579 research outputs found
Protectiecurven voor de FM-band van centrale antenne-inrichtingen
No full textProtectiecurven voor de FM-band van centrale antenne-inrichtingen zijn grafieken welke het toelaatbare niveau van intermodulatieprodukten geven als functie van het gewenste FM-signaal en het stoorprodukt. Dit afstudeerverslag baseert zich op het opleggen van.de CCIR ruis- en single frequentie-eisen aan het hoorbare signaal, er worden dus voor elk stoorprodukt twee curven gegeven. De intermodulatieprodukten worden ingedeeld naar de modulatie van de bronsignalen, FM-geluid en restzijband-beeld. De resultaten zijn ondergebracht in hoofdstuk 9, dat los van de rest van het verslag gelezen kan worden.Applied SciencesElectrical EngineeringLaboratorium voor Transmissie van Informati
Sediment management and the renewability of floodplain clay for structural ceramics
No full textThe Netherlands has vast resources of clay that are exploited for the fabrication of structural ceramic products such as bricks and roof tiles. Most clay is extracted from the so-called embanked floodplains along the rivers Rhine and Meuse, areas that are flooded during high-discharge conditions. Riverside clay extraction is-at least in theory-compensated by deposition. Based on a sediment balance (deposition versus extraction), we explore the extent to which clay can be regarded as a renewable resource, with potential for sustainable use. Beyond that, we discuss the implications for river and sediment management, especially for the large engineering works that are to be undertaken to increase the discharge capacities of the Rhine and Meuse. Extraction rates are based on production statistics for clay, as well as those for fired end-products. Deposition rates are estimated from published and unpublished geological data (clay volumes and thicknesses, datings, etc.) and from morphological modeling studies. Comparisons between extraction and deposition are made at three different time-space scales: (1) long term (post-1850)/large scale (all Dutch floodplains), (2) present/large scale, and (3) present/site scale. The year 1850 is relevant because it approximately marks the beginning of the current, fully engineered river systems, in which depositional processes are constrained by dikes and groynes. As the Industrial Revolution began in the same period, post-1850 sediments can be identified by their pollution with heavy metals. (1) We estimate the post-1850 clay volume in situ at about 0.20 km(3), and the total extracted volume in the same period at about 0.17 km(3). This puts the net long-term average deposition rate of clay at similar to 1.3 million m(3)/year and the corresponding extraction rate at similar to 1.1 million m(3)/year. (2) Current accumulation is approximately 0.4 million m(3)/year and expected to increase, and current extraction is about 0.7 million m(3)/year and expected to decrease. (3) Clay extraction creates a depression that has an increased sediment-trapping efficiency. This local effect is not considered explicitly in large-scale morphological modeling. Based on maximum observed sedimentation rates, we estimate that replenishment of a clay site takes in the order of 150 years. As clay extraction lowers some 0.5 km(2) of floodplain yearly, a surface area of approximately 75 km(2) would be required for sustainable clay extraction. This is about 1/6 of the total surface area of the embanked floodplains. On the long term, clay extraction from the embanked floodplain depositional environment has been sustainable. At strongly decreasing deposition rates, the ratio between extraction and replenishment seems to have shifted towards unsustainable. However, current sedimentation is estimated conservatively. The site-scale approach suggests that, even if extraction would currently exceed deposition, this could be resolved with sediment management, that is, with site restoration measures aimed at higher sediment-trapping efficiency. Our results have implications for river engineering, especially where substantial digging is involved (floodplain lowering, high-discharge bypass channels, obstacle removal). First, this inevitably affects the clay resources that we studied, while resource sterilization should be avoided. Secondly, the effect that any form of digging has on subsequent sedimentation-increased rates-relates to long-term river maintenance. We conclude that floodplain clay is a renewable resource, especially if managed accordingly. Beyond that, we established that clay extraction is a significant, lasting factor in floodplain evolution along the Rhine and Meuse Rivers. The interests of the extractive industry and river managers could be served jointly with sediment management plans that are based on sediment-budget analyse
Understanding the changes in the circular dichroism of light harvesting complex II upon varying its pigment composition and organization.
