1,906,427 research outputs found
Face To Face by Ethan Ash
No full text4 track music album by Ethan Ash. Rob Toulson credited Producer and Recording Engineer
Characterization of ash derived from combustion of paper mill waste sludge: Comparison with municipal solid waste incinerator ash
Full text linkFly ash derived from incineration of Malaysian paper mill waste sludge (PMWS) was physically and chemically characterized in order to determine its potential toxicity as well as its application as cement replacement material. The results were compared with results obtained from similar characterization on Malaysian municipal solid waste incineration (MSWI) bottom ash. Principal analyses conducted include particle size distribution, elemental analysis, toxicity characteristic leaching procedure (TCLP) as well as thermogravimetric, x-ray diffractometry and FTIR analyses. TCLP result indicated that both the PMWS and MSWI ashes should not be classified as hazardous wastes in terms of heavy metal leachability, since leachable copper, cadmium, lead and nickel concentrations were detected below the stipulated leachability limits. Both ashes could be reused as cement replacement materials since both contained SiO2 which is one of the main building components in cement and concrete utilizations. Nonetheless, PMWS ash could be more suitable as a cement replacement material as compared to MSWI ash, as the former had significantly smaller particle size distribution and lower organic content
The compressive strength of fly ash concrete and its mineralogy
No full textIncludes bibliographical references.The use of fly ash as a cement extender in portland cement concrete is well established. Strict requirements are set for the fly ash on its physical properties and chemical composition to ensme its successful application as a partial replacement material for cement. An investigation was undertaken into the effectiveness and properties of a high carbon clinker ash when used as a cement extender at a 30 direct mass to mass substitution for portland cement. The clinker ash came from the Van Eck power station in Windhoek, Namibia and was milled to pass a 63micron sieve. For comparison fly ashes from the Escom power stations of Lethabo, Duvha and Matla were used. Both concrete and pure paste specimens were prepared for the evaluations
Utilization of Coal Fly Ash as CO Gas Adsorbent
Full text linkThis research focused on coal fly ash fabricated as CO adsorbent. Coal fly ash having grain size of 325 mesh was characterized by XRF, XRD and SEM-EDX. Physical activation was done at temperatures of 5000C, 5200C, 5400C, 5600C, 5800C and 6000C. Chemical activation was undertaken by mixing between fly ash and NaOH with mass ratio of 1: 1.2 with subsequent heating at 7500C for 1 h and followed by washing the specimens until pH=7. The samples were dried at 1000C for 1 h. The major constituents of unactivated coal fly ash are Fe, Ca, K, Si and Al in the form of quatz and anorthite. The chemical activation led to reduce the amount of quartz or increase the amount of anorthite. Physical activation does not affect the amount of minerals. Surface area of coal fly ash with physical activation at temperature 5400C and chemical activation is 32.444 m²/g (BET)
The use of fly ash to stabilise low concentrations of mercury in the environment
No full textThe work investigates if fly ash from Ekibatuz Power Plant can stabilise low concentrations of mercury in the environment and prevent it from becoming soluble in water and in preventing it transforming into the methylated form. The work demonstrates that mercury bound to fly ash from the coal fired 4,000 Mwatt Ekibatuz Power Plant in Kazakhstan is fairly stable at pH levels that are found in most natural water bodies. The adsorption behavior followed the Freundlich adsorption model. The adsorption capacity of the fly ash for Hg (II) was found to be 3.0 mg.g-1 of dry ash, the adsorption equilibrium being reached after 96 hours. The adsorption kinetic and studied at pHs between 6 and 8. The study showed that between the pH range of 6.0 and 8.0 bound mercury on wet and air dried ash was fairly resistant to leaching with the maximum leaching being 0.292 mg.l-1 and 0.14 mg.l-1 for the wet and air dried fly ash, respectively, with leachate at pH 7.0. Laboratory studies of the stability of the adsorbed mercury on fly ash when mixed with organic rich sediments in an anaerobic environment at pH 7.0 showed that despite ideal conditions for methylation to take place after 8 weeks, the concentration in solution was less than 2 ?g.l-1. The studies showed that unburnt carbon contained in raw fly ash was the key factor for adsorption reaction. The results indicated that fly ash from the 4,000 Mwatt Ekibatuz Power Plant in Kazakhstan fired with high ash medium volatile coal can be used to stabilise low concentration of mercury in the natural aquatic environmen
Volcanic ash beds in the Waikato district
No full textThis report lies somewhere between the "pathfinder" variety and the completed account for the reason that the results of detailed mapping and identification are still being prepared for publication. For the younger beds less than 36,000 years we now know both the source and the distribution, but for the older ashes commonly referred to as the Hamilton ash, sources are unknown and a knowledge of distribution restricted to the Waikato district. The principal source is the Okataina volcanic centre with Taupo as a subsidiary (Healy, 1964; Thompson, 1964 :44), and on this information, current mapping into the Waikato district proceeds from the east.
