1,720,956 research outputs found
The Phase Behavior of Asphaltene + Polystyrene + Toluene Mixtures at 293 K
Full text linkPolymers of various types are added to crude oils and oil products to prevent wax deposition, break water-in-oil emulsions, reduce drag in pipelines and to stabilize asphaltenes. In mixtures where a polymer does not adsorb on colloids, two stable liquid phases can arise due to depletion flocculation. Asphaltenes in heavy oils and toluene mixtures form sterically stabilized colloidal particles. In this work, the addition of a non-adsorbing polymer (polystyrene) to C5 Maya asphaltene + toluene mixtures was investigated experimentally and theoretically. As concentrated asphaltene + toluene mixtures are opaque to visible light, phase volumes and compositions were detected using ultrasound. The sensors comprised two commercial 64 element phased-array acoustic probes. The operation of the view cell, and kinetic and equilibrium data processing procedures were validated using mixtures of methanol + alkanes. Acoustic speed and attenuation profiles were found to provide independent measures of phase separation. At equilibrium, acoustic speed profiles are uniform in each phase with a step change at the interface. Acoustic wave attenuation profiles exhibit a sharp peak/spike at liquid-liquid interfaces. Mixtures of asphaltenes + polystyrene + toluene are shown to exhibit liquid-liquid phase behavior over broad ranges of composition. This is the first report of liquid-liquid phase behavior for such mixtures. One phase is asphaltene rich and the other phase is polystyrene rich. Liquid-liquid critical points were also identified along the liquid-liquid/liquid phase boundary for mixtures with two mean molar masses of polystyrene.
Compositions of co-existing phases were computed using phase volume variations along dilution lines, acoustic speed data and a mass balance model. A parameter was introduced to improve the agreement between calculated and experimental speeds of sound. The results of the model indicate that more than half of the asphaltenes, by volume, participate in the depletion flocculation process. Phase compositions were measured independently using UV-visible spectrophotometry. The nominal size of asphaltene colloidal particles participating in the phase separation mechanism was estimated by comparing calculated phase boundaries with the experimental phase diagram. The estimated size of asphaltene colloidal particles is in agreement with the expected size of asphaltenes in toluene mixtures obtained exogenously
Confined Boiling Heat Transfer Over a Saturated Porous Structure
Full text linkAn experimental investigation was performed to study the confined boiling heat transfer characteristics over a saturated porous structure using distilled water as the working fluid. A thin stainless steel resistive foil stretched between two copper electrodes was used to heat a saturated porous plate with an effective pore size of 50 gm. The temperature distribution on the foil heater was measured using a high speed thermal imaging camera. The effect of the gap height between the heater and the porous plate on the heat transfer was investigated for gap heights ranging from 0 um to 1000 um and for heat fluxes ranging from 11.7 kW/m2 to 58.3 kW/m2. It was observed that the highest heat transfer rate was obtained at a gap height of approximately 600 pm. The main heat transfer mechanism is thought to be confined boiling in the small gap between the heating surface and the saturated porous structure. It was observed that the effect of the subcooled liquid temperature did not have a significant effect on the heat transfer. The effect of the pore size in the porous plate was investigated by repeating the measurements with a porous plate of 200 gm pore size. It was observed that the thermal resistance for the plate with a 200 gm pore size was significantly higher than the plate with 50 gm pores for gaps less than 300 gm. At a larger gap height of 600 gm, similar heat transfer performances were obtained for the two porous media.ThesisMaster of Applied Science (MASc
Impact of Two-Phase Flow Pattern on Solvent Vapour Extraction
No full textSolvent Vapour extraction (Vapex) is a promising technology for in-situ heavy oil recovery from oil sands deposits. The prediction of oil recovery rates requires fundamental understanding of the pore-scale mechanisms and their impact on mass transfer and oil production. To bridge the gap between pore-scale mechanisms and macro scale recovery, a dynamic pore-network model for two-phase flow with mass transfer is developed. The impact of pressure gradient on two-phase flow pattern, mass transfer and oil production are investigated. It is found that at high capillary numbers, in viscous dominated flow, dissolved oil is moved in intermittent liquid clusters to the outlet of the network. This mechanism of interface renewal maintains a steep solvent mole fraction gradient at the interface and enhances mass transfer, resulting in high oil production. In capillary dominated flow, capillary fingering with low mass transfer and oil production are observed