No full textIn this work we modeled the circular dichroism (CD) spectrum of LHCII, the main light harvesting antenna of photosystem II of higher plants. Excitonic calculations are performed for a monomeric subunit, taken from the crystal structure of trimeric LHCII from spinach [Liu, Z. F., Yan, H. C., Wang, K. B., Kuang, T. Y., Zhang, J. P., Gui, L. L., An, X. M., and Chang, W. R. (2004) Nature 428, 287-292]. All of the major features of the CD spectrum above 450 nm are satisfactorily reproduced, and possible orientations of the Chl and carotenoid transition dipole moments are identified. The obtained modeling parameters are used to simulate the CD spectra of two complexes with altered pigment composition: a mutant lacking Chls a 611-612 and a complex lacking the carotenoid neoxanthin. By removing the relevant pigment(s) from the structure, we are able to reproduce their spectra, which implies that the alteration does not disturb the overall structure. The CD spectrum of trimeric LHCII shows a reversed relative intensity of the two negative bands around 470 and 490 nm as compared to monomeric LHCII. The simulations reproduce this reversal, indicating that it is mainly due to interactions between chromophores in different monomeric subunits, and the trimerization does not induce observable changes in the monomeric structure. Our simulated spectrum resembles one of two different trimeric CD spectra reported in literature. We argue that the differences in the experimental trimeric CD spectra are caused by changes in the strength of the monomer-monomer interactions due to the differences in detergents used for the purification of the complexes
Tunneling times and excited state interactions between chromophores
No full textThis Thesis consists of two related parts. The first part (Chapters 2 and 3) presents the results of a fundamental theoretical study of the interpretation of quantum mechanics, and particularly of tunneling processes. Part two (Chapters 4, 5, and 6) describes the experimental results of spectroscopic investigations of quantum mechanical interactions between chromophores, which may play a role in electron transport by means of tunneling.The formulation of the quantum theory at the beginning of the twentieth century resulted in a scientific revolution. The impact of this theory on our physical world picture is still visible today. The quantum theory is impressively successful in its predictions of the outcomes of experiments, but the interpretation of the theory is still shaky. The predictions of quantum mechanics about the outcome of experiments are detailed and testable, but the meaning of the theory for quantum systems, in which no measurement has taken place is not clear. Various interpretations exist. Two of these are compared in Chapter 2. The first is the orthodox or Copenhagen interpretation, which was advocated by the Copenhagen-based Niels Bohr. His followers claimed that, in the orthodox interpretation, nothing can be said about the properties of systems if no suitable measurement has been carried out. The alternative is the causal interpretation of quantum mechanics, in which a particle, e.g. an electron, has a well-defined position and velocity at each instant of time independent of a measurement act. The causal theory does not assign a special role to the observer. In the causal interpretation the location as a function of time amounts to trajectories. The two interpretations are empirically equivalent, i.e. they predict the same experimental outcomes.In Chapter 2 the meaning of the two interpretations is clarified by the notion of tunneling time. Tunneling is the quantum mechanical phenomenon that a particle can cross a barrier even if its energy is less than the barrier energy. The time a particle takes to tunnel is the tunneling time. Time is a confusing concept: quantum theory appears not to know how to handle this topic. Time appears in the quantum mechanical formulae as a parameter, and not as an operator that corresponds to an observable quantity. Since an unambiguous time operator is missing, it is interesting to see what different interpretations have to say about tunneling times. It is strictly speaking impossible to define tunneling times in the orthodox interpretation because of the lack of a clear time operator, of which the expectation value can be observed by experiment. In the causal interpretation, every trajectory corresponds to a possible path of an electron. The density functions determine the probability that particles move on particular trajectories. This is how the stochastic character of quantum mechanics is accounted for in this interpretation. The transmission time is defined as the time spent inside the barrier by the electrons that eventually cross the barrier. The average transmission time can be defined by means of the trajectories, both in the case of stationary wave functions and in that of time-dependent, Gaussian wave packets. The Gaussian wave packets travel from minus infinity to plus infinity. On the way they meet potential barriers, which cause them to be reflected or transmitted. The process by which an electron moves from one chromophore to another can be described as tunneling because of the high potential barrier formed by the medium between the chromophores. In this Thesis the experimental