct nanoparticles (SiO2 and ZnO) within the refrigeration system. The nanoparticles were individually introduced into the R600a refrigerant in masses of 0.5 g, 1.0 g, and 1.5 g. The experimental outcomes demonstrated a noteworthy enhancement in COP with the addition of nanoparticles. Specifically, the introduction of 1.5 g of SiO2 resulted in a substantial increase of 25.88% in COP, marking it as the most influential dosage. Similarly, the addition of 1.0 g of ZnO led to a significant COP increase of 13.6%, representing the optimal quantity for ZnO. Furthermore, the inclusion of 1.5 g of SiO2 brought about a remarkable reduction in energy consumption, with a decrease of 25.58%, while 1.5 g of ZnO resulted in a notable 16.28% decrease in energy consumption. The experimental configuration involved the use of 20 g of refrigerant and 500 ml of POE lubricant. Comparative analysis demonstrated that the refrigeration system incorporating nanoparticles outperformed the conventional R600a refrigeration system devoid of nanoparticles. This study contributes valuable insights into the potential enhancements in refrigeration system efficiency through the strategic incorporation of SiO2 and ZnO nanoparticles, offering a promising avenue for optimizing the performance of refrigeration technology
MORPHOLOGICAL AND PROPERTIES OF PORTLAND-COMPOSITE CEMENTS WITH CLASS C FLY ASH
Get PDFPortland-composite cements (PCC) were prepared with partial substitution of 5 to 25% of class C fly ash, obtained from East Java steam power plant. Properties of the composite cements was evaluated, through the setting time (initial and final) and compressive strength (3, 7, and 28 days) compared with control PCC. Setting time is retarded in Portland-composite cements with higher fly ash content. The retardation is highest in PCC with substitution of 25% fly ash. Lower compressive strength is obtained after 3 and 7 days of curing for PCC with 5-25% fly ash substitution in comparison with control cement, since pozzolanic reaction still did not show its effect. After 28 days, compressive strength was higher than that for control cement because pozzolanic reaction show its effect, highlighted by compressive strength increase of PCC substituted by 5% and 10% fly ash, 16.48 MPa and 16.52 MPa, respectively. This attributed to the differences in the pozzolanic activity of the applied fly ash. The compressive strength increase was explained by Scanning Electron Microscope (SEM), which shows that PCC with substitution of 10% fly ash had more Tobermorite presented compared to control cement
ADVANCING ENERGY CONSERVATION AND SUSTAINABLE BUILDING PRACTICES THROUGH COMPREHENSIVE THERMAL-COOLING LOAD ANALYSIS IN AIRPORT BUILDING
Get PDFThe global discussion on conserving energy's importance has persisted, paralleling the surge in energy use over two decades. This rise presents challenges for local energy supply to diverse buildings. Designing energy-efficient buildings has become crucial in reducing energy usage and promoting sustainability. This research comprehensively analyzed and assessed thermal-cooling loads within an airport building using Panasonic software. The investigation primarily focuses on evaluating cooling load and thermal dynamics within the airport facility, emphasizing enhancing energy efficiency, and ensuring thermal comfort. Additionally, duct sizing design was conducted to achieve a comprehensive HVAC installation. From the result of the investigation, it was found that the highest Cooling Load at the airport occurs at 4:00 PM, aligning with the peak temperature resulting from heat transmitted into the building, reaching 263,591 Watts for the Airport Lounge and 82,202 Watts for the Luggage Room. Building energy management must be undertaken to minimize the energy consumption during that period. By thoroughly examining thermal-cooling loads within an airport building, this research contributes to decision-making for designing and operating HVAC systems, thereby advancing sustainable building practices
BIODIESEL PRODUCTION FROM WASTE FISH CANNING OIL USING COCOPEAT ASH CATALYST