Under the circumstances of partly completed work it seems prudent to discuss relevant ash beds already known (Vucetich and Pullar, 1963:65-6; 1964:45-6) to introduce briefly current work by the same authors and by W. T. Ward, and then to relate all of this to previous work portrayed in a soil-forming ash shower map by Taylor (1953)
Prediction of ash deposition for biomass combustion and coal/biomass co-combustion
Full text linkIn this thesis, a model that couples a reduced alkali kinetic mechanism for alkali sulphate formation during biomass combustion with an ash deposition model using computational fluid dynamics (CFD) techniques has been presented. Starting with a detailed gas-phase kinetic mechanism for the alkali chemistry, a systematic reduction procedure has been performed using a sensitivity analysis to reduce the reaction mechanism to a level that can be implemented into a CFD calculation. An ash deposition model that takes into consideration the ash-sticking probability and the condensation of potassium salts has been developed. The reduced mechanism and the deposition model developed are implemented into a CFD model to predict ash depositions in a 10 MWth biomass grate furnace.
Also, a CFD model to predict the deposition rates for the co-combustion of coal with biomass has been developed. This deposition model is based on the combined sticking probabilities of the ash particle viscosity and the melting behaviour of the ash particles. A Numerical Slagging Index (NSI) is also employed to estimate the degree of the sintering of the deposits. Experimental data from the Entrained Flow Reactor (EFR) at Imperial College, London, have been used to validate the models. The predicted results from both the ash deposition models agreed with the experimental measurements, and the NSI has successfully ranked the investigated coal-biomass mixtures according to their degree of sintering
Evaluation of Fly Ash in Water Reduced Paving Mixtures;MLR-84-07, June 1985
Full text linkFly ash was used to replace 15% of the cement in C3WR and C6WR concrete paving mixes containing ASTM C494 Type A water reducin9 admixtures. Two Class C ashes and one Class F ash from Iowa approved sources were examined in each mix. When Class C ashes were used they were substituted on the basis of 1 pound of ash added for each pound of cement deleted. When Class F was used it was substituted on the basis of 1.25 pounds of ash added for each pound of cement deleted. Compressive strengths of the water reduced mixes, with and without fly ash, were determined at 7, 28, and 56 days of age. In every case except one the mixes containing the fly ash exhibited higher strengths than the same
concrete mix without the fly ash. An excellent correlation existed between the C3WR and C6WR mixes both with and without fly ash substitutions. The freeze-thaw durability of the concrete studied was not affected by presence or absence of fly ash. The data gathered suggests that the present Class C water reduced concrete paving mixes can be modified to allow the substitution of 15% of the cement with an approved fly ash
Strong responses of Southern Ocean phytoplankton communities to volcanic ash
No full textVolcanic eruptions have been hypothesized as an iron supply mechanism for phytoplankton blooms; however, little direct evidence of stimulatory responses has been obtained in the field. Here we present the results of twenty-one 1–2?day bottle enrichment experiments from cruises in the South Atlantic and Southern Ocean which conclusively demonstrated a photophysiological and biomass stimulation of phytoplankton communities following supply of basaltic or rhyolitic volcanic ash. Furthermore, experiments in the Southern Ocean demonstrated significant phytoplankton community responses to volcanic ash supply in the absence of responses to addition of dissolved iron alone. At these sites, dissolved manganese concentrations were among the lowest ever measured in seawater, and we therefore suggest that the enhanced response to ash may have been a result of the relief of manganese (co)limitation. Our results imply that volcanic ash deposition events could trigger extensive phytoplankton blooms, potentially capable of significant impacts on regional carbon cycling
Contorted stratification with clay lobes in volcanic ash beds, Raglan-Hamilton region, New Zealand
No full textContorted stratification in basal volcanic ash beds of the Pleistocene Hamilton Ash Formation incorporates halloysitic clay lobes which project upward into a bed of predominantly allophanic material. The forms produced are similar to convolute laminations described in other marine and non-marine sedimentary sequences.
The halloysitic clay lobes have been described previously as concretions and as the products of differential weathering processes.
A third hypothesis is proposed to explain the formation of the clay lobes and associated contorted stratification of these basal ash beds, namely, that the beds were deformed by plastic flowage of halloysitic clay into a sensitive allophanic bed. This deformation was possibly a result of water-saturated beds rapidly losing strength as a result of cyclic reversals of stress and strain produced by earthquake shock waves
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