media used are polymer films and apolar solutions. The model described in Chapter 2 is generally used in the literature but appears not to be applicable for a system of two chromophores and a tunneling electron, because electrons belonging to chromophores neither start in infinity nor go to infinity. A better model, a double potential well, is used in Chapter 3. The conclusion of Chapter 2 is that the transmission time can be defined in the causal interpretation when time-dependent wave packets are used.Chapter 3 illustrates the preceding by tunneling of a particle from one potential well to another passing a potential barrier. This model is the so-called double potential well. Examples are primary charge separation in the photosynthetic reaction center and in artificial model systems of chromophores in solutions and polymer films. The latter two cases are investigated spectroscopically in this Thesis. In these molecular systems, effective electron transport between chromophores after absorption of light takes place, yielding charge separation, i.e. the formation of chromophore cations. During their transport between natural or artificial chromophores, the released electrons often have to pass weak conducting media, corresponding to high potential barriers. If the energy of the electron exceeds the energy of the potential barrier, electron transport can be explained by classical theories. However, if the energy of the electron falls below the energy of the potential barrier, this is no longer possible. The transport mechanism is then understood as quantum mechanical tunneling. Experimental proof of tunneling has been found at low temperatures in photosynthesis.In Chapter 3 the chromophores and the tunneling electrons are described by double potential wells. Each well represents a chromphore and the space between the molecules a potential barrier. The formalism of the causal interpretation is applied to define a transmission time. The transmission time can be found using trajectories. An alternative method provides the average transmission time without calculating the trajectories. Arrival time distribution functions are defined and these are used to determine the average arrival time of the tunneling electrons at the entrance and at the exit of the barrier. Because arrival time distribution functions and hence both average arrival times and transmission times are not determined in an experimental context, we conclude that these definitions of transmission times are meaningless in the orthodox interpretation. The question posed at the end of Chapter 3 is whether, and if so how, these transmission times are experimentally accessible.The theoretical models developed in Chapters 2 and 3 are too simple to be extrapolated to real systems, such as electron transport between an electron donor and an acceptor, one of which is excited by light. Intermolecular interactions between excited electron donor molecules and ground state surrounding molecules cannot be neglected in chromophore films and solutions with relatively high concentrations of chromophores. These excitonic interactions should be included in adequate descriptions of electron transfer. Chapters 4, 5, and 6 describe these interactions using absorption and emission spectroscopy. In Chapter 4 a theoretical description of the absorption characteristics of chromophores in disordered films is given. At low concentrations, chromophores in films are mainly monomers. On statistical grounds, however, we conclude that some molecules are close enough together to form dimer-like structures, concentration pairs with characteristic absorption spectra. The presence of these concentration pairs influences the emission characteristics of chromophore films as well. When monomer electrons are excited by the absorption of photons, the electrons might return to the ground state, giving off their energy as fluorescence. Light energy can also be transferred to neighboring concentration pairs, in which case the fluorescence is quenched.The aim of Chapter 4 is to estimate the influence of potential quenchers in the vicinity of excited monomers and to predict the influence of these quenchers on the absorption spectra. The transfer of energy from monomers to concentration pairs, the so-called Förster transfer, takes place over quite large distances (1-5 nm). Statistics can be used to calculate the number of quenchers in particular concentrations of chromophores. In the literature it is assumed that two monomers that form a concentration pair are randomly oriented with respect to each other. If these pairs consisted of randomly oriented monomers and all fluctuations are taken into account, it appears on theoretical grounds that there would not be enough quenchers to describe the experimental changes. Because most chromophores are elongated or pancake-like, they are not randomly oriented but exhibit preferential orientations. These preferential orientations increase the efficiency of fluorescence quenching and theory and experiment are thereby reconciled. An analytical expression of the spectral changes compared to monomeric spectra of randomly oriented dimers is presented. To describe the interaction between chromophores that have one dominant transition dipole moment, a point dipole exciton model is used. To enhance the description