Get PDFBiodiesel is an environmentally friendly alternative fuel for diesel engines. The research studies the extraction process of biodiesel from waste produced by a fish canning factory using a heterogeneous catalyst known as cocopeat ash. The experiment was designed utilizing a completely randomized design with two factorial treatments and four repetitions. The primary factor under investigation was the composition of the catalyst, specifically 3%, 5%, and 7% w/v methanol. The second factor examined was the reaction time of either 60 minutes or 120 minutes. Data analysis revealed variations in density, viscosity, acid number, and Free Fatty Acids (FFA) in fish oil before and after refinement. The treatment that yielded the highest results was A3B2, featuring a catalyst composition of 7% and a reaction time duration of two hours, which achieved an impressive biodiesel yield of 81%. Moreover, several parameters tested for compliance with SNI-04-7182-2015 standards showed positive outcomes. These parameters include a density value measuring 876.3 kg/m³, the flash point around 160°C, iodine number reaching 16.36 g/100g, and heating value 47.47 MJ/Kg
MECHANICAL STUDY OF 9CR-SS316L-1MO MATERIAL FOR CLADDING NUCLEAR FUEL POWER REACTORS
Get PDFIn this research, SS316 steel and modified 9Cr-1Mo steel were developed. The aim is to analyze the results of the hardness test, impact test, bending test, and microstructure. The Mo element was chosen because it has a relatively small microscopic cross-section of the neutron, which is 2.6 barn. The element Mo is in the same periodic period as Zr and Nb, so that the mechanical properties and so on are not much different. In this study, samples of SS316L steel and modified 9Cr-1Mo steel were made. Samples material of 90% SS316L + 9% Cr + 1% Mo were melted by electric arc melting. Tempering was carried out after the smelting process was completed. The sample consisted of 6 pieces, 1 sample did not receive tempering treatment while the other 5 samples received tempering treatment at 100°C, 200°C, 300°C, 400°C, and 500°C. The samples were tested using various methods including Rockwell hardness test, impact test, microstructure test, bending test, and examination of other properties of the material samples. Hardness, impact, and bending test results as well as the samples microstructure were analyzed. The highest decrease in hardness value was in specimen 1 (non-treatment) which was 21.33 HRc and the lowest decrease was in specimen 6 (heat treatment at 500°C) which was 16.66 HRc. For the results of the impact energy test (EI) with an average value, there was not too much difference, namely the highest value was 1.0034 joules/mm2 in specimen 2 (heat treatment at 100°C) and the lowest value was 1.0020 joules/mm2 in specimen 6 (heat treatment at 500°C). The results of the microstructure test showed that the ferrite and pearlite content is still present in the test object. The highest bending test result in sample 6 with 500°C tempering had a maximum load-bearing strength of 1050 Newton so that the bending strength was 7875 kgf/cm2 and the lowest result was in sample 1 without tempering having a maximum load-bearing strength of 670 Newton so that the bending strength was 5025 kgf/ cm
DESIGN OF A 10 TONS OVERHEAD CRANE WITH 21 METERS SPAN USING FINITE ELEMENT METHOD
Get PDFA crane is a lifting equipment widely used to move cargo, construction sites, storage, and unload. The type of crane that is commonly used in industrial environments is the overhead crane. The overhead crane functions as a lifting device. Besides that, it also works as a load transfer tool even though the load being moved is limited to an environment that is not too large (indoor) at PT. A overhead crane is designed to overcome the problem of moving material in the mold storage area due to the area's expansion and the addition of 5-7 tons of mold material. Therefore, proper design is needed so the overhead crane can function properly. The design method uses the VDI 2221 or Finite Element with Solid works software. The results of the structure obtained are double box girder type girders with dimensions p = 21 m, t = 1224 mm, and l = 600 mm. The deflection results are 13.75 mm, and the runway uses steel profile I with dimensions 400 x 200 x 8 x 13 mm, with a deflection value at the runway stem of 5.6 mm. The type of wire rope used is type 6 x 37, with a diameter of 28 mm. The stress that occurs in the steel rope is 4306.1 Kg, less than the maximum allowable tensile stress of 8009.4 Kg. The single hook type with a hook diameter of 120 mm is made of material S45C. The tensile stress on the hook is 0.88 Kg, and the result is smaller than the allowable tensile stress of 12.72 Kg. The pulley diameter is 630 mm, the drum diameter is 604.9 mm, and the drum length is 279 mm
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