Impact of Two-Phase Flow Pattern on Solvent Vapour Extraction
No full textSolvent Vapour extraction (Vapex) is a promising technology for in-situ heavy oil recovery from oil sands deposits. The prediction of oil recovery rates requires fundamental understanding of the pore-scale mechanisms and their impact on mass transfer and oil production. To bridge the gap between pore-scale mechanisms and macro scale recovery, a dynamic pore-network model for two-phase flow with mass transfer is developed. The impact of pressure gradient on two-phase flow pattern, mass transfer and oil production are investigated. It is found that at high capillary numbers, in viscous dominated flow, dissolved oil is moved in intermittent liquid clusters to the outlet of the network. This mechanism of interface renewal maintains a steep solvent mole fraction gradient at the interface and enhances mass transfer, resulting in high oil production. In capillary dominated flow, capillary fingering with low mass transfer and oil production are observed
Going Beyond Counting First Authors in Author Co-citation Analysis
Full text linkThe present study examines one of the fundamental aspects of author co-citation analysis (ACA) - the way co-citation
counts are defined. Co-citation counting provides the data on which all subsequent statistical analyses and mappings
are based, and we compare ACA results based on two different types of co-citation counting - the traditional type that
only counts the first one among a cited work's authors on the one hand and a non-traditional type that takes into
account the first 5 authors of a cited work on the other hand. Results indicate that the picture produced through this non-traditional author co-citation counting contains more coherent author groups and is therefore considerably clearer. However, this picture represents fewer specialties in the research field being studied than that produced through the traditional first-author co-citation counting when the same number of top-ranked authors is selected and analyzed. Reasons for these effects are discussed
Variations on the Author
Full text link“Variations on the Author” discusses two of Eduardo Coutinho’s recent films (Um Dia na Vida, from 2010, and Últimas Conversas, posthumously released in 2015) and their contribution to the general question of documentary authorship. The director’s filmography is characterized by a consistent yet self-effacing form of authorial self-inscription: Coutinho often features as an interviewer that rather than express opinions propels discourses; an interviewer that is good at listening. This mode of self-inscription characterizes him as an author who is not expressive but who is nonetheless markedly present on the screen. In Um Dia na Vida, however, Coutinho is completely absent form the image, while Últimas Conversas, on the contrary, includes a confessional prologue that moves the director from the margins to the center of his films. This article examines the ways in which these works stand out in the filmography of a director who offers new insights into the notion of cinematic authorship
Appropriate Similarity Measures for Author Cocitation Analysis
Full text linkWe provide a number of new insights into the methodological discussion about author cocitation analysis. We first argue that the use of the Pearson correlation for measuring the similarity between authors’ cocitation profiles is not very satisfactory. We then discuss what kind of similarity measures may be used as an alternative to the Pearson correlation. We consider three similarity measures in particular. One is the well-known cosine. The other two similarity measures have not been used before in the bibliometric literature. Finally, we show by means of an example that our findings have a high practical relevance.information science;Pearson correlation;cosine;similarity measure;author cocitation analysis
Dispelling the Myths Behind First-author Citation Counts
Full text linkWe conducted a full-scale evaluative citation analysis study of scholars in the XML research field to explore just how different from each other author rankings resulting from different citation counting methods actually are, and to demonstrate the capability of emerging data and tools on the Web in supporting more realistic citation counting methods. Our results contest some common arguments for the continued
use of first-author citation counts in the evaluation of scholars, such as high correlations between author rankings by first-author citation counts and other citation
counting methods, and high costs of using more realistic citation counting methods that are not well-supported by the ISI databases. It is argued that increasingly available digital full text research papers make it possible for citation analysis studies to go beyond what the ISI databases have directly supported and to employ more
sophisticated methods
- …