of the spectral changes, homogeneous and inhomogeneous line broadening and monomer-to- monomer distance fluctuations should be taken into account. Inclusion of these factors in the model gives rise to the conclusion that the dimer spectra are broadened compared to the monomeric spectra and that the broadening is stronger at the blue end than at the red end of the spectra. However, to detect the blue-shifted spectral profile of randomly oriented dime-like samples, the concentration needs to be so high that isolated dimers cannot be observed. Then, simulation of the dimers becomes impossible, and all mutual interactions must be taken into account. Modeling of these interactions shows that the blue shift is not visible, and that only a broadening of the absorption spectra with respect to the monomeric spectra remains.Chapter 5 describes spectral changes that result from changes in the concentration changes of elongated Erythrosin-B (Ery B) chromophores in polyvinylalcohol (PVA) films. At low concentrations, monomers are numerous,giving monomeric absorption spectra. At higher concentrations, measurements of fluorescence quenching show formations of pairs, which are not visible in the absorption spectra. At higher concentrations still, a broadening of the absorption spectra is observed, as predicted by the theory developed in Chapter 4. Further increase of the concentrations induces order of the chromophores. Preferential orientations for dimers, trimers, and tetramers are determined by use of molecular mechanics. Structures that are energetically favorable according to these calculations are selected. The mutual orientations of these oligomers are used to simulate absorption spectra using an exciton model. All structures show dominant blue-shifted spectra, like the experimental spectra. At very high concentrations, the experimental peak shifts to the red end of spectra. Red shifts can be explained theoretically, by simulation of very densely packed molecules.Chapter 6 describes absorption spectra of four porfyrin dimers in toluene solutions. Porphyrines are pancake-like molecules containing two perpendicular transition dipole moments. The experimental absorption spectra are explained with the aid of simple exciton models. To account for the two perpendicular transition dipole moments, the exciton model presented in Chapter 5 is extended. The orientations and rotational freedom of the monomers comprising a dimer explain the spectral changes in the absorption spectra.This Thesis uses the quantum theory at various levels. Both tunneling and the excitonic interactions between molecules involved in tunneling processes can be described only by the quantum theory. This theory is well equipped to explain experimental data but at the same time appears to yield more questions than answers. This Thesis reports on the fascinating interplay of question and answer between the quantum mechanics of molecular processes and our knowledge of observable processes</p
New Approaches to Political Economy: Discussion Forum
No full textThe discussion on ‘New Approaches to Political Economy (PE)’ gives us a state-of-the-art overview of the main theoretical and conceptual developments within the concept of political economy. Thereby, it invites us to broaden our knowledge regarding manifold novel approaches, which make use of more complex methods to study the less stable, less predictable, but faster changing realities of smaller or bigger geographical regions. In this discussion forum, Amable takes a closer look on the nature of ‘conflict’ as well as the relationship between conflict and institutional change or stability. After stressing the relevance of comparative capitalism in general, Regan also zooms in on the political conflicts in comparative political economy from three different perspectives (electoral politics, organized interest groups and business-state elites), where he finds new avenues, tensions and research agendas are opening up. From a different perspective, Avdagic reviews the broad developments in the field of political economy with respect to the supply and demand side of redistributive policy. Thereafter, Baccaro and Pontusson sketch an alternative ‘growth model perspective’, which puts demand and distribution at the center of the analysis. Finally, Van der Zwan analyses the usefulness of financialization studies for the study of (comparative) political economy.Bruno Amable: The Political Economy of Institutional Change Aidan Regan: The New Political Economy of Comparative Capitalism Sabina Avdagic: The Political Economy of Redistribution: Advances and Challenges Lucio Baccaro, Jonas Pontusson: Shifting Focus: Why CPE Should Engage (Again) with the Politics of Growth Natascha Van der Zwan: The New Political Economy of Financializatio
De verdwenen voorspelbaarheid. Het Nederlandse Europabeleid tijdens en na de Koude Oorlog; een vergelijking
No full textDe verdwenen voorspelbaarheid. Het Nederlandse Europabeleid tijdens en na de Koude Oorlog; een vergelijking
No full textReilen en zeilen van 't kofschip
No full textZie ook [Kees van der Zwan,] “Wie bedacht ’t kofschip?”, Onze Taal 67 (1998), no. 6, 157.In deze bijdrage wordt aannemelijk gemaakt dat de Nederlandse taalkundige L.A. te Winkel (1809-1868) de bedenker van de bekende ezelsbrug "'t kofschip" is geweest
- …
